Low sink marks and excellent surface appearance reinforced polyamide compositions
View Patent ↗The invention relates to resin compositions comprising a) at least one amorphous semi-aromatic polyamide; b) at least two semi-crystalline polyamides, b1) and b2) and c) at least one glass reinforcement agent and shaped articles thereof showing a good balance of properties in terms of good mechanical properties, excellent surface appearance and reduced sink marks.
1. A resin composition comprising:
a) about 20 to about 50 wt-% of at least one amorphous semi-aromatic polyamide selected from the group consisting of poly(hexamethylene isophthalamide/hexamethylene terephthalamide); poly(hexamethylene isophthalamide/hexamethylene terephthalamide/4,4′bis(cyclohexyl)methane isophthalamide/4,4′bis(cyclohexyl)methane terephthalamide); poly(hexamethylene isophthalamide/4,4′bis(3,3′-dimethylcyclohexyl)methane isophthalamide/4,4′bis(3,3′-dimethylcyclohexyl)methane terephthalamide), poly(hexamethylene isophthalamide/hexamethylene terephthalamide/4,4′bis(3,3′-dimethylcyclohexyl)methane isophthalamide), poly(12-amidododecanamide/4,4′bis(3,3′-dimethylcyclohexyl)methane terephthalamide), poly(2,2,4-trimethylhexamethylene terephthalamide), poly(hexamethylene isophthalamide/hexamethylene terephthalamide/3-methyl-3,5,5-trimethylcyclohexyl isophthalamide/3-methyl-3,5,5-trimethylhexyl terephthalamide), and poly(caprolactam/2,2,4-trimethylhexamethylene terephthalamide/hexamethylene terephthalamide);
b) about 10 to about 40 wt-% of at least two semi-crystalline polyamides, b1) and b2), wherein b1) is poly(hexamethylene adipamide) and is present in an amount from about 5 to about 20 wt-%, and b2) is selected from the group consisting of; poly(hexamethylene sebacamide); poly(hexamethylene dodecanoamide); poly(decamethylene sebacamide) and combinations thereof and is present in about 5 to about 20 wt-%; and
about 10 to about 70 wt-%, of at least one glass reinforcement agent,
wherein the weight percentages are based on the total weight of the resin composition.
2. The resin composition according to claim 1 , wherein the glass reinforcement agent is fibrous non-circular cross-sectional glass.
3. The resin composition according to claim 1 further comprising one or more additional reinforcing agents.
4. The resin composition according to claim 1 further comprising one or more antioxidants.
5. A method for making an article comprising a step of shaping the resin composition of claim 1 .
6. A shaped article formed from the resin composition described in claim 1 .
7. The shaped article according to claim 6 , which is a portable electronic device housing.
8. The portable electronic device housing according to claim 7 , wherein the device is a mobile phone.