Thermally resistant anaerobically curable compositions

1. An anaerobic curable composition, comprising:

(a) a (meth)acrylate component;

(b) an anaerobic cure system; and

(c) calcium fluoride present in an amount of about 10 to about 50 weight percent based on the total weight of the composition; and

(d) a polyolefin, a halogenated polyolefin or a combination thereof, present in an amount of about 2 to about 30 weight percent based on the total weight of the composition.

2. The composition according to claim 1 , wherein the (meth)acrylate component is represented by H 2 C═CGCO 2 R 1 , wherein G is a member selected from the group consisting of H, halogen and alkyl having from 1 to about four carbon atoms, and R 1 is a member selected from the group consisting of alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkaryl, and aryl groups having from 1 to about 16 carbon atoms, with or without substitution or interruption by a member selected from the group consisting of silane, silicon, oxygen, halogen, carbonyl, hydroxyl, ester, carboxylic acid, urea, urethane, carbamate, amine, amide, sulfur, sulfonate and sulfone.

3. The composition according to claim 1 , wherein the (meth)acrylate component is selected from the group consisting of silicone (meth)acrylates, polyethylene glycol di(meth)acrylates, bisphenol-A-(meth)acrylates, ethoxylated bisphenol-A-(meth)acrylates, bisphenol-F-(meth)acrylates, ethoxylated bisphenol-F-(meth)acrylates, tetrahydrofuran (meth)acrylates and di(meth)acrylates, hydroxypropyl (meth)acrylate, hexanediol di(meth)acrylate, and trimethylol propane tri(meth)acrylate.

4. The composition according to claim 1 , wherein the anaerobic cure system comprises a cure system selected from the group consisting of the following lettered cure systems:

A. the combination of saccharin, toluidines, acetyl phenylhydrazine, maleic acid, and quinones;

B.

wherein R 1 -R 7 are each independently selected from the group consisting of hydrogen, C 1-4 alkyl and alkoxy; Z is a carbon-carbon single bond or carbon-carbon double bond; m is 0 or 1; and n is an integer between 1 and 5;

C.

wherein Y is an aromatic ring, optionally substituted at up to five positions by C 1-6 alkyl or alkoxy, or halo groups; A is C═O, S═O or O═S═O; X is NH, O or S and Z is an aromatic ring, optionally substituted at up to five positions by C 1-6 alkyl or alkoxy, or halo groups, or Y and Z taken together may join to the same aromatic ring or aromatic ring system, provided that when X is NH, o-benzoic sulfimide is excluded therefrom;

D.

wherein R is selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, hydroxyalkyl, hydroxyalkenyl, carboxyl, or sulfonato, and R 1 is as defined above and alkenyl, hydroxyalkyl, hydroxyalkenyl, or aralkyl;

E. trithiadiaza pentalenes represented by the following structure:

wherein A and A l are each independently selected from the group consisting of O and N; and

R, R 1 , R 2 and R 3 are the same or different, are as defined above and cycloalkyl, cycloalkenyl, and aryl, having from 1 to about 30 carbon atoms, and may be substituted or interrupted with a heteroatom, and heterocyclic structures, or

R 1 and R 3 taken together may join to form a cyclic structure having from about 20 to about 28 ring atoms, and together represent dialkyl substituted polyether structures that may be substituted or interrupted with the trithiadiaza pentalene structure, which itself may or may not be substituted by A 1 , R 2 , or R 3 , as defined above; and

F. the combination of a triazine and a thiol.

5. The composition according to claim 1 , wherein the polyolefin is a member selected from the group consisting of polyethylenes, polypropylenes, polybutylenes, copolymers thereof,and combinations thereof.

6. The composition according to claim 1 , wherein the halogenated polyolefin is a member selected from the group consisting of halogenated polyethylenes, halogenated polypropylenes, halogenated polybutylenes, copolymers thereof,and combinations thereof.

7. The composition according to claim 6 , wherein the halogen of the halogenated polyolefin is fluorine.

8. Reaction products of the composition according to claim 1 .

9. An anaerobic curable composition, comprising:

(a) a (meth)acrylate component;

(b) an anaerobic cure system; and

(c) a compound of a Group IA or Group IIA element and a halogen, present in an amount of about 25 to about 35 weight percent based on the total weight of the composition; and

(d) a polyolefin, a halogenated polyolefin or a combination thereof, present in an amount of about 10 to about 25 weight percent based the total weight of the composition.

10. An anaerobic curable composition, comprising:

(a) a (meth)acrylate component;

(b) an anaerobic cure system; and

(c) calcium fluoride present in an amount of about 25 to about 30 weight percent, based on the total weight of the composition; and

(d) a polyolefin and a halogenated polyolefin present in an amount of about 20 to about 22 weight percent, wherein the polyolefin is present in an amount of at least 2 weight percent with a balance thereof being the halogenated polyolefin, based on the total weight of the composition.