IP Library Granted Patent US 8,557,260
Granted Patent B2
US 8,557,260 · App. 12/640,235 · Granted Oct 15, 2013

Composition comprising at least two different cycloalkylmethicones and use thereof

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Quick Facts
Patent No.
US 8,557,260
App. No.
12/640,235
Granted
Oct 15, 2013
Kind
B2
Abstract

A cosmetic composition includes comprising a blend of cycloalkylmethicones comprising at least two different cycloalkylmethicones having general formula I: where R 1 is a hydrocarbon radical containing about 2 to about 4 carbon atoms; R 2 , R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of a hydrocarbon radical containing about 1 to about 4 carbon atoms; a is a positive number between 0<a<5; b and c are independently selected from 0 to 5 wherein (a+b+c)≦5; and wherein the rates of evaporation of the composition as measured in accordance with standard DIN 53249 test is from about 80% to about 99% by weight loss in about 200 to about 6000 minutes, more preferably in about 200 to about 1000 minutes, and even more preferably in about 200 to about 500 minutes.

Claims (24)

1. A composition comprising a blend of cycloalkylmethicones comprising at least two different cycloalkylmethicones having general formula I:

where R 1 is a hydrocarbon radical containing about 2 to about 4 carbon atoms;

R 2 , R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of a hydrocarbon radical containing about 1 to about 4 carbon atoms;

a is a positive number between 0<a<5;

b and c are independently selected from 0 to 5 wherein (a+b+c)≦5; and

wherein the rates of evaporation of the composition as measured in accordance with standard DIN 53249 test is from about 80% to about 99% by weight loss in about 200 to about 6000 minutes, wherein the composition is a cosmetic composition and wherein the blend of cycloalkylmethicones comprises from 0.1 to 99.0 percent by weight of the composition.

2. The composition of claim 1 wherein the cycloalkylmethicones are selected from the group consisting of 1,3,5-triethyl-1,3,5- trimethylcyclotrisiloxane, 1,3,5,7- tetraethyl-1,3,5,7-tetramethylcyclotetrasiloxane, 1,3,5,trimethyl-1,3,5-tripropylcyclotrisiloxane and 1,3,5 ,7-tetramethyl-1,3,5,7-tetrapropylcyclotetrasiloxane.

3. The composition of claim 1 comprising a blend of 1,3,5-triethyl-1,3,5-trimethylcyclotrisiloxane, 1,3,5,7-tetraethyl-1,3,5,7-tetramethylcyclotetrasiloxane.

4. The composition of claim 1 comprising a blend of from 45 weight percent to 91.1 weight percent of 1,3,5-triethyl-1,3,5-trimethylcyclotrisiloxane and from 8.9 weight percent to 55 weight percent of 1,3,5,7-tetraethyl-1,3,5,7-tetramethylcyclotetrasiloxane.

5. The composition of claim 1 comprising a blend of 1,3,5,trimethyl-1,3,5-tripropylcyclotrisiloxane and 1,3,5,7-tetramethyl-1,3,5,7-tetrapropylcyclotetrasiloxane.

6. The composition of claim 1 comprising a blend of 75 weight percent to 80 weight percent of 1,3,5,trimethyl-1,3,5-tripropylcyclotrisiloxane and 20 weight percent to 25 weight percent of 1,3,5,7-tetramethyl-1,3,5,7-tetrapropylcyclotetrasiloxane.

7. The composition of claim 1 wherein the blend of cycloalkylmethicones comprises from 0.5 to 60.0 percent by weight of the composition.

8. The composition of claim 1 wherein the blend of cycloalkylmethicones comprises from 1.0 to 40.0 percent by weight of the composition.

9. The composition of claim 1 wherein said composition is an aqueous emulsion where the discontinuous phase comprises water and the continuous phase comprises the blend of cycloalkylmethicones.

10. The composition of claim 1 wherein said composition is an aqueous emulsion where the discontinuous phase comprises the blend of cycloalkylmethicones and the continuous phase comprises water.

11. The composition of claim 1 comprising a non-aqueous organic hydroxylic solvent selected from the group consisting of alcohols, glycols, polyhydric alcohols, polymeric glycols and mixtures thereof, said non-aqueous organic hydroxylic solvents being liquid at ambient conditions.

12. The composition of claim 11 wherein said composition is a non-aqueous emulsion where the discontinuous phase comprises the non-aqueous hydroxylic organic solvent and the continuous phase comprises the blend of cycloalkylmethicones.

13. The composition of claim 11 wherein said composition is a non-aqueous emulsion where the discontinuous phase comprises the blend of cycloalkylmethicones and the continuous phase comprises the non-aqueous hydroxylic organic solvent.

