Tar-free gasification system and process
View Patent ↗A novel tar-free gasification process and system is disclosed that involves the partial combustion of recycled dry solids and the drying of a slurry feedstock comprising carbonaceous material in two separate reactor zones in a two stage gasifier, thereby producing mixture products comprising synthesis gas. The synthesis gas produced from the high temperature first stage reaction zone is then quenched in the second stage reaction zone of the gasifier prior to introduction of a slurry feedstock. The temperature of the final syngas exiting the second stage reaction zone of the gasifier is thereby moderated to be in the range of about 350-900° F., which is below the temperature range at which tar is readily formed, depending upon the type of carbonaceous feedstock utilized.
1. A process for the gasification of a carbonaceous material, comprising the steps of:
a. introducing a dry feedstock into a reactor lower section and partially combusting therein with a gas stream comprising an oxygen-containing gas or steam to evolve heat and form products comprising hot synthesis gas and molten slag;
b. passing said synthesis gas from step a) upward into a reactor upper section and injecting at least one cooling agent into said reactor upper section, wherein said hot synthesis gas from step a) transfers heat to said at least one cooling agent, thereby producing a cooled synthesis gas;
c. introducing a slurry of particulate carbonaceous material in a liquid carrier into said reactor upper section downstream from the point of injecting the cooling agent of step b), and drying the slurry with said cooled synthesis gas from step b) in said reactor upper section to form mixture products comprising a dry solid stream and a gaseous stream, wherein said drying occurs at a temperature that prevents the formation of tar and is below the temperature at which tar is formed, thereby producing a tar-free gaseous stream, wherein the temperatire of said reactor upper section after step b) and prior to step c) is maintained between 600° F and 2000° F and at a pressure in a range of 14.7 psig to 2000 psig;
d. passing said mixture products through a separating device, wherein said dry solid stream is separated from said tar-free gaseous stream; and
e. recycling said dry solid stream back to said reactor lower section, wherein said dry solid stream comprises ash, char, and dried carbonaceous solid particles formed in the unfired reactor upper section, and wherein said dry solid stream is used as dry feedstock for said reactor lower section.
2. The process of claim 1 , wherein step a) is carried out at a temperature in a range of 1500° F. and 3500° F. and at a pressure in a range of 14.7 psig to 2000 psig.
3. The process of claim 1 wherein step a) is carried out at a temperature in a range of 2000° F. and 3200° F. and at a pressure in a range of 50 psig to 1500 psig.
4. The process of claim 1 , wherein the temperature of said reactor upper section after step b) and prior to step c) is maintained between 800° F. and 1800° F. and at a pressure in a range of 50 psig to 1500 psig.
5. The process of claim 1 , wherein said cooling agent is selected from a group consisting of water, recycled syngas, and any mixture thereof.
6. The process of claim 1 , wherein said gas stream comprising an oxygen-containing gas or steam is introduced into said reactor lower section at a feeding rate in a range of 20 to 120 feet per second, and wherein the residence time of said dry feedstock in said reactor lower section is in a range of 2 to 10 seconds.
7. The process of claim 1 , wherein said gas stream comprising an oxygen-containing gas or steam is introduced into said reactor lower section at a feeding rate in a range of 20 to 90 feet per second, and wherein the residence time of said dry feedstock in said reactor lower section is in a range of 4 to 6 seconds.
8. The process of claim 1 , wherein said slurry comprising particulate carbonaceous material in said liquid carrier is introduced into said reactor upper section at a feeding rate in a range of 10 to 80 feet per second, and wherein the residence time of said slurry in said reactor upper section is in a range of 5 to 40 seconds.
9. The process of claim 1 , wherein said cooling agent is introduced into said reactor upper section at a feeding rate in a range of 10 to 120 feet per second.
10. The process of claim 1 , wherein said liquid carrier is selected from group consisting of water, liquid CO 2 , petroleum liquid and any mixtures thereof.
11. The process of claim 1 , wherein said particulate carbonaceous material is selected from group consisting of coal, lignite, petroleum coke and any mixtures thereof.
12. The process of claim 1 , wherein said slurry comprising particulate carbonaceous material has a solids concentration from 30 to 75 percent by weight based upon the total weight of said slurry.
13. The process of claim 1 , wherein said slurry comprising particulate carbonaceous material has a solids concentration from 45 to 70 percent by weight based upon the total weight of said slurry.
14. The process of claim 1 , wherein said oxygen-containing gas is selected from a group consisting of air, oxygen-enriched air, oxygen and any mixtures thereof.
15. The process of claim 1 , further comprising a step of passing said gaseous product stream through a particulate filtering device, whereby residual solid fines and particulates are separated from said gaseous product stream.
16. The process of claim 1 , wherein the temperature of said mixture products exiting reactor upper section, prior to entering said separation device, is between 300° F. and 1200° F.
17. The process of claim 1 , wherein the temperature of said mixture products exiting reactor upper section, prior to entering said separation device, is between 400° F. and 600° F.
18. The process of claim 1 , wherein said dry feedstock comprises recycled char, ash, and dried carbonaceous solid particles.
19. The process of claim 1 , wherein said solid stream comprises recycled char, ash, and dried carbonaceous solid particles, and wherein said gaseous stream comprises synthesis gas and molten slag.