Optical recording medium
View Patent ↗To provide an optical recording medium excellent in the balance of characteristics, which has a sufficient surface hardness and of which the deformation when the environmental temperature and the environmental humidity change is small. An optical recording medium comprising a resin substrate, a recording and reading layer, a cover coat layer which is a cured product of a radiation-curable composition containing a urethane (meth)acrylate (A) and a (meth)acrylate compound (B) other than the urethane (meth)acrylate (A), and a hard coat layer having a surface hardness of at least B in this order, wherein of the cover coat layer, the ratio of the elastic modulus in tension upon absorbing water to saturation to the elastic modulus in tension at 25° C. under a humidity of 45% is at least 0.20.
1. An optical recording medium comprising a resin substrate, a recording and reading layer, a cover coat layer which is a cured product of a radiation-curable composition comprising a urethane (meth)acrylate (A) and a (meth)acrylate compound (B) other than the urethane (meth)acrylate (A), and a hard coat layer having a surface hardness of at least B in this order, wherein the cover coat layer has a ratio of at least 0.20 where the ratio is defined by an elastic modulus in tension upon absorbing water to saturation over an elastic modulus in tension at 25° C. under a humidity of 45% before absorbing water.
2. The optical recording medium according to claim 1 , wherein the water absorption of the cover coat layer is at most 2 (wt/wt) % at 25° C.
3. The optical recording medium according to claim 1 , wherein for the optical recording medium left at rest in an environment at 25° C. for a certain time and then left at rest in an environment at 5° C. for one hour, and for the optical recording medium left at rest in an environment at 25° C. for a certain time and then left at rest in an environment at 55° C. for one hour, when a displacement amount in the direction vertical to the surface of the resin substrate at a position farthest from the center in the recording and reading region of each optical recording medium is measured, the displacement amount is at most 150 μm.
4. The optical recording medium according to claim 1 , wherein the (meth)acrylate compound (B) other than the urethane (meth)acrylate (A) is at least one of a monofunctional (meth)acrylate (b1) and a multifunctional (meth)acrylate (b2).
5. The optical recording medium according to claim 1 , wherein the surface hardness of the hard coat layer is at least HB; the cover coat layer is a cured product of a radiation-curable composition comprising the urethane (meth)acrylate (A) which is a reaction product of a composition comprising a polyisocyanate (a1), a diol (a2) having a molecular weight less than 400, a polyol (a3) having a molecular weight of at least 400and a hydroxyl group-containing (meth)acrylate (a4), and the monofunctional (meth)acrylate (b1) and the multifunctional (meth)acrylate (b2); the elastic modulus upon absorbing water to saturation of the cover coat layer is within a range of from 200 MPa to 1,100 MPa; and the thickness of the cover coat layer is within a range of from 70μm to 105 μm.
6. The optical recording medium according to claim 5 , wherein the cover coat layer is a cured product of a radiation-curable composition comprising the urethane (meth)acrylate (A), the monofunctional (meth)acrylate (b1) and the multifunctional (meth)acrylate (b2), and contents of the respective components are such that (A): 10 to 85 wt %, (b1): 10 to 80 wt %, and (b2): 0 to 30 wt %.
7. The optical recording medium according to claim 5 , wherein the polyol (a3) having a molecular weight of at least 400 comprises a polyol (a3-1) having a molecular weight of at least 400 and less than 1,500 and a polyol (a3-2) having a molecular weight of at least 1,500.
8. The optical recording medium according to claim 5 , wherein the polyol (a3) having a molecular weight of at least 400 is a polyether polyol.
9. The optical recording medium according to claim 5 , wherein the diol (a2) having a molecular weight less than 400 is a diol having two hydroxyl groups connected by carbon.
10. The optical recording medium according to claim 4 , wherein at least one of the monofunctional (meth)acrylate (b1)and the multifunctional (meth)acrylate (b2) is an alicyclic (meth)acrylate.
11. The optical recording medium according to claim 5 , wherein the multifunctional (meth)acrylate (b2) is an aliphatic multifunctional (meth)acrylate.
12. A Blu-ray Disc comprising the optical recording medium according to claim 1 .