High yield ratio and high-strength hot-dip galvanized steel sheet excellent in workability and production method thereof
A high-strength hot-dip galvanized steel sheet excellent in workability according to the present invention: contains C, Si, Mn and other elements; has a dual phase structure containing ferrite and martensite as the metallographic structure; and, in the ferrite structure, satisfies the expression 0.2≦(L b /L a )≦1.5 when the length per unit area of the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is defined as L a and the length per unit area of the grain boundaries of crystal grains the crystal orientation differences of which are less than 10 degrees is defined as L b , and further satisfies the requirements that the average value of D is 25 μm or less and the area ratio of crystal grains satisfying the expression D≦30 μm in the ferrite grains surrounded by the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is 50% or more when the circle equivalent diameter of each of ferrite grains surrounded by the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is defined as D; and has a tensile strength of 980 MPa or more.
1. A hot-dip galvanized steel sheet containing
C: 0.05 to 0.3% (in terms of mass %, hereunder same as above with respect to chemical composition),
Si: 0.005 to 3.0%,
Mn: 1.5 to 3.5%,
Al: 0.005 to 0.15%,
P: 0.1% or less, and
S: 0.05% or less,
with the remainder comprising of iron and unavoidable impurities, wherein:
in percentage in a metallographic structure,
the area ratio of ferrite is 5 to 85%,
the area ratio of martensite is 15 to 90%,
the area ratio of retained austenite is 20% or less, and
the sum of the area ratios of said ferrite, said martensite, and said retained austenite is 70% or more;
in the ferrite structure, when the length per unit area of the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is defined as L a and the length per unit area of the grain boundaries of crystal grains the crystal orientation differences of which are less than 10 degrees is defined as L b , the expression 0.2≦(L b /L a )≦1.5 is satisfied;
when the circle equivalent diameter of each of ferrite grains surrounded by the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is defined as D,
the average value of D is 25 μm or less, and
the area ratio of crystal grains satisfying the expression D≦30 μm in the ferrite grains surrounded by the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is 50% or more; and
the tensile strength of said hot-dip galvanized steel sheet is 980 MPa or more.
2. A high-strength hot-dip galvanized steel sheet according to claim 1 , further containing Cr: 1.0% or less.
3. A high-strength hot-dip galvanized steel sheet according to claim 1 , further containing Mo: 1.0% or less.
4. A high-strength hot-dip galvanized steel sheet according to claim 1 , further containing at least one selected from among the group of Ti: 0.2% or less, Nb: 0.3% or less, and V: 0.2% or less.
5. A high-strength hot-dip galvanized steel sheet according to claim 1 , further containing at least either one of Cu: 3% or less, and Ni: 3% or less.
6. A high-strength hot-dip galvanized steel sheet according to claim 1 , further containing B: 0.01% or less.
7. A high-strength hot-dip galvanized steel sheet according to claim 1 , further containing at least one selected from among the group of Ca: 0.01% or less, Mg: 0.01% or less, and REM: 0.005% or less.
8. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein alloying hot-dip galvanizing is applied as the hot-dip galvanizing.
9. A method for producing a high-strength hot-dip galvanized steel sheet according to claim 1 , said method comprising:
heating a cold-rolled steel sheet so that the heating rate may satisfy the expressions (1) to (3) below and the highest achieved temperature during the heating may satisfy the expression (4) below; and
applying annealing so that the residence time in the temperature range from 600° C. to said highest achieved temperature may be 400 seconds or less,
heating rate from room temperature to 350° C.: HR1≦900° C./min. (1),
heating rate from 350° C. to 700° C.: HR2≧60° C./min. (2),
5° C./min.≦heating rate from 700° C. to highest achieved temperature: HR3≦420° C./min. (3),
Ac 1 point≦(highest achieved temperature)≦(lower temperature of either T rec or Ac 3 point) (4),
where T rec is defined as
T rec =−4×(cold reduction ratio)+1,000+3×(Si %)+14×(Mn %)+2×(Cr %)+19×(Mo %)+38×(Cu %)+2×(Ni %),
when none of Ti, Nb, and V is contained, and
T rec =−10×(cold reduction ratio)+1,100+3×(Si %)+14×(Mn %)+2×(Cr %)+19×(Mo %)+38×(Cu %)+2×(Ni %)+5,000×(Ti %)+6,200×(Nb %)+4,350×(V %),
when at least one of Ti, Nb, and V is contained.
(each (element name %) represents the content (mass %) of each element).
10. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the expression 0.25≦(L b /L a )≦1.4 is satisfied.
11. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the expression 0.30≦(L b /L a )≦1.3 is satisfied.
12. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the average value of D is 20 μM or less.
13. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the average value of D is 15 μm or less.
14. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the area ratio of crystal grains satisfying the expression D≦30 μm in the ferrite grains surrounded by the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is 60% or more.
15. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the area ratio of crystal grains satisfying the expression D≦30 μm in the ferrite grains surrounded by the grain boundaries of crystal grains the crystal orientation differences of which are 10 degrees or more is 70% or more.
16. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the sum of the area ratios of said ferrite, said martensite, and said retained austenite is 75% or more.
17. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein the hot-dip galvanized steel sheet has a yield ratio of 60% or more.
18. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein when total elongation is 14% or more, the expression 980 MPa≦TS<1,180 MPa is satisfied, wherein TS means tensile strength.
19. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein when total elongation is 12% or more, the expression 1,180 MPa≦TS<1,270 MPa is satisfied, wherein TS means tensile strength.
20. A high-strength hot-dip galvanized steel sheet according to claim 1 , wherein when total elongation is 11% or more, the expression 1,270 MPa≦TS<1,370 MPa is satisfied, wherein TS means tensile strength.