Thermoplastic molding compound with processing-independent viscosity
The present invention relates to thermoplastic molding compositions comprising a mixture composed of (A) at least one methyl methacrylate polymer, (B) at least one copolymer, obtainable via polymerization of a mixture, composed of (B1) at least one vinylaromatic monomer, and (B2) at least one vinyl cyanide, as monomers, (C) at least one graft polymer, obtainable from a core, and a first graft shell, and a second graft shell, (D) at least one polybutyl acrylate whose molar mass is from 1700 to 4000 g/mol (determined as M w by means of gel permeation chromatography), and (E) if appropriate conventional additives, as component (E), to a process for preparation of these thermoplastic molding compositions, to the use of this thermoplastic molding composition for production of moldings, and also to the use of styrene-methyl methacrylate copolymers whose molar mass is from 1700 to 4000 g/mol (determined as M w by means of gel permeation chromatography) for improvement of flowability and for reduction of the dependency of notched impact strength and haze values of thermoplastic molding compositions on injection-molding conditions.
1. A thermoplastic molding composition, comprising a mixture composed of
(A) at least one methyl methacrylate polymer, obtainable via polymerization of a mixture, composed of
(A1) methyl methacrylate, and
(A2) at least one C 1 -C 8 -alkyl acrylate, as monomers,
as component (A),
(B) at least one copolymer, obtainable via polymerization of a mixture, composed of
(B1) at least one vinylaromatic monomer, and
(B2) at least one vinyl cyanide, as monomers,
as component (B),
(C) at least one graft copolymer, obtainable from
(C1) a core, and
(C2) a first graft shell, obtainable via polymerization of a monomer mixture, composed of
(C21) at least one vinylaromatic monomer,
(C22) at least one C 1 -C 8 -alkyl methacrylate, and
(C23) optionally, at least one crosslinking monomer, as monomers,
and
(C3) a second graft shell, obtainable via polymerization of a monomer mixture, composed of
(C31) at least one C 1 -C 8 -alkyl methacrylate, and
(C32) at least one C 1 -C 8 -alkyl acrylate, as monomers,
as component (C),
(D) at least one polybutyl acrylate whose molar mass is from 1700 to 4000 g/mol (determined as M w by means of gel permeation chromatography),
as component (D), and
(E) optionally, conventional additives, as component (E).
2. The thermoplastic molding composition according to claim 1 , which comprises
an amount of from 20 to 68.9% by weight, based on the entirety of components (A) to (D), of component (A),
an amount of from 20 to 69% by weight, based on the entirety of components (A) to (D), of component (B),
an amount of from 1 to 60% by weight, based on the entirety of components (A) to (D), of component (C),
an amount of from 0.1 to 5% by weight, based on the entirety of components (A) to (D), of component (D), and
an amount of from 0 to 20% by weight, based on the entirety of components (A) to (D), of component (E).
3. The thermoplastic molding composition according to claim 1 , wherein, in component (A), the amount present of (A1) is from 92 to 98% by weight and the amount present of (A2) is from 2 to 8% by weight, based in each case on (A).
4. The thermoplastic molding composition according to claim 1 , wherein, in component (B), the amount present of (B1) is from 75 to 88% by weight and the amount present of (B2) is from 12 to 25% by weight, based in each case on (B).
5. The thermoplastic molding composition according to claim 1 , wherein, in component (C), the amount present of (C1) is from 60 to 90% by weight, the amount present of (C2) is from 5 to 20% by weight, and the amount present of (C3) is from 5 to 20% by weight, based in each case on (C).
6. A process for preparation of a thermoplastic molding composition according to claim 1 via mixing of components (A) to (D) and, optionally, (E) in the melt.
7. The process according to claim 6 , wherein the mixing is carried out at a temperature of from 200 to 300° C.
8. A molding, comprising a thermoplastic molding composition according to claim 1 .
9. A process for production of moldings according to claim 8 via injection molding, blow molding, pressing, calendering, extrusion, vacuum forming, or a combination thereof.
10. A method of producing moldings comprising preparing the thermoplastic molding composition according to claim 1 .
11. A method of improving flowability and reducing of the dependency of notched impact strength and haze values of thermoplastic molding compositions under injection-molding conditions comprising preparing the thermoplastic molding composition according to claim 1 .
12. The thermoplastic molding composition according to claim 2 , wherein, in component (A), the amount present of (A1) is from 92 to 98% by weight and the amount present of (A2) is from 2 to 8% by weight, based in each case on (A).
13. The thermoplastic molding composition according to claim 2 , wherein, in component (B), the amount present of (B1) is from 75 to 88% by weight and the amount present of (B2) is from 12 to 25% by weight, based in each case on (B).
14. The thermoplastic molding composition according to claim 3 , wherein, in component (B), the amount present of (B1) is from 75 to 88% by weight and the amount present of (B2) is from 12 to 25% by weight, based in each case on (B).
15. The thermoplastic molding composition according to claim 2 , wherein, in component (C), the amount present of (C1) is from 60 to 90% by weight, the amount present of (C2) is from 5 to 20% by weight, and the amount present of (C3) is from 5 to 20% by weight, based in each case on (C).
16. The thermoplastic molding composition according to claim 3 , wherein, in component (C), the amount present of (C1) is from 60 to 90% by weight, the amount present of (C2) is from 5 to 20% by weight, and the amount present of (C3) is from 5 to 20% by weight, based in each case on (C).
17. The thermoplastic molding composition according to claim 4 , wherein, in component (C), the amount present of (C1) is from 60 to 90% by weight, the amount present of (C2) is from 5 to 20% by weight, and the amount present of (C3) is from 5 to 20% by weight, based in each case on (C).
18. A process for preparation of a thermoplastic molding composition according to claim 2 via mixing of components (A) to (D) and, optionally, (E) in the melt.
19. A process for preparation of a thermoplastic molding composition according to claim 3 via mixing of components (A) to (D) and, optionally, (E) in the melt.
20. A process for preparation of a thermoplastic molding composition according to claim 4 via mixing of components (A) to (D) and, optionally, (E) in the melt.