IP Library Granted Patent US 8,039,290
Granted Patent B2
US 8,039,290 · App. 12/639,099 · Granted Oct 18, 2011

Method of making photovoltaic cell

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Quick Facts
Patent No.
US 8,039,290
App. No.
12/639,099
Granted
Oct 18, 2011
Kind
B2
Abstract

Methods of making a photovoltaic (PV) cell are disclosed. The methods comprise at least the steps of, providing a first component comprising a cadmium telluride (CdTe) layer comprising an interfacial region, and subjecting the first component to a functionalizing treatment in the presence of a material comprising copper.

Claims (52)

1. A method of making a photovoltaic (PV) cell, said method comprising the steps of:

(a) providing a first component comprising a cadmium telluride (CdTe) layer comprising an interfacial region;

(b) subjecting the first component to a functionalizing treatment to obtain a first green component, said functionalizing treatment comprising treating at least a portion of the interfacial region with a first material comprising copper and a second material comprising chlorine;

(c) subjecting the first green component to a first annealing treatment to obtain a second green component;

(d) subjecting the second green component to a processing treatment; and

(e) disposing a second component adjacent the CdTe layer to form the PV cell.

2. The method of claim 1 , wherein the processing treatment comprises a soaking treatment.

3. The method of claim 2 , the soaking treatment comprises the use of a solvent comprising ethylene di-amine (EDA).

4. The method of claim 1 , wherein the processing treatment comprises deposition of a copper layer on at least a portion of the interfacial region.

5. The method of claim 1 , wherein the processing treatment comprises a second annealing treatment.

6. The method of claim 1 , wherein the first component comprises a layer comprising a transparent conducting oxide.

7. The method of claim 6 , wherein the transparent conducting oxide comprises aluminum doped zinc oxide, indium tin oxide, fluorine tin oxide, cadmium tin oxide, or combinations thereof.

8. The method of claim 1 , wherein the first component comprises a layer comprising a high resistance oxide.

9. The method of claim 8 , wherein the high resistance oxide comprises zinc tin oxide, aluminum oxide, tin oxide, gallium oxide, silicon oxide, indium oxide, or combinations thereof.

10. The method of claim 1 , wherein the first component comprises a layer comprising cadmium sulphide.

11. The method of claim 1 , wherein the second component comprises a back-contact layer.

12. The method of claim 11 , wherein the back-contact layer comprises a plurality of layers.

13. The method of claim 12 , wherein each of the plurality of layers is disposed sequentially adjacent the CdTe layer.

14. The method of claim 1 , wherein disposing the second component is performed via a deposition method comprising at least one of screen printing, sputtering, evaporating, electroplating, electrodepositing, or combinations thereof.

15. The method of claim 1 , wherein the second material comprises cadmium chloride.

16. The method of claim 1 , wherein a ratio of an amount of the first material to an amount of the second material lies within the range from about 0.01 ppm to about 100 ppm.

17. The method of claim 1 , wherein the first annealing treatment is performed at temperatures that lie within a range from about 300° C. to about 500° C.

18. The method of claim 1 , wherein the first annealing treatment is performed for a time-period that lies within a range from about 1 minute to about 60 minutes.

19. The method of claim 1 , wherein an environment of the first green component during the first annealing treatment comprises an oxidizing environment.

20. The method of claim 1 , wherein the CdTe layer is rendered substantially p-type after step (c).

21. A method for making a photovoltaic cell, said method comprising the steps of:

(a) providing a first component comprising a cadmium telluride (CdTe) layer comprising an interfacial region;

(b) subjecting the first component to a functionalizing treatment to obtain a first green component, said functionalizing treatment comprising soaking at least a portion of the interfacial region in the presence of a first solution comprising copper;

(c) subjecting the first green component to a first annealing treatment in the presence of a second solution comprising chlorine to obtain a second green component;

(d) subjecting the second green component to a processing treatment; and

(e) disposing a second component adjacent the CdTe layer to form the photovoltaic cell.

22. The method of claim 21 , wherein the processing treatment comprises a soaking treatment.

23. The method of claim 22 , the soaking treatment comprises the use of a solvent comprising EDA.

24. The method of claim 21 , wherein the processing treatment comprises deposition of a copper layer on at least a portion of the interfacial region.

25. The method of claim 21 , wherein the processing treatment comprises a second annealing treatment.

26. The method of claim 21 , wherein the first solution comprises an a solvent.

27. The method of claim 26 , wherein the solvent comprises EDA.

28. The method of claim 21 , wherein the first component comprises a layer comprising a transparent conducting oxide.

29. The method of claim 28 , wherein the transparent conducting oxide comprises aluminum doped zinc oxide, indium tin oxide, fluorine tin oxide, cadmium tin oxide, or combinations thereof.

30. The method of claim 29 , wherein the first component comprises a layer comprising a high resistance oxide.

31. The method of claim 30 , wherein the high resistance oxide comprises zinc tin oxide, aluminum oxide, tin oxide, gallium oxide, silicon oxide, indium oxide, or combinations thereof.

32. The method of claim 21 , wherein the first component comprises a layer comprising cadmium sulphide.

33. The method of claim 21 , wherein the second component comprises a back-contact layer.

34. The method of claim 33 , wherein the back-contact layer comprises a plurality of layers.

35. The method of claim 34 , wherein each of the plurality of layers is disposed sequentially adjacent the CdTe layer.

36. The method of claim 21 , wherein disposing the second component is performed via a deposition method comprising at least one of screen printing, sputtering, evaporating, electroplating, electrodepositing, or combinations thereof.

37. The method of claim 21 , wherein the second solution comprises cadmium chloride.

38. The method of claim 21 , wherein a concentration of the copper within the first solution lies within the range from about 0.01 ppm to about 100 ppm.

39. The method of claim 21 , wherein the first annealing treatment is performed at temperatures that lie within a range from about 300° C. to about 500° C.

40. The method of claim 21 , wherein the first annealing treatment is performed for a time-period that lies within a range from about 1 minute to about 60 minutes.

41. The method of claim 21 , wherein an environment of the first green component during the first annealing comprises an oxidizing environment.

42. The method of claim 21 , wherein the CdTe layer is rendered substantially p-type after step (c).

Assignments (6)
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Nov 15, 2021
From: JPMORGAN CHASE BANK, N.A.
To: FIRST SOLAR, INC.
Reel/Frame 058132/0566 →
PATENT SECURITY AGREEMENT Recorded Jul 12, 2017
From: FIRST SOLAR, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 043177/0581 →
CORRECTIVE ASSIGNMENT TO CORRECT THE APPLICATION NUMBER FROM '13/301162' PREVIOUSLY RECORDED ON REEL 032045 FRAME 0657. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT APPLICATION NUMBER SHOULD BE '13/601162'. Recorded Feb 10, 2014
From: FIRST SOLAR MALAYSIA SDN. BHD.
To: FIRST SOLAR, INC.
Reel/Frame 032239/0005 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2014
From: FIRST SOLAR MALAYSIA SDN. BHD.
To: FIRST SOLAR, INC.
Reel/Frame 032045/0657 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 5, 2013
From: GENERAL ELECTRIC COMPANY
To: FIRST SOLAR MALAYSIA SDN.BHD.
Reel/Frame 031581/0457 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 16, 2009
From: FELDMAN-PEABODY, SCOTT; LITA, BOGDAN; COZENS, MICHAEL BURNASH; SADEGHI, MEHRAN; ZHAO, YU; WHITNEY, RENEE MARY
To: GENERAL ELECTRIC COMPANY
Reel/Frame 023659/0911 →