14. The composition of claim 1 comprised in deodorants, antiperspirants, antiperspirant/deodorants, shaving products, skin lotions, moisturizers, toners, bath products, cleansing products, shampoos, conditioners, mousses, styling gels, hair sprays, hair dyes, hair color products, hair bleaches, waving products, hair straighteners, nail polish, nail polish remover, nails creams and lotions, cuticle softeners, sunscreen, insect repellent and anti-aging products, lipsticks, foundations, face powders, eye liners, eye shadows, blushes, makeup, mascaras or drug delivery systems for topical application of medicinal compositions that are to be applied to the skin.

15. The composition of claim 1 further comprising one or more of emollients, moisturizers, humectants, pigments, bismuth oxychloride, titanium dioxide coated mica, colorants, fragrances, biocides, preservatives, antioxidants, anti-microbial agents, anti-fungal agents, antiperspirant agents, exfoliants, hormones, enzymes, medicinal compounds, vitamins, salts, electrolytes, alcohols, polyols, absorbing agents for ultraviolet radiation, botanical extracts, surfactants, silicone oils, organic oils, waxes, film formers, thickening agents, talc, kaolin, starch, modified starch, nylon, bentonite and organo-modified clays.

16. The composition of claim 1 further comprising an antiperspirant agent selected from the group consisting of aluminum halides, aluminum hydroxyhalides, and complexes or mixtures thereof with zirconyl oxyhalides and zirconyl hydroxyhalides.

17. The composition of claim 1 further comprising one or more skin care component selected from the group consisting of triglyceride esters, wax esters, alkyl or alkenyl esters of fatty acids or polyhydric alcohol esters, pigments, Vitamin A, Vitamin C, Vitamin E, titanium dioxide, zinc oxide, oxybenzone, octylmethoxy cinnamate, butylmethoxy dibenzoylm ethane, p-aminobenzoic acid and octyl dimethyl-p-aminobenzoic acid.

18. The composition of claim 1 further comprising a volatile component selected from the group consisting of dodecamethylcyclohexasiloxane decamethylcyclotetrasiloxane, octamethylcylcosiloxane, isododecane, 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane, isohexadecane, capryl methicone, ethyl alcohol, hexamethyldisiloxane, isobutene, and linear low molecular weight silicones.

19. The composition of claim 1 wherein the rate of evaporation of the composition as measured in accordance with standard DIN 53249 test is from about 80% to about 99% by weight loss in about 200 to about 500 minutes.

Assignments (18)
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS Recorded Mar 31, 2023
From: BNP PARIBAS
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 063259/0133 →
RELEASE OF SECURITY INTEREST Recorded Mar 30, 2023
From: KOOKMIN BANK NEW YORK
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 063197/0373 →
FIRST LIEN TERM LOAN PATENT AGREEMENT Recorded Jun 5, 2019
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: BNP PARIBAS, AS ADMINISTRATIVE AGENT
Reel/Frame 049387/0782 →
ABL PATENT AGREEMENT Recorded Jun 5, 2019
From: MOMENTIVE PERFORMANCE MATERIALS INC.; MOMENTIVE PERFORMANCE MATERIALS GMBH
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 049388/0252 →
SECOND LIEN TERM LOAN PATENT AGREEMENT Recorded Jun 5, 2019
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: KOOKMIN BANK, NEW YORK BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 049388/0220 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS Recorded May 21, 2019
From: JPMORGAN CHASE BANK, N.A.
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 050304/0555 →
RELEASE OF SECURITY INTEREST Recorded May 15, 2019
From: BOKF, NA
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 049194/0085 →
RELEASE OF SECURITY INTEREST Recorded May 15, 2019
From: BOKF, NA
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 049249/0271 →
NOTICE OF CHANGE OF COLLATERAL AGENT - ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY - SECOND LIEN Recorded Mar 6, 2015
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
To: BOKF, NA, AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 035137/0263 →
NOTICE OF CHANGE OF COLLATERAL AGENT - ASSIGNMENT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY Recorded Mar 6, 2015
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
To: BOKF, NA, AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 035136/0457 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Oct 30, 2014
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 034113/0252 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Oct 30, 2014
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 034113/0331 →
SECURITY INTEREST Recorded Oct 27, 2014
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS COLLATERAL AGENT
Reel/Frame 034066/0662 →
SECURITY INTEREST Recorded Oct 27, 2014
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS COLLATERAL AGENT
Reel/Frame 034066/0570 →
SECURITY AGREEMENT Recorded Apr 29, 2013
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 030311/0343 →
PATENT SECURITY AGREEMENT Recorded Apr 3, 2013
From: MOMENTIVE PERFORMANCE MATERIALS INC.
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A., THE
Reel/Frame 030185/0001 →
SECURITY AGREEMENT Recorded May 31, 2012
From: MOMENTIVE PERFORMANCE MATERIALS INC
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A., THE
Reel/Frame 028344/0208 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 17, 2009
From: FALK, BENJAMIN
To: MOMENTIVE PERFORMANCE MATERIALS INC.
Reel/Frame 023667/0288 →