Process for flocculation of a tailings stream
View Patent ↗A process for the treatment of a tailings stream is provided. The tailings stream comprises water, sand and clay fines and is produced from bitumen extraction process of an oil sands ore. The process for treating the tailings stream comprises contacting a polysilicate microgel, a polyacrylamide and one or both of a multivalent metal compound and a low molecular weight cationic organic polymer with a tailings stream to flocculate sand and clay fines.
1. A process for treating a tailings stream which comprises sand, clay fines and water, the process comprising (a) contacting a polysilicate microgel, an anionic polyacrylamide and one or both of (i) a multivalent metal compound and (ii) a low molecular weight cationic organic polymer with the tailings stream to flocculate the sand and clay fines producing flocculated solids, and (b) separating the flocculated solids from the stream.
2. A process according to claim 1 wherein the tailings stream is a coarse tailings, a fine tailings or a froth treatment tailings produced in a process for extracting bitumen from an oil sands ore.
3. A process according to claim 1 wherein the multivalent metal compound and/or low molecular weight cationic organic polymer is added and then the anionic polyacrylamide is added to the tailings stream.
4. A process according to claim 1 wherein the addition sequence to the tailings stream is (1) a first polymer, which is the anionic polyacrylamide, then (2) a multivalent metal compound and/or low molecular weight cationic organic polymer, and then (3) a second polymer, which is a cationic or anionic polyacrylamide, wherein the polysilicate is added prior to or after additions (1), (2) or (3).
5. A process according to claim 4 wherein the first polymer is an anionic polyacrylamide and the second polymer is a cationic polyacrylamide.
6. A process according to claim 4 wherein polysilicate microgel is added after addition (1).
7. A process according to claim 4 wherein polysilicate microgel is added after addition (2).
8. A process according to claim 4 wherein polysilicate microgel is added after addition (3).
9. A process according to claim 1 wherein a multivalent metal compound is added in step (a) and the multivalent metal is calcium, magnesium, aluminum, iron, titanium, zirconium or a combination of two or more thereof.
10. A process according to claim 9 wherein the multivalent metal compound is calcium chloride, calcium sulfate, calcium hydroxide, aluminum sulfate, magnesium sulfate, aluminum chloride, polyaluminum chloride, polyaluminum sulfate, or aluminum chlorohydrate.
11. A process according to claim 10 wherein the multivalent metal compound is calcium sulfate, aluminum sulfate, polyaluminum sulfate, polyaluminum chloride, or aluminum chlorohydrate.
12. A process according to claim 1 wherein a low molecular weight cationic organic polymer is added in step (a) and the low molecular weight cationic organic polymer is selected from the group consisting of polyethylene imine, polyamines, polycyandiamide formaldehyde polymers, diallyl dimethyl ammonium chloride polymers, diallylaminoalkyl (meth)acrylate polymers, dialkylaminoalkyl (meth)acrylamide polymers, a copolymer of acrylamide and diallyl dimethyl ammonium chloride, a copolymer of acrylamide and diallylaminoalkyl (meth)acrylates, a copolymer of acrylamide and dialkyldiaminoalkyl (meth)acrylamide, and a copolymer of dimethylamine and epichlorohydrin.
13. A process according to claim 1 wherein separating is accomplished by using a thickener, hydrocyclone, or a centrifuge, or by decantation or filtration.