Aqueous-triggered color-appearing inks
View Patent ↗The invention describes a color-developing composition that contains at least four major components: (1) a leuco dye or a combination of leuco dyes, (2) an electron-withdrawing color-developer agent or a combination of color-developers that can form colored complexes with the leuco dyes, (3) a separator or combination of separators that when present in sufficient amounts, can prevent the formation of the colored complexes between the color-developer and leuco dyes, all contained within (4) an encapsulation matrix that includes at least one film-forming and one aqueous-insoluble polymer. All of the foregoing components are dissolved together in a volatile organic solvent medium to form a homogeneous solution that can be applied as an ink on substrates, which can be incorporated as part of absorbent articles or personal care products.
1. A colorless or pale-colored, non-aqueous-based, homogeneous solution comprising: a) one or more leuco dyes; b) one or more separators that are non-volatile and soluble in both volatile organic solvents and water; c) one or more electron withdrawing color-developers that cannot form colored complexes with said leuco dyes in the presence of said separators without the presence of water, but can form colored complexes with the leuco dyes in the presence of water; wherein the solution is in a water-pervious, organic polymeric cage that comprises at least one polymer that is soluble in volatile organic solvents.
2. The homogenous solution according to claim 1 , wherein said polymeric cage comprises a polymeric resin.
3. The homogeneous solution according to claim 1 , wherein said composition includes one or more volatile organic solvents.
4. The homogeneous solution according to claim 1 , wherein said one or more leuco dyes are present from about 0.01 wt. % to about 10 wt. %; said one or more separators are present from about 1 wt. % to about 25 wt. %; said one or more developers are present from about 0.5 wt. % to about 12 wt. %.
5. The homogeneous solution according to claim 1 , wherein a polymeric resin is present from about 10 wt. % to about 80 wt. %.
6. The homogeneous solution according to claim 1 , wherein said one or more volatile organic solvents are present from about 20 wt. % to about 90 wt. %.
7. The homogeneous solution according to claim 1 , wherein said leuco dyes are selected from phthalide leuco dyes, triarylmethane leuco dyes, and fluoran leuco dyes.
8. The homogeneous composition according to claim 1 , wherein said separators include neutral components that are without a charge.
9. The homogeneous solution according to claim 8 , wherein said separators are selected from the group consisting of polyalkylene glycol of <1000 Daltons, polyalkylene oxide of <10000 Daltons, block copolymers of polyoxyehtylene polyoxypropylene glycol, polyoxyehtylene nonylphenyl ether, polyoxyethylene distyrenated phenyl ether, and neutral surfactants.
10. The homogeneous solution according to claim 1 , wherein said color-developers are selected from the group consisting of bisphenol A, zinc chloride, zinc salicylate, and phenol resins.
11. The homogeneous solution according to claim 1 , wherein volatile organic solvents are selected from the group consisting of ethanol, methanol, propanol, isopropanol, butanol, acetone, tetrahydrofuran (THF), benzene and toluene, methylene chloride, chloroform, and combinations thereof.