Coating system
View Patent ↗A coating system is provided that includes an undercoat composition that includes a thermoplastic dispersion. In certain preferred embodiments, the coating system is a multi-coat system that includes the undercoat composition and an overcoat composition that includes a thermoplastic dispersion. In one embodiment, the coating system is suitable for use on a food-contact surface of a food or beverage container.
1. A coated article, comprising:
a twist off cap or lid closure for use in sealing a food or beverage container, comprising:
a metal substrate;
a multi-coat coating formed from a coating system applied to at least a portion of the metal substrate, the coating system comprising:
an overcoat layer formed from an overcoat composition comprising more than 10 wt-% of a polyester polymer, based on the total nonvolatile weight of the overcoat composition, and thermoplastic halogenated polyolefin polymer particles dispersed in an overcoat carrier; and
an undercoat layer formed from an undercoat composition applied to the metal substrate comprising thermoplastic halogenated polyolefin polymer particles dispersed in an undercoat carrier; and
wherein the coating system is substantially free of bound BPA; and
a closure compound applied to the multi-coat coating.
2. The coated article of claim 1 , wherein the coating system is substantially free of oxirane-containing compounds.
3. The coated article of claim 1 , wherein the thermoplastic halogenated polyolefin polymer particles include poly(vinyl chloride).
4. The coated article of claim 3 , wherein the poly(vinyl chloride) is present in an amount from about 10 to about 60 wt-%, based on the total nonvolatile weight of the undercoat composition.
5. The coated article of claim 3 , wherein the poly(vinyl chloride) polymer of the undercoat composition has a number average molecular weight (M n ) of about 50,000 to about 300,000.
6. The coated article of claim 1 , wherein the undercoat composition further comprises a crosslinker.
7. The coated article of claim 1 , wherein the undercoat composition comprises:
from about 10 to about 60 wt-% of the thermoplastic halogenated polyolefin polymer particles, based on the total nonvolatile weight of the undercoat composition;
from about 10 to about 40 wt-% a polyester polymer, based on the total nonvolatile weight of the undercoat composition; and
from about 1 to about 30 wt-% of a crosslinker, based on the total nonvolatile weight of the undercoat composition.
8. The coated article of claim 1 , wherein the undercoat composition comprises:
from about 10 to about 60 wt-% of thermoplastic poly(vinyl chloride) polymer particles;
at least about 5 wt-% of stabilizer; and
at least about 1 wt-% of crosslinker.
9. The coated article of claim 1 , wherein the overcoat thermoplastic polymer comprises a poly(vinyl chloride) polymer.
10. The coated article of claim 1 , wherein the overcoat composition comprises:
from about 10 to about 60 wt-% of the halogenated polyolefin polymer particles, based on the nonvolatile weight of the overcoat composition; and
from more than 10 to about 40 wt-% of the polyester polymer, based on the nonvolatile weight of the overcoat composition;
from about 1 to about 25 wt-% of a crosslinker, based on the nonvolatile weight of the undercoat composition.
11. The coated article of claim 1 , wherein the undercoat composition includes at least 30 wt-% of the thermoplastic halogenated particles, based on the total nonvolatile weight of the undercoat composition.
12. The coated article of claim 1 , wherein the overcoat composition includes at least 20% by weight of a polyester polymer, based on the total nonvolatile weight of the overcoat composition.
13. The coated article of claim 1 , wherein the coating system is substantially free of mobile and bound epoxidized oils and the thermoplastic halogenated polyolefin polymer particles have an average particle size of about 0.1 to about 30 microns.
14. The coated article of claim 1 further comprising a food or beverage container sealed with the twist off cap or lid closure and having a packaged food or beverage product contained therein.
15. A coating system, comprising:
an overcoat composition comprising more than 10% by weight of a polyester polymer, based on the total nonvolatile weight of the overcoat composition, and thermoplastic halogenated polyolefin particles dispersed in an overcoat carrier liquid; and
an undercoat composition comprising:
at least 30 wt-% of halogenated thermoplastic poly(vinyl chloride) polymer particles dispersed in an undercoat carrier liquid;
at least 5 wt-% of a stabilizer;
at least 1 wt-% of a crosslinker; and
less than 40 wt-%, if any, of a polyester polymer;
wherein the above weight percentages are based on the total nonvolatile weight of the undercoat composition, and wherein the coating system comprises a hardenable coating system that is substantially free of bound BPA and oxirane-containing compounds; and
a closure compound.
16. The coating system of claim 15 , wherein when the coating system is tested pursuant to the Corrosion Resistance Test described herein using a 1 week immersion test period in a 40° C. simulant solution of 4.5 w/w % NaCl and 4.5 w/w % acetic acid, the coating system passes the Corrosion Resistance Test.
17. The coating composition of claim 15 , wherein the overcoat composition includes at least 15% by weight of a polyester polymer, based on the total nonvolatile weight of the overcoat composition.
18. A method comprising:
applying an undercoat composition to at least a portion of a metal substrate, the undercoat composition comprising:
from 10 to 60 wt-% of thermoplastic halogenated polyolefin polymer particles dispersed in an undercoat carrier liquid, based on the total nonvolatile weight of undercoat composition,
a stabilizer,
a crosslinker, and
less than 40 wt-%, if any, of a polyester polymer, based on the total nonvolatile weight of the undercoat composition;
drying and at least partially curing the undercoat composition and then applying an overcoat composition to the coated metal substrate, the overcoat composition comprising more than 10% by weight of a polyester polymer, based on the total nonvolatile weight of the overcoat composition, and halogenated thermoplastic polyolefin particles dispersed in an overcoat carrier;
curing the overcoat composition to produce a cured coating system adhered to the metal substrate;
forming a closure, for use in sealing a food or beverage container, from the coated metal substrate including the cured coating system; and
applying a closure compound to the cured coating system of the closure.
19. The method of claim 18 , wherein the overcoat composition includes at least 15% by weight of a polyester polymer, based on the total nonvolatile weight of the overcoat composition.