IP Library Granted Patent US 9,118,020
Granted Patent B2
US 9,118,020 · App. 12/633,991 · Granted Aug 25, 2015

Electroluminescent devices including organic eil layer

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Quick Facts
Patent No.
US 9,118,020
App. No.
12/633,991
Granted
Aug 25, 2015
Kind
B2
Abstract

An OLED device comprises a cathode, an anode, and has therebetween a light emitting layer (LEL) comprising a phosphorescent emitting compound disposed in a host comprising a mixture of at least one electron transporting co-host which is a benzophenone derivative with a spiro substituent and at least one hole transporting co-host which is a triphenylamine which contains one trivalent nitrogen atom that is bonded only to carbon atoms, at least one of which is a member of an aromatic ring, wherein there is present an electron transporting layer contiguous to the LEL (HBL?) on the cathode side comprising an anthracene or a fluoranthene and wherein there is present an election injecting layer comprising a phenanthroline or a lithium quinolate contiguous to the cathode.

Claims (27)

1. An OLED device comprising a cathode, an anode, and having therebetween a light emitting layer (LEL) comprising a phosphorescent emitting compound disposed in a host comprising a mixture of at least one electron transporting co-host represented by

wherein:

m is an integer from 0 to 5;

each x is an integer from 0 to 4;

y is an integer from 0 to 3;

R 2 and R 3 are independently selected from hydrogen; alkyl of from 1 to 24 carbon atoms, aryl or hetero-atom substituted aryl of from 5 to 20 carbon atoms, halo, or atoms necessary to complete a fused aromatic ring;

and at least one hole transporting co-host represented by

wherein there is present an electron transporting layer contiguous to the LEL on the cathode side and

wherein there is present an electron-injection layer (EIL) containing a heteroaromatic compound contiguous to the cathode;

wherein the electron transporting layer comprises an aromatic hydrocarbon material selected from:

an anthracene represented by:

wherein

Ar 9 and Ar 10 independently represent an aryl group;

v 1 , v 2 , v 3 , v 4 , v 5 , v 6 , v 7 , and v 8 independently represent hydrogen or a substituent; and

a fluoranthene represented by:

wherein

each R 1 is independently selected from alkyl, aryl, and heteroaryl groups;

R 2 through R 7 are independently selected from H, alkyl, phenyl, cyano and alkoxy groups; and

n is an integer selected from 0 to 4;

wherein the electron-injection layer comprises a heteroaromatic compound selected from:

wherein

each R 5 is independently selected from hydrogen, alkyl, aryl groups and at least one of R 5 is aryl or substituted aryl; and

wherein

M is Li;

R 8 and R 9 are independently selected substituent groups, provided adjacent substituents may combine to form ring groups;

h and i are independently integers from 0 to 3; and

j is an integer from 1 to 6.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 5, 2011
From: BEGLEY, WILLIAM J.
To: GLOBAL OLED TECHNOLOGY LLC
Reel/Frame 026233/0048 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 11, 2010
From: EASTMAN KODAK COMPANY
To: GLOBAL OLED TECHNOLOGY LLC
Reel/Frame 024068/0468 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 9, 2009
From: KONDAKOVA, MARINA E.; KONDAKOV, DENIS Y.; BROWN, CHRISTOPHER T.; HATWAR, TUKARAM K.; SPINDLER, JEFFREY P.
To: EASTMAN KODAK COMPANY
Reel/Frame 023626/0581 →