Capture of volatilized vanadium and tungsten compounds in a selective catalytic reduction system
View Patent ↗An apparatus and method for treating diesel exhaust gases are described. The system consists of two functionalities, the first being a selective catalytic reduction (SCR) catalyst system and the second being a capture material for capturing catalyst components that have appreciable volatility under extreme exposure conditions. The SCR catalyst component is typically based on a majority phase of titania, with added minority-phase catalyst components comprising of one or more of the oxides of vanadium, silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper and/or manganese vanadia. The capture material typically comprises a majority phase of high surface area oxides such as silica-stabilized titania, alumina, or stabilized alumina, for example, wherein the capture material maintains a low total fractional monolayer coverage of minority phase oxides for the duration of the extreme exposure. The method involves treatment of hot exhaust streams by both the catalyst material and capture material, wherein the capture material can be in a mixture with the catalyst material, or can be located downstream thereof, or both, but still be maintained at the extreme temperatures. Volatile catalyst components such as vanadia are thus removed from the vapor phase of the exhaust gas.
1. A selective catalytic reduction catalyst system, comprising:
a catalyst bed material having a majority phase containing titania, and a minority phase which includes a catalyst component comprising a vanadium oxide; and
a capture bed material, wherein volatile metal oxides or volatile metal hydroxides originating from the catalyst bed material are captured by the capture bed material and are maintained at a total fractional monolayer coverage on the capture bed material of 3.1 or less when the capture bed material is exposed to conditions of 750° C. for 4 hours at a gas-hourly space velocity of 100,000 hr −1 and 5 vol % water.
2. The selective catalytic reduction catalyst system of claim 1 , wherein the minority phase catalyst components of the catalyst bed material are maintained at a total fractional monolayer value of 5 or less on the majority phase of the catalyst bed material after exposure of the catalyst bed material to conditions of 750° C. for 4 hours at a gas-hourly space velocity of 100,000 hr −1 and 5 vol % water.
3. The selective catalytic reduction catalyst system of claim 1 , wherein the capture bed material is able to capture substantially all volatile metal oxides or volatile metal hydroxides originating from the catalyst bed material.
4. The selective catalytic reduction catalyst system of claim 1 , wherein the capture bed material includes at least one compound selected from the group consisting of aluminas, stabilized aluminas, silicas, silica-aluminas, amorphous silicas, titanias, silica-stabilized titanias, zeolites molecular sieves, and combinations thereof.
5. The selective catalytic reduction catalyst system of claim 4 , wherein the stabilized aluminas are stabilized by lanthanum or other lanthanides.
6. The selective catalytic reduction catalyst system of claim 1 , wherein the capture bed material includes silica-stabilized titania and the majority phase of the catalyst bed material includes silica-stabilized titania.
7. A diesel engine exhaust treatment system, comprising:
a selective catalytic reduction catalyst system having a catalyst bed material containing a majority phase containing titania, and a minority phase which includes a catalyst component comprising a vanadium oxide; and
a capture bed material, wherein volatile metal oxides or volatile metal hydroxides originating from the catalyst bed material are captured by the capture bed material and are maintained at a total fractional monolayer coverage on the capture bed material of 3.1 or less when exposed to conditions of 750° C. for 4 hours at a gas-hourly space velocity of 100,000 hr −1 and 5 vol % water; and
a diesel particulate filter.
8. The diesel engine exhaust treatment system of claim 7 , wherein the minority-phase catalyst components of the catalyst bed material of the selective catalytic reduction catalyst system are maintained at a total fractional monolayer value of 5 or less on the majority phase of the catalyst bed material after exposure to conditions of 750° C. for 4 hours at a gas-hourly space velocity of 100,000 hr −1 and 5 vol % water.
9. The diesel engine exhaust treatment system of claim 7 , wherein the capture bed material of the selective catalytic reduction catalyst system is able to capture substantially all volatile metal oxides or volatile metal hydroxides originating from the catalyst bed material.
10. The diesel engine exhaust treatment system of claim 7 , wherein the capture bed material of the selective catalytic reduction catalyst system includes at least one compound selected from the group consisting of aluminas, stabilized aluminas, silicas, silica-aluminas, amorphous silicas, titanias, silica-stabilized titanias, zeolites, molecular sieves, and combinations thereof.
11. The diesel engine exhaust treatment system of claim 10 , wherein the stabilized aluminas are stabilized by lanthanum or other lanthanides.
12. The diesel engine exhaust treatment system of claim 7 , wherein the capture bed material includes silica-stabilized titania and the majority phase of the catalyst bed material of the selective catalytic reduction catalyst system includes silica-stabilized titania.
13. The selective catalytic reduction catalyst system of claim 1 , wherein the capture bed material is located downstream of the catalyst bed material.
14. The selective catalytic reduction catalyst system of claim 1 , wherein the catalyst component of the minority phase includes at least one oxide selected from the group consisting of oxides of silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper, manganese, and combinations thereof.
15. The diesel engine exhaust treatment system of claim 7 , wherein the capture bed material of the selective catalytic reduction catalyst system is positioned downstream of the catalyst bed material.
16. The diesel engine exhaust treatment system of claim 7 , wherein the catalyst component of the minority phase of the catalyst bed material includes an oxide selected from the group consisting of oxides of silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper, manganese, and combinations thereof.