Photoalignment material and method of manufacturing display substrate using the same
View Patent ↗A photoalignment material and a method of manufacturing of a display substrate using the photoalignment material are disclosed. The photoalignment material includes a photoalignment polymer, a photoalignment additive, and an organic solvent. When the photoalignment additive is used, a side reaction due to ultraviolet (UV) light may be prevented, and the stability of alignment layer may be improved.
1. A photoalignment material, comprising:
a photoalignment polymer having a weight of about 1 percent to about 10 percent of a weight of the photoalignment material and including a polyimide;
a photoalignment additive comprising an ultraviolet stabilizer to block or to absorb ultraviolet light, a weight of the photoalignment additive being about 0.001 percent to about 2 percent of the weight of the photoalignment material; and
an organic solvent.
2. The photoalignment material of claim 1 , wherein the ultraviolet stabilizer comprises at least one compound selected from the group consisting of a phenol compound, an aromatic amine compound, a benzophenone compound, a benzotriazole compound, an acrylate compound, and a salicylic acid derivative.
3. The photoalignment material of claim 2 , wherein the ultraviolet stabilizer absorbs light having a wavelength in a range of about 290 nm to 400 nm.
4. The photoalignment material of claim 1 , wherein the organic solvent comprises at least one chemical compound selected from the group consisting of chlorobenzene, N-methylpyrrolidone, dimethyl sulfoxide, dimethylformamide, toluene, chloroform, gamma-butyrolactone, methyl cellosolve, butyl carbitol, and tetrahydrofurane.
5. A photoalignment material, comprising:
a photoalignment polymer having a weight of about 1 percent to about 10 percent of a weight of the photoalignment material;
a photoalignment additive comprising an epoxy compound comprising two to four epoxy groups, a weight of the photoalignment additive being about 0.01 percent to about 3.5 percent of the weight of the photoalignment material; and
an organic solvent.
6. The photoalignment material of claim 5 , wherein the epoxy compound comprises at least one compound selected from the group consisting of trimethylolpropane triglycidyl ether (TMTE) and N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane (TGDDM).
7. The photoalignment material of claim 5 , further comprising a diamine compound comprising at least one photoreactive part, the diamine compound having a weight of about 0.001 percent to about 2 percent of the weight of the photoalignment material.
8. The photoalignment material of claim 5 , further comprising an ultraviolet stabilizer to block or to absorb ultraviolet light, the ultraviolet stabilizer having a weight of about 0.001 percent to about 2 percent of the weight of the photoalignment material.
9. The photoalignment material of claim 8 , wherein the ultraviolet stabilizer comprises at least one compound selected from the group consisting of a phenol compound, an aromatic amine compound, a benzophenone compound, a benzotriazole compound, an acrylate compound, and a salicylic acid derivative.
10. A method of manufacturing a display substrate, the method comprising:
forming a pixel unit on a base substrate;
forming an alignment layer by coating a photoalignment material on the base substrate, the photoalignment material comprising:
about 1 percent to about 10 percent by weight of a photoalignment polymer, based on the total weight of the photoalignment material, the photoalignment polymer comprising a polyimide;
an organic solvent; and
about 0.001 percent to about 2 percent by weight of a photoalignment additive, based on the total weight of the photoalignment material, the photoalignment additive comprising an ultraviolet stabilizer to block or to absorb ultraviolet light; and
irradiating light on the base substrate comprising the alignment layer.
11. The method of claim 10 , wherein the ultraviolet stabilizer comprises at least one compound selected from the group consisting of a phenol compound, an aromatic amine compound, a benzophenone compound, a benzotriazole compound, an acrylate compound, and a salicylic acid derivative.
12. The method of claim 10 , wherein forming the pixel unit on the base substrate comprises:
forming a switching element on the base substrate, the switching element connected to a gate line and a data line; and
forming a pixel electrode connected to the switching element.
13. The method of claim 10 , wherein forming the pixel unit on the base substrate comprises:
forming color filters on the base substrate; and
disposing a common electrode on the base substrate comprising the color filters.
14. The method of claim 10 , wherein irradiating the light comprises:
irradiating about 10 mJ to 10 J of linearly polarized ultraviolet light in a direction inclined by an angle of about 0° to about 70° with respect to a vertical direction of the substrate.
15. A method of manufacturing a display substrate, the method comprising:
forming a pixel unit on a base substrate;
forming an alignment layer by coating a photoalignment material on the base substrate, the photoalignment material comprising a photoalignment polymer, an organic solvent, and a photoalignment additive comprising an epoxy compound having two to four epoxy groups; and
irradiating light onto the base substrate comprising the alignment layer.
16. The method of claim 15 , wherein forming an alignment layer comprises disposing the photoalignment material comprising:
the photoalignment polymer having a weight of about 1 percent to about 10 percent of a weight of the photoalignment material;
the photoalignment additive having a weight of about 0.01 percent to about 3.5 percent of the weight of the photoalignment material; and
the organic solvent.
17. The method of claim 16 , wherein the epoxy compound comprises at least one compound selected from the group consisting of trimethylolpropane triglycidyl ether (TMTE) and N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane (TGDDM).
18. The method of claim 15 , wherein the photoalignment material further comprises a diamine compound having at least on photoreactive part, the diamine compound having a weight of about 0.001 percent to about 2 percent of the weight of the photoalignment material.
19. The method of claim 15 , wherein the photoalignment material further comprises an ultraviolet stabilizer to block or to absorb ultraviolet light, the ultraviolet stabilizer having a weight of about 0.001 percent to about 2 percent of the weight of the photoalignment material.
20. The method of claim 15 , wherein irradiating the light comprises:
irradiating about 10 mJ to 10 J of linearly polarized ultraviolet light in a direction inclined by an angle of about 0° to about 70° with respect to a vertical direction of the substrate.