Antifoulant for impact copolymers and method
View Patent ↗A process for producing a heterophasic copolymer is provided. The process includes introducing an antifoulant to a second polymerization reactor which operates in series with a first polymerization reactor. The antifoulant may be a multicomponent antifoulant and/or a coating agent. Provision of either antifoulant enables the production of a heterophasic copolymer with an Fc value from about 10% to about 50% by inhibiting reactor fouling during polymerization.
1. A process for producing a copolymer comprising:
introducing an active polymer from a first polymerization reactor into a second polymerization reactor;
contacting the active polymer with at least one olefin under polymerization conditions in the second polymerization reactor to form a heterophasic copolymer that is a sticky polymer;
continuously adding a multicomponent antifoulant directly to the second polymerization reactor at a rate such that the multicomponent antifoulant is present in the heterophasic copolymer in a concentration from about 25 ppm to about 200 ppm; and
inhibiting, with the multicomponent antifoulant, fouling within the second polymerization reactor; and
forming a sticky polymer having an Fc greater than 30% and a minimum bin opening for free flow at zero storage time of 2 feet.
2. The process of claim 1 comprising continuously adding the multicomponent antifoulant such that the multicomponent antifoulant is present in the heterophasic copolymer in a concentration of about 25 ppm.
3. The process of claim 1 wherein decreasing the amount of multicomponent antifoulant present in the heterophasic copolymer increases the Fc value of the heterophasic copolymer.
4. The process of claim 1 comprising forming a propylene impact copolymer with an Ec value from about 1% to about 80% and inhibiting fouling of the propylene impact copolymer in the second polymerization reactor.
5. The process of claim 1 wherein the multicomponent antifoulant comprises an activity limiting agent (ALA) and a selectivity control agent (SCA), the process comprising increasing the ratio of ALA to SCA to decrease the Fc value of the heterophasic copolymer.
6. The process of claim 1 comprising adding a multicomponent antifoulant comprising isopropyl myristate.
7. The process of claim 1 comprising forming a propylene impact copolymer having an Ec value from about 10 wt % to about 60%.
8. The process of claim 1 comprising forming a heterophasic copolymer having an Ec value greater than about 30 wt % to about 50%.
9. The process of claim 1 comprising forming a heterophasic copolymer that is a high rubber copolymer having an Fc value from greater than 30% to 50%.
10. The process of claim 1 comprising preventing, with the multicomponent antifoulant, adhesion on second polymerization reactor components selected from the group consisting of reactor inner sidewalls, piping, heat exchanger, distributor plate, compressor, and combinations thereof.
11. The process of claim 1 comprising preventing, with the multicomponent antifoulant, agglomeration of the sticky polymer.
12. The process of claim 1 comprising forming particles of the heterophasic copolymer; and
coating the particles with the multicomponent antifoulant.
13. The process of claim 1 comprising coating, with the multicomponent antifoulant, interior surfaces of the second polymerization reactor and preventing adhesion of the heterophasic copolymer to the interior surfaces.