Method and apparatus for tunable electrical conductivity
View Patent ↗An embodiment relates a method comprising creating a reversible change in an electrical property by adsorption of a gas by a composition, wherein the composition comprises a noble metal-containing nanoparticle and a single walled carbon nanotube. Another embodiment relates to a method comprising forming a composition comprising a noble metal-containing nanoparticle and a single walled carbon nanotube and forming a device containing the said composition. Yet another method relates to a device comprising a composition comprising a noble metal-containing nanoparticle and a single walled carbon nanotube on a silicon wafer, wherein the composition exhibits a reversible change in an electrical property by adsorption of a gas by the composition.
1. A method comprising:
providing a semiconducting composite comprising single-walled carbon nanotubes and metal nanoparticles comprising a noble metal;
adsorbing a gas to the semiconducting composite to form a metallic composite, wherein the gas comprises hydrogen gas or helium gas;
applying a voltage to the metallic composite such that a first electrical current flows in the metallic composite;
desorbing the gas from the metallic composite to form the semiconducting composite; and
applying about the same voltage to the semiconducting composite such that a second electrical current flows in the semiconducting composite wherein the first electrical current is greater than the second electrical current.
2. The method of claim 1 , wherein the gas comprises hydrogen gas.
3. The method of claim 2 , wherein adsorbing the gas to the semiconducting composite to form the metallic composite comprises exposing the composite to a partial pressure of the hydrogen gas of at least about 100 torr.
4. The method of claim 1 , wherein the gas comprises helium gas.
5. The method of claim 1 , wherein the noble metal comprises at least one of gold or silver.
6. The method of claim 1 , wherein the metal nanoparticles have an average diameter from about 1 nm to about 100 nm.
7. The method of claim 1 , wherein desorbing the gas from the metallic composite to form the semiconducting composite comprises applying a vacuum to the metallic composite.
8. The method of claim 7 , wherein applying the vacuum comprises applying a pressure of about 10 −2 torr.
9. The method of claim 1 , wherein the semiconducting composite is disposed on a silicon wafer.
10. The method of claim 9 , wherein the semiconducting composite is electrically coupled to a pair of conductive pads on opposing sides of the semiconducting composite.
11. The method of claim 10 , wherein applying the voltage to the metallic composite such that the first electrical current across the metallic composite comprises applying the voltage to the pair of conductive pads.
12. The method of claim 1 , wherein the semiconducting composite is disposed in a sealed chamber.
13. A method comprising:
providing a semiconducting composite comprising single-walled carbon nanotubes and metal nanoparticles comprising a noble metal;
adsorbing an amount of gas into the semiconducting composite to form a metallic composite, wherein the amount of gas adsorbed into the composite is effective to reversibly change an electrical property of the composite from a semiconducting property to a metallic property;
applying a voltage to the metallic composite;
desorbing the gas from the metallic composite to form a semiconducting composite; and
applying a voltage to the semiconducting composite.
14. The method of claim 13 , wherein the gas is configured to adsorb within interstitial channels between the single-walled carbon nanotubes in the composite.
15. The method of claim 14 , wherein the gas comprises hydrogen gas.
16. The method of claim 13 , wherein the semiconducting composite is disposed on a silicon wafer.
17. The method of claim 13 , wherein the semiconducting composite is electrically coupled to a pair of conductive pads on opposing sides of the semiconducting composite.
18. The method of claim 13 , wherein the semiconducting composite is disposed in a sealed chamber.
19. The method of claim 13 , wherein the noble metal is gold.
20. The method of claim 13 , wherein the noble metal is silver.