Hydrogen storage apparatus using porous carbon nanospheres
View Patent ↗Hydrogen is stored by adsorbing the hydrogen to a carbon nanomaterial that includes carbon nanospheres. The carbon nanospheres are multi-walled, hollow carbon nanostructures with a maximum diameter in a range from about 10 nm to about 200 nm. The nanospheres have an irregular outer surface with graphitic defects and an aspect ratio of less than 3:1. The carbon nanospheres can store hydrogen in quantities of at least 1.0% by weight.
1. A hydrogen storage apparatus, comprising:
a vessel comprising a chamber and having an inlet for receiving hydrogen; and
a carbon nanomaterial disposed in the chamber of the vessel so as to be exposed to hydrogen introduced into the chamber through the inlet, the carbon nanomaterial comprising at least 10 wt % multi-walled carbon nanospheres, the carbon nanospheres having an average outer diameter in a range from about 10 nm to about 200 nm, an aspect ratio of less than 3:1, and an irregularly-shaped surface with graphitic defects for increased hydrogen storage capacity.
2. A hydrogen storage apparatus as in claim 1 , wherein the carbon nanomaterial is manufactured by,
forming a precursor mixture comprising a carbon precursor and a plurality of templating nanoparticles, the templating nanoparticles comprising a catalytic metal;
carbonizing the precursor mixture to form an intermediate carbon material comprising a plurality of carbon nanostructures, amorphous carbon, and optionally remaining catalytic metal; and
purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally a portion of any remaining catalytic metal.
3. A hydrogen storage apparatus as in claim 2 , in which the templating nanoparticles are prepared by,
(a) reacting a plurality of precursor catalyst atoms with a plurality of organic dispersing agent molecules to form complexed catalyst atoms; and
(b) allowing or causing the complexed catalyst atoms to form the templating nanoparticles.
4. A hydrogen storage apparatus as in claim 1 , in which the plurality of carbon nanospheres comprises at least about 50 wt % of the carbon nanomaterial.
5. A hydrogen storage apparatus as in claim 1 , in which the plurality of carbon nanospheres comprises at least about 90 wt % carbon nanospheres.
6. A hydrogen storage apparatus as in claim 1 , in which the carbon nanospheres have a BET surface area in a range from about 80 g/m 2 to about 400 g/m 2 .
7. A hydrogen storage apparatus as in claim 1 , in which the carbon nanospheres have a BET surface area in a range from about 120 g/m 2 to about 300 g/m 2 .
8. A hydrogen storage apparatus as in claim 1 , in which the carbon nanospheres have an aspect ratio of less than about 2:1.
9. A hydrogen storage apparatus as in claim 1 , in which the carbon nanospheres have an aspect ratio of less than about 1.5:1.
10. A hydrogen storage apparatus as in claim 1 , in which the carbon nanomaterial comprises a transition metal in a concentration of about 12% to about 0.01%.
11. A hydrogen storage apparatus as in claim 1 , in which the carbon nanospheres have an inner diameter in a range of about 0.5 nm to about 90 nm.
12. A hydrogen storage apparatus as in claim 1 , in which the carbon nanospheres have an inner diameter in a range of about 1 nm and about 50 nm.
13. A hydrogen storage apparatus as in claim 1 , further comprising hydrogen adsorbed onto the carbon nanomaterial in a concentration of at least about 1 wt % of the carbon nanomaterial.
14. A hydrogen storage apparatus as in claim 13 , wherein the hydrogen is under a pressure in a range from 100 atm to about 0.1 atm.
15. A hydrogen storage apparatus as in claim 13 , wherein the hydrogen is under a pressure in a range from 50 atm to about 1 atm.
16. A hydrogen storage apparatus, comprising:
a vessel comprising a chamber and having an inlet for receiving hydrogen;
a carbon nanomaterial disposed in the chamber of the vessel so as to be exposed to hydrogen introduced into the chamber through the inlet, the carbon nanomaterial comprising at least 10 wt % multi-walled carbon nanospheres, the carbon nanospheres having an average outer diameter in a range from about 10 nm to about 200 nm, an aspect ratio of less than 3:1, a BET surface area of at least about 120 g/m 2 , and an irregularly-shaped surface with graphitic defects for increased hydrogen storage capacity; and
hydrogen adsorbed onto the carbon nanomaterial in a concentration of at least about 1 wt % of the carbon nanomaterial.
17. A hydrogen storage apparatus as in claim 16 , wherein the hydrogen is under a pressure in a range from 50 atm to about 1 atm.
18. A hydrogen storage apparatus as in claim 16 , wherein the carbon nanomaterial is manufactured by,
forming a precursor mixture comprising a carbon precursor and a plurality of templating nanoparticles, the templating nanoparticles comprising a catalytic metal;
allowing or causing the carbon precursor to polymerize around the templating nanoparticles;
carbonizing the precursor mixture to form an intermediate carbon material comprising a plurality of carbon nanostructures, amorphous carbon, and optionally remaining catalytic metal; and
purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally a portion of any remaining catalytic metal.
19. A hydrogen storage apparatus as in claim 18 , in which the templating nanoparticles are prepared by,
(a) reacting a plurality of precursor catalyst atoms with a plurality of organic dispersing agent molecules to form complexed catalyst atoms; and
(b) allowing or causing the complexed catalyst atoms to form the templating nanoparticles.
20. A method for manufacturing a hydrogen storage apparatus, comprising,
providing a carbon nanomaterial, the carbon nanomaterial comprising at least 10 wt % multi-walled carbon nanospheres, the carbon nanospheres having an average outer diameter in a range from about 10 nm to about 200 nm, an aspect ratio of less than 3:1, and an irregularly-shaped surface with graphitic defects for increased hydrogen storage capacity; and
introducing the carbon nanomaterial into a vessel comprising a chamber and having an inlet for receiving hydrogen.
21. A method as in claim 20 , further comprising introducing hydrogen into the chamber of the vessel through the inlet and allowing the carbon nanomaterial to adsorb at least 1 wt % hydrogen.
22. A method as on claim 20 , in which the carbon nanospheres have a BET surface area in a range from about 80 g/m 2 to about 400 g/m 2 .
23. A method as in claim 20 , wherein the carbon nanomaterial is manufactured by,
forming a precursor mixture comprising a carbon precursor and a plurality of templating nanoparticles, the templating nanoparticles comprising a catalytic metal;
allowing or causing the carbon precursor to polymerize around the templating nanoparticles;
carbonizing the precursor mixture to form an intermediate carbon material comprising a plurality of carbon nanostructures, amorphous carbon, and optionally remaining catalytic metal; and
purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally a portion of any remaining catalytic metal.
24. A method as in claim 23 , in which the templating nanoparticles are prepared by,
(a) reacting a plurality of precursor catalyst atoms with a plurality of organic dispersing agent molecules to form complexed catalyst atoms; and
(b) allowing or causing the complexed catalyst atoms to form the templating nanoparticles.