High-clarity ionomer compositions and articles comprising the same
View Patent ↗An ionomer composition comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt %, based on the total weight of the precursor acid copolymer, of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; a melt flow rate of about 10 to about 4000 g/10 min; and, when neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. Further provided are articles comprising the ionomer composition.
1. A precursor acid copolymer comprising:
(A) copolymerized units of ethylene and about 20 to about 30 wt %, based on the total weight of the acid copolymer, of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid and methacrylic acid; wherein
(B) the precursor acid copolymer has a melt flow rate of about 10 to about 4000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein
(C) said precursor acid copolymer, being neutralized to a level of about 40% to about 90% based on the total number of the carboxylic acid groups present in the precursor acid copolymer, produces a sodium ionomer, said sodium ionomer comprising carboxylate groups and counterions, said counterions consisting essentially of sodium cations, and wherein the sodium ionomer has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, as determined by differential scanning calorimetry in accordance with ASTM D3418.
2. An ionomer composition comprising an ionomer that is a neutralized product of the precursor acid copolymer of claim 1 .
3. The ionomer composition of claim 2 , wherein the precursor acid copolymer has a melt flow rate of about 100 to about 500 g/10 min.
4. The ionomer composition of claim 2 , wherein precursor acid copolymer comprises about 20 to about 25 wt % of copolymerized units of the α,β-ethylenically unsaturated carboxylic acid.
5. The ionomer composition of claim 2 , wherein about 40% to about 70% of the carboxylic acid groups present in the precursor acid copolymer have been neutralized by a sodium ion-containing base.
6. The ionomer composition of claim 2 , wherein the ionomer has a melt flow rate of about 1 to about 10 g/10 min.
7. The ionomer composition of claim 2 , wherein the ionomer has a freeze enthalpy that is not detectable.
8. An article comprising the ionomer composition of claim 2 .
9. The article of claim 8 , which is in the form of a film or a sheet or a molded article.
10. The article of claim 9 , which is a film or sheet prepared by a process selected from the group consisting of dipcoating, solution casting, lamination, melt extrusion, blown film, extrusion coating, and tandem extrusion coating.
11. The article of claim 9 , which is a molded article prepared by a process selected from the group consisting of compression molding, injection molding, extrusion molding, and blow molding.
12. The article of claim 11 , which is an injection molded article.
13. The article of claim 12 , having a minimum thickness of at least about 3 mm.
14. The article of claim 12 , wherein the injection molded article has a multi-layer structure having at least one layer that consists essentially of the composition, said at least one layer having a minimum thickness of at least about 1 mm.
15. The article of claim 14 that is a container.
16. The article of claim 12 that is a sheet, a container, a cap or stopper, a tray, a medical device or instrument, a handle, a knob, a push button, a decorative article, a panel, a console box, or a footwear component.
17. The article of claim 12 , which is produced by a process selected from the group consisting of co-injection molding; over-molding; injection blow molding; injection stretch blow molding and extrusion blow molding.
18. An article prepared by injection molding, said article consisting essentially of the ionomer composition of claim 2 and having a thickness of about 1 to about 100 mm.
19. The article of claim 17 that is produced by over-molding and wherein the ionomer has a melt flow rate of from about 0.75 to about 35 g/10 min.
20. The article of claim 17 that is produced by injection blow molding, injection stretch blow molding or extrusion blow molding; wherein the precursor acid copolymer has a melt index of about 200 to about 500 g/10 min; and the ionomer has a melt flow rate of from about 0.75 to about 35 g/10 min.