Methods for producing rubber mixtures
View Patent ↗The invention relates to processes for the production of microgel-containing rubber mixtures, to rubber mixtures obtainable by the processes, to processes for the production of vulcanizates, and also to vulcanizates after the vulcanization process, in particular in the form of tires, parts of tires, or industrial rubber items.
1. A process for the production of a rubber mixture, comprising the steps of:
admixing the following components:
one or more rubber components,
one or more oxidic fillers containing hydroxy groups,
one or more microgels containing hydroxy groups, and
one or more sulfur-containing organosilicon compounds,
wherein the sulfur-containing organosilicon compounds are admixed in at least a first portion and a separate second portion, wherein the first portion comprises at least 30% by weight of the total amount of the sulfur-containing organosilicon compounds.
2. The process according to claim 1 , wherein said admixing is performed in at least a first mixing stage, whereby a first mixture is formed, and a second mixing stage, whereby a second mixture is formed.
3. The process according to claim 2 , wherein the addition of the organosilicon compounds is performed in the first mixing stage and the second mixing stage.
4. The process according to claim 1 , wherein said admixing comprises at least a first mixing stage and a second mixing stage wherein the first mixing stage comprises admixing:
the one or more rubber components,
the one or more oxidic fillers containing hydroxy groups,
the one or more microgels containing hydroxy groups,
the one or more sulfur-containing organosilicon compounds,
at temperatures of more than 60° C., and
wherein at least 30% by weight of the total amount of the sulfur-containing organosilicon compounds are added, thereby forming a first mixture, and subsequent to said first mixing stage, performing a second mixing stage, wherein at least one further portion of the total amount of the sulfur-containing organosilicon compounds are added to the first mixture and mixed at temperatures of more than 60° C., thereby forming a second mixture.
5. The process according to claim 4 , wherein during said second mixing stage, the entire remaining amount of the sulfur-containing organosilicon compounds are added.
6. The process according to claim 1 , wherein said one or more microgels containing hydroxy groups are added in at least two separate portions.
7. The process according to claim 2 , wherein the addition of the one or more microgels containing hydroxy groups is performed in the first mixing stage and the second mixing stage.
8. The process according to claim 7 , wherein during the second mixing stage, the entire remaining amount of the one or more microgels containing hydroxy groups are added.
9. The process according to claim 2 , wherein the first mixing stage and the second mixing stage are preformed at temperatures of more than 60° C.
10. The process according to claim 2 , wherein the first and second mixtures are cooled between the first and second mixing stages.
11. The process according to claim 2 , wherein during the first mixing stage from 30 to 80% by weight of the sulfur-containing organosilicon compound, based on the total amount of the sulfur-containing organosilicon compound used, are added.
12. The process according to claim 4 , further comprising:
cooling the second mixture, and
subsequent to the second mixing stage, performing a third mixing stage, wherein one or more rubber additives, one or more vulcanization accelerators, and one or more vulcanizing agents, are admixed with the second mixture at temperatures less than 60° C., thereby forming a third mixture.
13. The process according to claim 12 , in which a first part of the one or more microgels containing hydroxy groups is added in the first mixing stage and a second part thereof is added in third mixing stage.
14. The process according to claim 1 ,
wherein the one or more sulfur-containing organosilicon compounds comprise at least two different sulfur-containing organosilicon compounds.
15. A process for the production of a vulcanizate, comprising:
vulcanizing the rubber mixtures obtained according to the process as claimed in claim 1 .
16. The process according to claim 1 , wherein said components further comprise
one or more vulcanizing agents, and
one or more rubber additives.
17. The process according to claim 2 , wherein the first mixing stage and the second mixing stage are preformed at temperatures of more than 100° C.