Method and system for monitoring a hydrocarbon adsorber
View Patent ↗A catalyst and method of forming the catalyst includes a catalyst body having hydrocarbon adsorber material and oxygen storage capacity material disposed thereon.
1. A system comprising:
a catalyst body configured to receive an exhaust gas from an engine;
a hydrocarbon adsorber disposed on or within the catalyst body, wherein the hydrocarbon adsorber is configured to have a first degradation rate at temperatures greater than a predetermined temperature at which the adsorber begins to degrade; and
an oxygen storage element disposed on or within the catalyst body, wherein the oxygen storage element comprises oxygen storage material, wherein the oxygen storage material is configured to have a second degradation rate at the temperatures greater than the predetermined temperature, and wherein the second degradation rate is greater than or equal to the first degradation rate.
2. A system as recited in claim 1 , wherein the hydrocarbon adsorber and the oxygen storage element are disposed within a washcoat of the catalyst body.
3. A system as recited in claim 2 , wherein the catalyst body comprises a substrate, wherein the washcoat is disposed on the substrate.
4. A system as recited in claim 3 , further comprising:
a first layer disposed directly on the substrate; and
a second layer disposed on the first layer.
5. A system as recited in claim 4 , wherein:
the first layer comprises the hydrocarbon adsorber; and
the second layer comprises the oxygen storage element.
6. A system as recited in claim 4 , wherein:
the first layer comprises the oxygen storage element; and
the second layer comprises the hydrocarbon adsorber.
7. A system as recited in claim 3 , wherein the hydrocarbon adsorber is disposed on an inlet portion of the catalyst body and upstream from the oxygen storage element.
8. A system as recited in claim 3 , wherein the oxygen storage material comprises cerium oxide (CeO 2 ), wherein the CeO 2 is dispersed uniformly within the washcoat.
9. A system as recited in claim 1 , wherein the oxygen storage material is dispersed non-uniformly within a washcoat of the catalyst body.
10. A system as recited in claim 1 , wherein the oxygen storage material is disposed on an outlet portion of the catalyst body and downstream from the hydrocarbon adsorber.
11. A system as recited in claim 1 , wherein the catalyst body has an annular cross section.
12. A system as recited in claim 1 , wherein:
the hydrocarbon adsorber comprises zeolite; and
the oxygen storage material comprises cerium oxide and degrades at a rate faster than or equal to the zeolite.
13. A system as recited in claim 1 , wherein the oxygen storage material:
comprises particles;
each of the particles has a surface area of a size less than a first predetermined surface area; and
the surface area, of the particles as disposed on or within the catalyst body, is greater than a second predetermined surface area per a predetermined number of grams of the particles.
14. A system as recited in claim 1 , wherein:
the oxygen storage element comprises metal elements; and
a concentration of the metal elements in the catalyst body is less than a predetermined number of grams per cubic foot.
15. A system as recited in claim 14 , wherein the metal elements comprise at least one of copper, gold, silver and platinum.
16. A system as recited in claim 14 , wherein:
the concentration of the metal elements is set such that a deactivation temperature of the oxygen storage element is matched to a deactivation temperature of the hydrocarbon adsorber; and
the deactivation temperature of the hydrocarbon adsorber is a temperature above which performance of the hydrocarbon adsorber begins to degrade.
17. A system as recited in claim 1 , wherein the hydrocarbon adsorber and the oxygen storage element begin to degrade at the predetermined temperature.
18. A system as recited in claim 1 , further comprising:
a first constituent determination module that determines an oxygen level within the exhaust gas;
a second constituent determination module that determines an amount of exhaust gas constituent within the hydrocarbon adsorber;
a storage capacity module that determines a storage capacity of the hydrocarbon adsorber based on the amount of exhaust gas constituent within the hydrocarbon adsorber or a time period associated with a lean-to-rich transition of an air fuel ratio of the engine; and
a comparison module that generates a fault signal based on the oxygen level within the exhaust gas and at least one of the amount of exhaust gas constituent within the hydrocarbon adsorber and the storage capacity, wherein the fault signal indicates that the storage capacity of the hydrocarbon adsorber is less than a minimum storage capacity.
19. A system as recited in claim 18 , further comprising:
a first sensor positioned upstream from the catalyst body, wherein the first sensor generates a first signal indicative of the oxygen level within the exhaust gas; and
a second sensor connected to the catalyst body, wherein the second sensor generates a second signal indicative of the amount of exhaust gas constituent in the hydrocarbon adsorber,
wherein the first constituent determination module determines the oxygen level within the exhaust gas based on the first signal, and
wherein the second constituent determination module determines the amount of exhaust gas constituent in the hydrocarbon adsorber based on the second signal.
20. A system as recited in claim 19 , wherein:
the storage capacity module determines the storage capacity of the hydrocarbon adsorber based on the time period associated with a lean-to-rich transition of the air fuel ratio of the engine; and
the time period associated with the lean-to-rich transition
starts when the first sensor transitions from indicating a lean mode to indicating a rich mode, and
ends when the second sensor transitions from indicating a lean mode to indicating a rich mode.
21. A system as recited in claim 18 , wherein:
the second constituent determination module determines an oxygen level within the hydrocarbon adsorber;
the storage capacity module that determines an oxygen storage capacity of the hydrocarbon adsorber based on the oxygen level within the hydrocarbon adsorber or the time period associated with the lean-to-rich transition of the air fuel ratio of the engine;
the comparison module that generates the fault signal based on the oxygen level within the exhaust gas and at least one of the oxygen level within the hydrocarbon adsorber and the oxygen storage capacity; and
the fault signal indicates that the oxygen storage capacity of the hydrocarbon adsorber is less than a minimum oxygen storage capacity.