Liquid crystal compound having lactone ring, liquid crystal composition, and liquid crystal display device
View Patent ↗A nematic liquid crystal compound represented by any one of formulas (a-1) to (a-6): in formulas (a-1) to (a-6), Ra and Rb are each independently hydrogen or alkyl having 1 to 10 carbons, provided that in the alkyl, —CH2- may be replaced by —O—, —(CH2)2- may be replaced by —CH═CH—, and hydrogen may be replaced by a halogen; ring A1 and ring A2 are each independently trans-1,4-cyclohexylene or 1,4-phenylene, provided that in these rings hydrogen may be replaced by a halogen, and in the case where the ring is trans-1,4-cyclohexylene, —CH2- may be replaced by —O—, and —CH2CH— may be replaced by —CH═C—; and Z1 and Z2 are each independently a single bond, —COO—, —OCO—, —OCH2-, —CH2O— or —CH2CH2-, provided that in formula (a-3), in the case where ring A2 is trans-1,4-cyclohexylene, Z2 is a single bond, —COO—, —OCO—, —OCH2- or —CH2O—, in the case where Ra is —C3H7, Rb is —OC2H5, and Z2 is a single bond, ring A2 is trans-1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 2-fluoro- 1,4-phenylene, 3-fluoro-1,4-phenylene, 2-fluoro-3-chloro-1,4-phenylene, 2-chloro- 3-fluoro-3,4-phenylene or 2,3-dichloro-1,4-phenylene, and in formula (a-4), in the case where ring A1 is trans-1,4-cyclohexylene, Z1 is a single bond, —COO—, —OCO—, —OCH2- or —CH2O—.
1. A nematic liquid crystal compound represented by any one of formulas (b-1), (b-3) to (b-6):
wherein in formulas (b-1), (b-3) to (b-6):
(i) Rc and Rd are each independently hydrogen, a halogen or alkyl having approximately 1 to approximately 10 carbons, provided that in the alkyl, —CH 2 — may be replaced by —O—, —(CH 2 ) 2 — may be replaced by —CH═CH—, and hydrogen may be replaced by a halogen;
(ii) ring A 3 and ring A 4 are each independently trans-1,4-cyclohexylene or 1,4-phenylene, provided that in these rings hydrogen may be replaced by a halogen, and in the case where the ring is trans-1,4-cyclohexylene, —CH 2 — may be replaced by —O—, and —CH 2 CH— may be replaced by —CH═C—; and
(iii) Z 3 and Z 4 are each independently a single bond, —COO—, —OCO—, —OCH 2 —, —CH 2 O— or —CH 2 CH 2 —; and
provided that in formula (b-6), A 4 are trans-1,4-cyclohexylene, provided that in these rings hydrogen may be replaced by a halogen, and in the case where the ring is trans-1,4-cyclohexylene, —CH 2 — may be replaced by —O—, and —CH 2 CH— may be replaced by —CH═C—.
2. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-1); and wherein Rc and Rd are each independently hydrogen, alkyl having approximately 1 to approximately 10 carbons or alkoxy having approximately 1 to approximately 9 carbons.
3. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-1); and wherein Rc and Rd are each independently hydrogen or alkyl having approximately 1 to approximately 10 carbons.
4. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); and wherein Z 3 or Z 4 is a single bond.
5. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); and wherein ring A 3 or ring A 4 is 1,4-cyclohexylene.
6. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); wherein Z 3 or Z 4 is a single bond; and wherein ring A 3 or ring A 4 is 1,4-cyclohexylene.
7. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); wherein Rc and Rd are each independently hydrogen or alkyl having 1 to 10 carbons; wherein Z 3 or Z 4 is a single bond; and wherein ring A 3 or ring A 4 is 1,4-cyclohexylene.
8. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); and wherein ring A 3 or ring A 4 is 1,4-phenylene, arbitrary hydrogen of which may be replaced by a halogen.
9. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); wherein Z 3 or Z 4 is a single bond; and wherein ring A 3 or ring A 4 is 1,4-phenylene, arbitrary hydrogen of which may be replaced by a halogen.
10. The nematic liquid crystal compound according to claim 1 , wherein the compound is represented by formula (b-3), (b-4), (b-5) or (b-6); wherein Rc and Rd are each independently hydrogen or alkyl having 1 to 10 carbons; wherein Z 3 or Z 4 is a single bond; and wherein ring A 3 or ring A 4 is 1,4-phenylene, arbitrary hydrogen of which may be replaced by a halogen.
11. A nematic liquid crystal composition comprising at least one compound selected from the group of the compound according to claim 1 .
12. The nematic liquid crystal composition according to claim 11 , further comprising at least one compound selected from the group of compounds represented by formulas (1), (2), (3), (4), (5), (6), (7), (8) and (9):
wherein in formulas (1) to (9):
R 1 and R 2 are each independently alkyl having approximately 1 to approximately 10 carbons, provided that in the alkyl, —CH 2 — may be replaced by —O—, —(CH 2 ) 2 — may be replaced by —CH═CH—, and hydrogen may be replaced by fluorine, and R 1 may be fluorine;
ring B and ring C are each independently 1,4-cyclohexylene, 1,4-phenylene or decahydro-2,6-naphthylene;
Z 5 and Z 6 are each independently —(CH 2 ) 2 —, —COO— or a single bond; and
L 1 , L 2 , L 3 and L 4 are each independently hydrogen or fluorine, provided that at least one of L 1 , L 2 , L 3 and L 4 is hydrogen.
13. The nematic liquid crystal composition according to claim 12 , further comprising at least one compound selected from the group of compounds represented by formulas (10), (11) and (12):
wherein in formulas (10) to (12):
R 3 and R 4 are independently alkyl having approximately 1 to approximately 10 carbons, provided that in the alkyl, —CH 2 — may be replaced by —O—, —(CH 2 ) 2 — may be replaced by —CH═CH—, and hydrogen may be replaced by fluorine;
ring D, ring E and ring F are each independently 1,4-cyclohexylene, pyrimidine-2,5-diyl, or 1,4-phenylene, arbitrary hydrogen of which may be replaced by fluorine; and
Z 7 and Z 8 are each independently —C═C—, —COO—, —(CH 2 ) 2 —, —CH═CH— or a single bond.
14. The nematic liquid crystal composition claim 11 , wherein the composition further comprises at least one optically active compound.
15. A liquid crystal display device comprising the nematic liquid crystal composition according to claim 11 .