Polymer-dispersed polyol and process for producing flexible polyurethane foam
View Patent ↗To provide a process for producing a flexible polyurethane foam having a higher biomass degree than a conventional flexible polyurethane foam and excellent in foam physical properties and its appearance. A polymer-dispersed polyol obtained by polymerizing a vinyl monomer in the presence of the following polyol (a1) derived from a natural fat/oil and/or the following polyoxyalkylene polyol (a2) is used: Polyol (a1) derived from a natural fat/oil: a polyol derived from a natural fat/oil, which is obtained by providing a natural fat/oil with hydroxy groups by chemical reaction, and which has a hydroxy value of from 20 to 250 mgKOH/g and a molecular weight distribution of at least 1.2; Polyoxyalkylene polyol (a2): a polyoxyalkylene polyol which is produced by ring-opening polymerization of an alkylene oxide (c) with the polyol (a1) derived from a natural fat/oil in the presence of at least one polymerization catalyst (b) selected from the group consisting of a coordination anionic polymerization catalyst and a cationic polymerization catalyst.
1. A polymer-dispersed polyol (A1) obtained by polymerizing a vinyl monomer in the presence of the the following polyoxyalkylene polyol (a2):
Polyol (a1) derived from a natural fat/oil: a polyol derived from a natural fat/oil, which is obtained by providing a natural fat/oil with hydroxy groups by chemical reaction, and which has a hydroxyl value of from 20 to 250 mgKOH/g and a molecular weight distribution of at least 1.2;
Polyoxyalkylene polyol (a2): a polyoxyalkylene polyol which is produced by ring-opening polymerization of an alkylene oxide (c) with the polyol (a1) derived from a natural fat/oil in the presence of at least one polymerization catalyst (b) selected from the group consisting of a coordination anionic polymerization catalyst and a cationic polymerization catalyst
wherein said polyol (a1) is obtained by providing a natural fat/oil having no hydroxyl groups with hydroxyl groups by chemical reaction.
2. The polymer-dispersed polyol according to claim 1 , wherein the polyol (a1) derived from a natural fat/oil is one obtained by blowing air or oxygen in a natural fat/oil to cause oxidative cross linking between unsaturated double bonds of the natural fat/oil and at the same time, to have hydroxyl groups provided.
3. The polymer-dispersed polyol according to claim 1 , wherein the polyol (a1) derived from a natural fat/oil is one obtained by deoxidizing unsaturated double bonds of a natural fat/oil by having an oxidizing agent acted thereto, followed by ring-opening in the presence of an active hydrogen compound to have hydroxyl groups provided.
4. The polymer-dispersed polyol according to claim 1 , wherein the natural fat/oil has an iodine value of from 50 to 200.
5. The polymer-dispersed polyol according to claim 1 , wherein the natural fat/oil is soybean oil.
6. The polymer-dispersed polyol according to claim 1 , wherein the vinyl monomer contains acrylonitrile and styrene.
7. The polymer-dispersed polyol according to claim 1 , wherein the polyoxyalkylene polyol (a2) has a hydroxyl value of from 15 to 250 mgKOH/g and a molecular weight distribution of from 1.2 to 20.
8. The polymer-dispersed polyol according to claim 1 , wherein the polymerization catalyst (b) is a zinc hexacyanocobaltate complex having an organic ligand.
9. The polymer-dispersed polyol according to claim 1 , wherein the alkylene oxide (c) is ethylene oxide and propylene oxide.
10. A process for producing a polymer-dispersed polyol, which comprises polymerizing a vinyl monomer in the presence of polyoxyalkylene polyol (a2):
Polyol (a1) derived from a natural fat/oil: a polyol derived from a natural fat/oil, which is obtained by providing a natural fat/oil with hydroxy groups by chemical reaction, and which has a hydroxyl value of from 20 to 250 mgKOH/g and a molecular weight distribution of at least 1.2;
Polyoxyalkylene polyol (a2): a polyoxyalkylene polyol which is produced by ring-opening polymerization of an alkylene oxide (c) with the polyol (a1) derived from a natural fat/oil in the presence of at least one polymerization catalyst (b) selected from the group consisting of a coordination anionic polymerization catalyst and a cationic polymerization catalyst.
11. A process for producing a flexible polyurethane foam, which comprises reacting a polyol (A) containing the polymer-dispersed polyol (A1) as defined in claim 1 and a polyisocyanate (B) in the presence of a catalyst (C) and a blowing agent (D).
12. The process for producing a flexible polyurethane foam according to claim 11 , wherein the polyol (A) further comprises a polyoxyalkylene polyol (A2) having an average number of hydroxyl groups of from 2 to 8 and a hydroxyl value of from 20 to 160 mgKOH/g.
13. The process for producing a flexible polyurethane foam according to claim 11 , wherein the polyol (A) further comprises the polyoxyalkylene polyol (a2).
14. The process for producing a flexible polyurethane foam according to claim 11 , wherein foam-molding is carried out in a sealed mold.
15. The process for producing a flexible polyurethane foam according to claim 11 , wherein the blowing agent (D) is water.
16. The process for producing a flexible polyurethane foam according to claim 11 , wherein the polyol (A) further comprises a polyoxyalkylene polyol (A2) having an average number of hydroxyl groups of from 2 to 8 and a hydroxyl value of from 20 to 160 mgKOH/g and wherein a ratio of polymer-dispersed polyol (A1) to polyoxyalkylene polyol (A2) is from 10/90 to 90/10 (mass ratio).