Heat transferable material for improved image stability
View Patent ↗A heat transferable material includes a heat transferable polymeric binder and a light stabilizer that is an N-oxyl radical derived from a hindered amine, the N-oxyl radical having the following formula, wherein R 1 , R 2 , R 5 , and R 6 are each independently selected from a straight or branched C 1 -C 6 alkyl, and R 3 and R 4 are each independently selected from H, OH, OR, COOH, or COOR, wherein R is a straight or branched C 1 -C 6 alkyl or alkene, and having a molecular weight of 600 or less, is described. The heat transferable material can be in one or more sections or patches on a thermal donor element to provide a protective overcoat material. Optionally, a patch in the donor element can also include a dye. The heat transferable material provides better image stability and improved iridescence when applied to a thermal, inkjet, electophotographic, or silver halide receiver.
1. A heat transferable donor element comprising a polymeric support, the support having at least one portion thereof coated with a heat transferable material comprising a heat transferable polymeric binder, a plasticizer in an amount of up to 5 weight %, and a light stabilizer that is an N-oxyl radical having the following formula:
2. The element of claim 1 comprising at least one protective overcoat patch.
3. The element of claim 1 wherein the heat transferable material further comprises a UV absorbing material in the amount of 20% by weight or less.
4. The element of claim 1 wherein the heat transferable material further comprises at least one resin selected from a polymer represented by the following Formula I, a styrene/allyl alcohol copolymer, and the combination thereof:
wherein n is from 10-100.
5. The element of claim 4 wherein the heat transferable material comprises from about 40% to about 90% by weight of the resin of Formula I, and from about 2 to about 20% of a UV absorbing material.
6. The element of claim 1 further comprising an adhesive layer on the surface of the heat transferable material.
7. A heat transferable overcoat material comprising a heat transferable polymeric binder, a plasticizer in an amount of up to 5 weight %, and a light stabilizer that is an N-oxyl radical having the following formula:
the heat transferable overcoat material further comprising at least one resin selected from a polymer represented by the following Formula I, a styrene/allyl alcohol copolymer, and the combination thereof:
wherein n is from 10-100.
8. The overcoat material of claim 7 further comprising a UV absorbing material in the amount of 20% or less.
9. The overcoat material of claim 7 further comprising a plasticizer in the amount of up to 2%.
10. The overcoat material of claim 7 wherein the heat transferable material comprises from about 40% to about 90% by weight of the resin of Formula I, and from about 2 to about 20% of a UV absorbing material.
11. A heat transferable donor element comprising a polymeric support and the heat transferable overcoat material of claim 7 .
12. A thermal transfer assemblage comprising a receiver element in contact with at least a portion of a heat transferable donor element, wherein the heat transferable donor element comprises a polymeric support at least one portion thereof coated with a heat transferable material comprising a heat transferable polymeric binder, a plasticizer in an amount of up to 5 weight %, and a light stabilizer that is an N-oxyl radical having the following formula:
13. The assemblage of claim 12 wherein the heat transferable material of the heat transferable donor element is an overcoat material that further comprises at least one resin selected from a polymer represented by the following Formula I, a styrene/allyl alcohol copolymer, and the combination thereof:
wherein n is from 10-100.
14. The assemblage of claim 13 wherein the heat transferable material of the heat transferable donor element comprises from about 40% to about 90% by weight of the resin of Formula I, and from about 2 to about 20% of a UV absorbing material.
15. The assemblage of claim 12 wherein the heat transferable donor element comprises two or more patches of a heat transferable material, wherein at least one patch includes a dye and at least one patch includes a protective overcoat material.
16. The assemblage of claim 12 wherein the receiver element is selected from an inkjet receiver, a thermal receiver, an electrophotographic receiver, and a silver halide print.