Production of reduced catalyst PDC via gradient driven reactivity
View Patent ↗A method of forming a PDC cutter having solvent metal catalyst located adjacent the diamond and/or in the diamond and a layer of reactive material on the layer of diamond, the layer of reactive material for promoting the flow of the solvent metal catalyst material from the layer of diamond under high pressure and high temperature.
1. A method of making a compact comprising:
depositing catalyst material on a substrate;
depositing diamond powder on the catalyst material;
depositing a reactive material on the diamond powder, the reactive material formulated to remove catalyst from the diamond powder under high pressure and high temperature; and
pressing and heating the reactive material, the diamond powder, the catalyst material, and the substrate to form a polycrystalline diamond compact from at least a portion of the diamond powder.
2. The method of claim 1 , wherein depositing a reactive material comprises depositing the reactive material opposite the substrate.
3. The method of claim 1 , wherein depositing diamond powder comprises:
depositing a first diamond powder having a first particle size distribution on the substrate; and
depositing a second diamond powder having a second particle size distribution on the first diamond powder.
4. The method of claim 3 , further comprising removing the second diamond powder after forming the polycrystalline diamond material.
5. The method of claim 1 , wherein depositing the reactive material comprises depositing one of fine diamond, graphite, metal, and a metal alloy.
6. The method of claim 1 , wherein depositing the reactive material comprises depositing crystalline graphite.
7. The method of claim 3 , wherein depositing the first diamond powder comprises depositing diamond particles having an average particle size within a range of from about 5 microns to about 40 microns.
8. The method of claim 7 , wherein depositing the second diamond powder comprises depositing second diamond particles having an average particle size within a range of from about 100 microns to about 500 microns.
9. The method of claim 3 , wherein depositing the second diamond powder comprises depositing diamond particles having multi-modal particle size distribution.
10. The method of claim 1 , wherein the diamond powder comprises diamond particles and a wetting agent.
11. The method of claim 1 , wherein depositing the catalyst material comprises depositing cobalt powder.
12. The method of claim 1 , wherein depositing the catalyst material comprises depositing a solid disc comprising cobalt.
13. The method of claim 1 , wherein depositing the catalyst material comprises depositing the catalyst material to extend around a portion of the substrate.
14. The method of claim 1 , wherein depositing the diamond powder comprises depositing the diamond powder to extend around a portion of the substrate.
15. The method of claim 1 , wherein depositing the reactive material comprises depositing the reactive material to extend around a portion of the diamond powder.
16. The method of claim 1 , wherein depositing the reactive material comprises depositing the reactive material to extend around portions of each of the diamond powder and the substrate.
17. The method of claim 1 , wherein the catalyst material has at least one aperture extending therethrough.
18. The method of claim 1 , wherein the catalyst material has a plurality of apertures extending therethrough.
19. A method of making a compact comprising:
depositing a catalyst material on a substrate;
depositing a first diamond powder on the catalyst material;
depositing a second diamond powder on the first diamond powder;
depositing a reactive material on the second diamond powder, the reactive material formulated to remove catalyst from the first diamond powder and the second diamond powder under pressure and temperature; and
sintering the reactive material, the second diamond powder, the first diamond powder, the catalyst material, and the substrate under high pressure and high temperature to form a polycrystalline diamond compact from the first diamond powder.
20. The method of claim 19 , wherein the second diamond powder comprises larger diamond particles than the first diamond powder.
21. The method of claim 19 , further comprising removing a material formed from the second diamond powder after forming the polycrystalline diamond compact.
22. The method of claim 19 , wherein depositing the reactive material comprises depositing one of fine diamond, graphite, metal, and a metal alloy.
23. A method of forming a polycrystalline diamond compact, comprising:
forming a diamond layer over a substrate;
forming a sacrificial layer on the diamond layer;
forming a reactive layer on the sacrificial diamond layer, the reactive layer comprising a reactive material formulated to be more reactive with catalyst material of the substrate than is a material of the diamond layer;
performing a sintering process to diffuse at least a portion of the catalyst material into each of the diamond layer, the sacrificial diamond layer, and the reactive layer and form a polycrystalline diamond compact from the diamond layer; and
removing the reactive layer and the sacrificial diamond layer after performing the sintering process.