Dispersions comprising hydroxyphenylpyruvate dioxygenase inhibitors
View Patent ↗The present invention relates to dispersions comprising A) one or more herbicidal active substances from the group of the HPPD inhibitors, B) one or more oils, C) one or more surface-active substances, D) diammonium oxalate, diammonium hydrogen phosphate or ammonium dihydrogen phosphate, E) one or more rheological additives, F) optionally one or more agrochemical active substances other than A), such as herbicides, insecticides, fungicides, safeners or growth regulators, G) optionally formulation auxiliaries from the group consisting of antifoams, evaporation inhibitors, perfumes, colorants, antifreeze agents and preservatives. The dispersions are suitable for use in the field of plant protection.
1. A dispersion comprising
A) 1 to 25% of one or more herbicidal active substances from the group of the hydroxyphenylpyruvate dioxygenase(HPPD) inhibitors,
B) 10 to 90% of one or more vegetable or mineral oils,
C) 0.5 to 40% of one or more surface-active substances,
D) 2 to 75% of diammonium oxalate, diammonium hydrogen phosphate or ammonium dihydrogen phosphate,
E) 0.1 to 4% of one or more rheological additives,
F) 0 to 20% of one or more agrochemical active substances other than A),
G) 0 to 5% of the formulation auxiliaries selected from the group consisting of antifoams, evaporation inhibitors, perfumes, colorants, antifreeze agents and preservatives.
2. The dispersion as claimed in claim 1 , comprising
A) 2 to 15% of one or more herbicidal active substances from the group of the HPPD inhibitors,
B) 10 to 80% of one or more vegetable or mineral oils,
C) 5 to 30% of one or more surface-active substances,
D) 4 to 45% of diammonium oxalate, diammonium hydrogen phosphate or ammonium dihydrogen phosphate,
E) 0.1 to 4% of one or more rheological additives,
F) 1 to 10% of one or more agrochemical active substances other than A), selected from the group consisting of herbicides, insecticides, fungicides, safeners or growth regulators,
G) 0 to 5% of formulation auxiliaries selected from the group consisting of antifoams, evaporation inhibitors, perfumes, colorants, antifreeze agents and preservatives.
3. The dispersion as claimed in claim 1 , wherein the HPPD inhibitors are selected from the group consisting of benzobicyclon, isoxaflutole, mesotrione, pyrasulfotole, pyrazolynate, sulcotrione, tefuryltrione, tembotrione, topramezone and 3-({2-[(2-methoxyethoxy)methyl]-6-(trifluoromethyl)pyridin-3-yl}carbonyl)bicyclo [3.2.1]octane-2,4-dione.
4. The dispersion as claimed in claim 3 , comprising, as herbicidal active substance, tembotrione.
5. The dispersion as claimed in claim 1 , comprising, as component D), ammonium dihydrogen phosphate.
6. The dispersion as claimed in claim 1 , comprising, wherein F) is present and comprises isoxadifen-ethyl.
7. A liquid herbicidal composition, obtainable by diluting the dispersion as claimed in claim 1 .
8. A method of controlling undesired vegetation, comprising applying an effective amount of the dispersion as claimed in claim 1 to plants, parts of the plants, plant seed or the area in which plants grow.
9. The method of controlling undesired vegetation according to claim 8 , wherein said effective amount of a dispersion is from 0.5 and 5.0 liters per hectare.
10. The method of controlling undesired vegetation according to claim 9 , wherein said effective amount of a dispersion is from 1.0 and 4.0 liters per hectare.
11. The method of controlling undesired vegetation according to claim 8 , wherein the ratio of the dispersion to water is from about 1:500 to 1:50.
12. The method of controlling undesired vegetation according to claim 8 , wherein application is an aerial application.
13. The dispersion according to claim 1 , wherein said one or more herbicidal active substances is tembotrione and said one or more vegetable or mineral oils is a rapeseed oil methyl ester.
14. The dispersion according to claim 1 , wherein said one or more vegetable or mineral oils is selected from the group consisting of soybean oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil, castor oil, rapeseed oil transesterification products, and rapeseed oil methyl esters.
15. The dispersion according to claim 1 , wherein said one or more vegetable or mineral oils is selected from the group consisting of a rapeseed oil methyl ester and C6-C16 aromatic mixtures having boiling point ranging from 219 degree C. to 282 degree C.
16. The dispersion according to claim 1 , wherein said one or more surface-active substances is a surfactant.
17. The dispersion according to claim 1 , wherein said one or more surface-active substances is selected from the group consisting of calcium sulfonate, ethoxylated castor oil with 40 ethylene oxide units and nonionic surfactant based on ethoxylated isotridecanol-polyglycol ether.
18. The dispersion according to claim 1 , wherein said component F) is present in an amount of from 1% to 10%.
19. The dispersion according to claim 1 , wherein said component G) is present and selected from the group consisting of consisting of antifoams, evaporation inhibitors, perfumes, colorants, antifreeze agents and preservatives.
20. The dispersion according to claim 1 comprising
A) 1 to 25% of tembotrione;
B) 10 to 90% of rapeseed oil methyl ester;
C) 0.5 to 40% of one or more surfactants;
D) 2 to 75% of ammonium dihydrogen phosphate;
E) 0.1 to 4% of one or more rheological additives;
F) 0 to 20% of one or more agrochemical active substances other than A), and
G) 0 to 5% of the formulation auxiliaries selected from the group consisting of antifoams, evaporation inhibitors, perfumes, colorants, antifreeze agents and preservatives.