Chrysene derivative materials
View Patent ↗There is provided an electroluminescent composition. The composition includes a material having Formula I In Formula I: R 1 is the same or different at each occurrence and is selected from D, alkyl, alkoxy, silyl, and siloxane, or adjacent R 1 groups may be joined together to form a 5- or 6-membered aliphatic ring; Ar 1 and Ar 2 are the same or different and are aryl groups; a is an integer from 0 to 6; b is an integer from 0 to 2; and c is an integer from 0 to 3.
1. A compound having Formula I
where:
R 1 is the same or different at each occurrence and is selected from the group consisting of H, D, alkyl, alkoxy, silyl, and siloxane, or adjacent R 1 groups may be joined together to form a 5- or 6-membered aliphatic ring,
Ar 1 and Ar 2 are the same or different and are aryl groups,
a is an integer from 1 to 6;
b is an integer from 1 to 2;
c is an integer from 1 to 3; and
wherein at least one R 1 is D.
2. The compound of claim 1 , wherein R 1 is D.
3. The compound of claim 1 , wherein R 1 is D, a=5-6, b=1-2 and c=2-3.
4. The compound of claim 1 , wherein at least one R 1 is a branched alkyl group.
5. The compound of claim 1 , wherein Ar 1 and Ar 2 are selected from the group consisting of phenyl, biphenyl, naphthyl, phenanthryl, anthracenyl, 4-naphthylphenyl, 4-phenanthrylphenyl, where any of the preceding groups may be further substituted with one or more substituents selected from the group consisting of D, alkyl groups, silyl groups, and phenyl, and a group having Formula II:
where:
R 2 is the same or different at each occurrence and is selected from the group consisting of H, D, alkyl, alkoxy, siloxane and silyl, or adjacent R 2 groups may be joined together to form an aromatic ring; and
m is the same or different at each occurrence and is an integer from 1 to 6.
6. The compound of claim 1 , wherein Ar 1 and Ar 2 are selected from the group consisting of phenyl, biphenyl, terphenyl, naphthylphenyl, and deuterated analogs thereof.
7. The compound of claim 1 , wherein Ar 1 ≠Ar 2 .
8. A chrysene compound selected from the group consisting of compounds C1 and C5:
and
wherein each of the above compounds C1 and C5 is deuterated.
9. The chrysene compound of claim 1 , wherein the compound is C2: