Isoolefin-diolefin production process and apparatus therefore
View Patent ↗In an isoolefin-diolefin rubber production process (e.g. a butyl rubber production process), the cold rubber slurry produced in the reaction vessel is transported from the reaction vessel to the flash tank during which time the cold slurry may be expressed to separate at least part of the cold liquid reaction medium from the isoolefin-diolefin rubber. The separated cold liquid reaction medium is transported off stream, for example by a mechanical filter, where it can be recycled back into the reaction vessel and/or where it can be used to cool a feed stream or streams of the reaction components. The isoolefin-diolefin rubber and the residual liquid reaction medium are transported to a flash tank for further processing. The ability to separate and recycle cold liquid reaction medium makes the process more economical. In one aspect, the slurry may be transported from the reaction vessel to the flash tank by a self-cleaning fully intermeshing co-rotating twin screw extruder, which helps overcome the problem of plugging due to rubber sticking to the surfaces of the slurry transfer apparatus.
1. A process for producing an isoolefin-diolefin rubber comprising:
(a) reacting an isoolefin with a diolefin in a liquid non-aqueous reaction medium in a reaction vessel at a temperature in a range of from −110° C. to −50° C. to produce an isoolefin-diolefin rubber in a slurry;
(b) expressing the slurry in a separation zone to separate at least part of the liquid non-aqueous reaction medium from the isoolefin-diolefin rubber;
(c) transporting the separated liquid non-aqueous reaction medium off stream; and,
(d) transporting residual slurry to a slurry processing zone, wherein the processing zone is a flash tank.
2. The process according to claim 1 , further comprising recycling the separated liquid non-aqueous reaction medium.
3. The process according to claim 1 , wherein the slurry being expressed in the separation zone has an initial concentration of isoolefin-diolefin rubber of from 10% to 40% by weight.
4. The process according to claim 1 , wherein the expression of the slurry is accomplished by a fully intermeshing co-rotating twin screw extruder.
5. The process according to claim 4 , wherein separation of the liquid non-aqueous reaction medium is further accomplished by a mechanical filter in fluid communication with the fully intermeshing co-rotating twin screw extruder.
6. The process according to claim 5 , wherein the mechanical filter is a fully-intermeshing counter-rotating twin screw extruder.
7. The process according to claim 1 , wherein the isoolefin-diolefin rubber is butyl rubber.