Stainless steel separator for fuel cell and the manufacturing method thereof

1. A method for surface treatment of a stainless steel separator for a fuel cell, comprising:

preparing a stainless steel sheet containing nickel, chrome and iron, and having a passive film on a surface of the stainless steel sheet; and

dipping the stainless steel sheet into an etching solution formed by mixing one of oxalic acid (C 2 H 2 O 4 ) and hydrogen peroxide (H 2 O 2 ) with a solution of nitric acid (HNO 3 ) and sulfuric acid (H 2 SO 4 ) prepared as a basic solution at a temperature of 50˜70° C. for 30 seconds to 30 minutes to selectively lower the amount of Fe in the passive film formed on the surface of the stainless steel sheet,

wherein the stainless steel separator has a contact resistance of 20 mΩ·cm 2 or less and corrosion current of 1 μA/cm 2 or less

wherein the etching solution comprises 5˜20 wt % pure nitric acid, 2˜15 wt % pure sulfuric acid, 0.5˜10 wt % pure oxalic acid or pure hydrogen peroxide, and a balance of water.

2. The method according to claim 1 , wherein the dipping step is performed for 30 seconds to 10 minutes to shorten a processing time.

3. The method according to claim 1 , wherein the stainless steel sheet comprises 0.08 wt % carbon (C), 16˜28 wt % chrome (Cr), 0.1˜20 wt % nickel (Ni), 0.1˜6 wt % molybdenum (Mo), 0.1˜5 wt % tungsten (W), 0.1˜2 wt % tin (Sn), 0.1˜2 wt % copper, and the balance of iron (Fe) and other unavoidable impurities.

4. The method according to claim 1 , wherein the passive film having the lowered amount of Fe has a condition of (Cr+Ni)/Fe≧1 in terms of atomic weight.

5. The method according to claim 1 , wherein the passive film having the lowered amount of Fe comprises 20˜75 wt % Cr.

6. The method according to claim 1 , wherein the passive film having the lowered amount of Fe comprises 30 wt % or less Fe.