Hybrid two- and three-component host-guest nanocomposites and method for manufacturing the same
View Patent ↗A hybrid organic-inorganic nanocomposite useful as a cathode in high discharge capacity lithium batteries is provided. The nanocomposite includes macromolecules that are located inside interlayer galleries of V 2 O 5 . These macromolecules include either conducting conjugated polymers or a combination of conducting conjugated polymers and ion conducting polymers. The nanocomposites possess high charge/discharge characteristics. A solvent-free mechanochemical method for the preparation of the hybrid organic-inorganic nanocomposites is also provided.
1. A method for preparing a hybrid two-component nanocomposite comprising a conducting conjugated polymer and vanadium oxide, the method comprising:
a) combining a V 2 O 5 xerogel and monomers of one or more of conducting conjugated polymers to form a reaction mixture; and
b) mechanochemical treatment of the reaction mixture in a ball mill to form the hybrid nanocomposite wherein the V 2 O 5 xerogel is from about 83 to 97 weight percent of the total weight of the reaction mixture.
2. The method of claim 1 wherein the monomers include a component selected from the group consisting of aniline, pyrrole, thiophene, and derivatives thereof, and combinations thereof.
3. The method of claim 1 wherein the reaction mixture subjected to step b) is substantially solvent free.
4. The method of claim 1 wherein the monomers of one or more conducting conjugated polymers is from about 3 to 17 weight percent of the total weight of the reaction mixture.
5. The method of claim 1 wherein the V 2 O 5 xerogel is prepared by evaporating a vanadium oxide sol.
6. The method of claim 1 wherein the conducting conjugated polymer comprises a component selected from the group consisting of polyaniline (“PAn”), polypyrrole (“PPy”), polythiophene (“PTh”), and derivatives thereof, and combinations thereof.
7. The method of claim 5 wherein the vanadium oxide sol is prepared by dissolving crystalline V 2 O 5 in an aqueous hydrogen peroxide solution followed by evaporation of the solution and drying of the V 2 O 5 xerogel until a distance between V 2 O 5 layers is from about 1.14 to about 1.19 nm.
8. A method for preparing a hybrid three-component nanocomposite comprising a conducting conjugated polymer, an ion conducting polymer, and vanadium oxide, the method comprising:
a) combining a V 2 O 5 xerogel and an ion conductive polymer to form a first reaction mixture;
b) mechanochemical treatment of the first reaction mixture in a ball mill to form a first hybrid nanocomposite;
c) combining the first hybrid nanocomposite and a monomer of one or more of conductive polymers to form a second reaction mixture; and
d) mechanochemical treatment of the second reaction mixture in a ball mill to form the hybrid three-component nanocomposite.
9. The method of claim 8 wherein steps b) and d) are each substantially solvent free.
10. The method of claim 8 wherein the V 2 O 5 xerogel is from about 94 to 98 weight percent of the total weight of the first reaction mixture.
11. The method of claim 8 wherein the ion conductive polymer is from about 2 to 6 weight percent of the total weight of the first reaction mixture.
12. The method of claim 8 wherein the monomers of one or more conducting conjugated polymers is from about 3 to 14 weight percent of the total weight of the second reaction mixture.
13. The method of claim 8 wherein the first hybrid nanocomposite is from about 86 to 97 weight percent of the total weight of the second reaction mixture.
14. The method of claim 8 wherein the V 2 O 5 xerogel is prepared by evaporating a vanadium oxide sol.
15. The method of claim 8 wherein the conducting conjugated polymer comprises a component selected from the group consisting of polyaniline (“PAn”), polypyrrole (“PPy”), polythiophene (“PTh”), and derivatives thereof, and combinations thereof.
16. The method of claim 14 wherein the vanadium oxide sol is prepared by dissolving crystalline V 2 O 5 in an aqueous hydrogen peroxide solution followed by evaporation of the solution and drying of the V 2 O 5 xerogel until the distance between V 2 O 5 layers is from about 1.14 to about 1.19 nm.
17. A hybrid nanocomposite comprising:
a conducting polymer selected from the group consisting of conducting conjugated polymers, ion conducting polymer, and combinations thereof and vanadium oxide wherein the nanocomposite is a two-component hybrid and conducting conjugated polymers are present in an amount from about 3 to 17 percent of the total weight of the hybrid nanocomposite.
18. The nanocomposite of claim 17 wherein the nanocomposite is a two-component hybrid and the vanadium oxide is present in an amount from about 83 to 97 percent of the total weight of the hybrid nanocomposite.
19. The nanocomposite of claim 17 wherein the nanocomposite is a three-component hybrid and the ion conducting polymer is present in an amount from about 2 to 6 percent of the total weight of the hybrid nanocomposite.
20. The nanocomposite of claim 17 wherein the nanocomposite is a three-component hybrid and vanadium oxide is present in an amount from about 80 to 95 percent of the total weight of the hybrid nanocomposite.
21. The nanocomposite of claim 17 wherein the nanocomposite is a three-component hybrid and the conducting conjugated polymer is present in an amount from about 3 to 14 percent of the total weight of the hybrid nanocomposite.