Integrated process and reactor arrangement for hydrocarbon synthesis
View Patent ↗The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor. It further relates to a reactor arrangement suitable for operating the process according to the invention for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas comprising at least two parallel operating reactors, each containing a catalyst, wherein the reactors are connected to a common header for the distribution of synthesis gas to the reactors, and wherein the common header comprises a distribution means for selectively controlling the amount of synthesis gas fed to each reactor.
1. A process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor.
2. A process according to claim 1 , wherein at least one of the reactors is a fixed bed reactor.
3. A process according to claim 1 , wherein at least one of the reactors is a slurry reactor.
4. A process according to claim 1 , wherein all reactors are fixed bed reactors or wherein all reactors are slurry reactors.
5. A process according to claim 1 , wherein the reactor arrangement comprises at least one fixed bed reactor and at least one slurry reactor.
6. A process according to claim 1 , wherein the catalyst comprises cobalt or iron on a carrier.
7. A process according to claim 1 , wherein the catalyst is a Fischer-Tropsch catalyst.
8. A process according to claim 1 , wherein from 20 to 80% by volume of the synthesis gas is fed to the reactor having the highest relative reaction rate, and the remainder is fed to reactors having a lower reaction rate.
9. A process according to claim 1 , wherein the relative reaction rate in a reactor is determined by measuring the total carbon monoxide conversion per pass, or wherein the reaction rate in a reactor is determined by measuring the total reactor productivity for hydrocarbons having 5 or more carbon atoms at a given temperature and pressure.
10. A process according to claim 1 , further comprising the steps of separating the obtained product mixture into normally liquid, solid and gaseous components, and subjecting the normally liquid, and/or normally solid products to hydroprocessing and/or catalytic dewaxing, and isolating n- and iso-paraffinic products from the reaction mixture.