IP Library Granted Patent US 8,420,731
Granted Patent B2
US 8,420,731 · App. 12/596,736 · Granted Apr 16, 2013

Dispersing and emulsifying resins comprising polyether

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Quick Facts
Patent No.
US 8,420,731
App. No.
12/596,736
Granted
Apr 16, 2013
Kind
B2
Abstract

The invention relates to dispersing resins for solids which are obtainable through the partial or complete reaction of the hydroxyl groups of carbonyl-hydrogenated ketone-aldehyde resins with one or more oxiranes and, if desired, subsequent complete or partial esterification with organic and/or inorganic acids.

Claims (32)

1. A dispersing resin for solids which is obtained through the partial or complete reaction of hydroxyl groups of carbonyl-hydrogenated ketone-aldehyde resins with one or more oxiranes and, if desired, subsequent complete or partial esterification with organic and/or inorganic acids, wherein during the preparation process one or more oxirane compounds of general formula (I)

are used in which

R is an aliphatic, cycloaliphatic, aromatic or araliphatic hydrocarbon radical or hydrogen, and

R a and R b are alike or different and are hydrogen or alkyl radicals which may also, together with the two oxirane carbon atoms, form a 5- to 8-membered ring, and

e is=0 or 1.

2. The dispersing resin as claimed in claim 1 , wherein R is an alkyl radical having 1 to 10 C atoms.

3. The dispersing resin as claimed in claim 1 , wherein R a and R b are alkyl radicals which, together with the two oxirane carbon atoms, form a 6-membered ring.

4. A dispersion of solids in a liquid medium, comprising at least one dispersing resin which is obtained through the partial or complete reaction of hydroxyl groups of carbonyl-hydrogenated ketone-aldehyde resins with one or more oxiranes and, if desired, subsequent complete or partial esterification with organic and/or inorganic acids, wherein during the preparation process one or more oxirane compounds of general formula (I)

are used in which

R is an aliphatic, cycloaliphatic, aromatic or araliphatic hydrocarbon radical or hydrogen, and

R a and R b are alike or different and are hydrogen or alkyl radicals which may also, together with the two oxirane carbon atoms, form a 5- to 8-membered ring, and

e is=0 or 1.

5. A dispersing resin of general formula (II)

K—(OX) w   (II)

in which

K is a carbonyl-hydrogenated ketone-formaldehyde resin and

X is a hydrogen atom or

the radical Y=[(C l H 2l O) a —(C m H 2m —O) b —(C n H 2n O) c —(SO) d —Z],

a, b and c independently of one another are values from 0 to 100, with the proviso that the sum of a+b+c is >0,

d=0 to 10,

l, m and n independently of one another are ≧2 to 14,

w=2 to 15,

SO=styrene oxide, and

Z is hydrogen and/or a radical selected from the group consisting of sulfonic acids, sulfuric acids, phosphonic acids, phosphoric acids, carboxylic acids, isocyanates, and epoxides,

with the proviso that the radical Y is present at least once in the molecule.

6. The dispersing resin as claimed in claim 5 , wherein a, b and c independently of one another adopt the values 5 to 35.

7. The dispersing resin as claimed in claim 5 , wherein d is <5.

8. The dispersing resin as claimed in claim 5 , wherein d is 0.

9. The dispersing resin as claimed in claim 5 , wherein l, m and n independently of one another are 2 to 4.

10. The dispersing resin as claimed in claim 5 , wherein w is 3 to 12.

11. The dispersing resin as claimed in claim 5 , wherein Z is selected from the group consisting of phosphoric acid and (meth)acrylic acid.

12. The dispersing resin as claimed in claim 5 , wherein Z is the radical of monoesterified or diesterified phosphoric acid.

Assignments (2)
MERGER Recorded Feb 26, 2014
From: EVONIK GOLDSCHMIDT GMBH
To: EVONIK DEGUSSA GMBH
Reel/Frame 032335/0326 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 20, 2009
From: CAVALEIRO, PEDRO; ESSELBORN, EBERHARD; GLOECKNER, PATRICK; LOEBBUS, MARIO; VEIT, THOMAS
To: EVONIK GOLDSCHMIDT GMBH
Reel/Frame 023396/0293 →