Process for preparing high concentrations of magnesium and boron combination materials
View Patent ↗The present invention describes a nanoparticle size composition comprising at least one overbase complex of a magnesium salt and an associated organic boron complex. The present compound is an improvement over previous processes due to less complicated processing requirements and the high concentration of both magnesium and boron that results.
1. A composition comprising a dispersion of alkaline earth metal-boron nano-particles in a hydrocarbon solvent, where the nano-particles include from about 1 wt. % to 8 wt. % boron and from about 10 wt. % to about 25 wt. % magnesium and where the dispersion is clear and bright and where the nano-particles are formed at a temperature of about 100° C. without the removal of solvent or water, where the water performs functions in the composition including insuring that boric acid remains or reforms in the composition when lubricating properties are desired.
2. The composition of claim 1 , wherein the boron is derived from the group consisting of boron powder, boron alkoxides, boric acid, and/or boranes.
3. The composition of claim 1 , wherein the alkaline earth metal is derived from an oil soluble sulfonic or carboxylic acid alkaline earth metal salt.
4. The composition of claim 1 , wherein the composition includes substantially no residue.
5. The composition of claim 3 , wherein the oil soluble sulfonic or carboxylic acid is an oil soluble hydrocarbon acid having a molecular weight of less than 500.
6. The composition of claim 5 , wherein the oil soluble sulfonic acid is a monoalkylbenzene sulfonic acid.
7. The composition of claim 5 , wherein the oil soluble sulfonic acid is dodecylbenzene sulfonic acid.
8. The composition of claim 5 , wherein the oil soluble sulfonic acid is a mixture of monoalkylbenzene and dialkylbenzene sulfonic acids.
9. The composition of claim 1 , wherein a ratio of magnesium to boron is from about 10 to 1 to about 1 to 1.
10. The composition of claim 1 , wherein the ratio of magnesium to boron is from about 4 to 1 to about 3 to 1.
11. The composition of claim 1 , wherein the boron is derived from boric acid.
12. The composition of claim 1 , wherein the hydrocarbon solvent has a boiling point at normal atmospheric pressure of at least about 300° F. and a flash point of at least 100° F.
13. The composition of claim 1 , wherein the alkaline earth metal is a magnesium sulfonic acid salt.
14. The composition of claim 1 , wherein the alkaline earth metal is a mixture of a magnesium monoalkylbenzene sulfonic acid salt and a magnesium dialkylbenzene sulfonic acid salt.
15. The composition of claim 3 , wherein the oil soluble caboxylic acid is a mixture of linear and cyclic carboxylic acids.
16. The composition of claim 3 , wherein the oil soluble carboxylic acid is a mixture of fatty acids.
17. The composition of claim 1 , wherein the alkaline earth metal is a magnesium carboxylic acid salt.
18. The composition of claim 1 , wherein the alkaline earth metal is a is a mixture of magnesium fatty acid salts.
19. A method for prepare a dispersion of nano-particles comprising:
contacting a boron donor and an oil soluble alkaline earth metal sulfonic acid salt and/or carboxylic acid salt in the presence of a hydrocarbon solvent for a time and at a temperature to produce a clear, bright dispersion of alkaline earth metal-boron nano-particles in a hydrocarbon solvent, where the nano-particles include from about 1 wt. % to 8 wt. % boron and from about 10 wt. % to about 25 wt. % magnesium without the removal of solvent or water, where the water performs functions in the composition including insuring that boric acid remains or reforms in the composition when lubricating properties are desired.
20. A fuel composition comprising a fuel and an effective amount of a clear, bright dispersion of alkaline earth metal-boron nano-particles in a hydrocarbon solvent, where the nano-particles include from about 1 wt. % to 8 wt. % boron and from about 10 wt. % to about 25 wt. % magnesium and where the nano-particles are formed at a temperature of about 100° C. without the removal of solvent or water, where the water performs functions in the composition including insuring that boric acid remains or reforms in the composition when lubricating properties are desired, and where the effective amount is sufficient to improve fuel efficiency and lubricity.
21. A lubricating composition comprising a lubricant and an effective amount of a clear, bright dispersion of alkaline earth metal-boron nano-particles in a hydrocarbon solvent, where the nano-particles include from about 1 wt. % to 8 wt. % boron and from about 10 wt. % to about 25 wt. % magnesium and where the nano-particles are formed at a temperature of about 100° C. without the removal of solvent or water, where the water performs functions in the composition including insuring that boric acid remains or reforms in the composition when lubricating properties are desired, and where the amount is sufficient to improve lubricity.