Semiconductor light emitting device, backlight, color image display device and phosphor to be used for them
View Patent ↗To provide a semiconductor light emitting device which is capable of accomplishing a broad color reproducibility for an entire image without losing brightness of the entire image. A light source provided on a backlight for a color image display device has a semiconductor light emitting device comprising a solid light emitting device to emit light in a blue or deep blue region or in an ultraviolet region and phosphors, in combination. The phosphors comprise a green emitting phosphor and a red emitting phosphor. The green emitting phosphor and the red emitting phosphor are ones, of which the rate of change of the emission peak intensity at 100° C. to the emission intensity at 25° C., when the wavelength of the excitation light is 400 nm or 455 nm, is at most 40%.
1. A phosphor comprising a crystal phase having a chemical composition represented by the following formula (1′), wherein the proportion of Mn based on the total mols of M IV′ and Mn is at least 0.1 mol % and at most 40 mol %, and the specific surface area is at most 1.3 m 2 /g:
M I′ 2 M IV′ F 6 :R (1′)
wherein M I′ is at least one element selected from the group consisting of K and Na, M IV′ is at least one metal element selected from the group consisting of Groups 4 and 14 of the Periodic Table comprising at least Si, and R is an activated element comprising at least Mn 4+ ,
wherein the phosphor is obtained by precipitation from a solution.
2. The phosphor according to claim 1 , wherein the particle size distribution of said phosphor has one peak value.
3. The phosphor according to claim 1 , wherein the quantile deviation of the particle size distribution is at most 0.6.
4. A process for producing the phosphor according to claim 1 , comprising reacting a solution comprising at least Si and F with a solution comprising at least K, Mn and F to obtain a compound represented by the formula (1′).
5. A process for producing a phosphor comprising a crystal phase having a chemical composition represented by the following formula (1′), comprising mixing at least two types of solutions each comprising at least one element selected from the group consisting of K, Na, Si, Mn and F:
M I′ 2 M IV′ F 6 :R (1′)
wherein M I′ is at least one element selected from the group consisting of K and Na, M IV′ is at least one metal element selected from the group consisting of Groups 4 and 14 of the Periodic Table comprising at least Si, and R is an activated element comprising at least Mn 4+ , and then obtaining the phosphor precipitated by the mixing without adding a poor solvent.
6. A phosphor-containing composition comprising the phosphor according to claim 1 and a liquid medium.
7. The phosphor according to claim 1 , wherein M I′ is K.
8. The phosphor according to claim 1 , wherein M IV′ is Si.
9. The phosphor according to claim 1 , which has a weight-average median diameter D 50 of at least 10 μm and at most 30 μm.
10. The phosphor according to claim 1 , wherein the specific surface area is at most 1.0 m 2 /g.
11. The phosphor according to claim 1 , wherein the quantile deviation of the particle size distribution is at most 0.25.