Modified ionomer composition
View Patent ↗The present invention relates to golf balls and golf ball components comprising a blend of one or more ionomers mixed with one or more metal or ammonium salts of chelating agent. The resulting modified ionomer compositions have improved processability as shown by the increase in melt flow index (I2) as compared to the unmodified ionomer analogs while demonstrating an increase in resiliency or speed as shown by increasing COR, while maintaining or showing only a slight increase in hardness as measured by Shore D.
1. A golf ball comprising;
1) a core comprising a center,
2) an outer cover layer; and
3) one or more intermediate layers,
wherein at least one of the intermediate layers comprises a blend composition of;
(A) of from about 75 to about 99 wt % (based on the combined weight of Components A and B) of one or more ionomers; and
(B) of from about 1 to about 25 wt % (based on the combined weight of Components A and B) of a sodium salt of poly(meth)acrylic acid; and
wherein said blend composition has a flexural modulus of from about 5 to about 500 kpsi, and a Shore D hardness of from about 25 to about 85;
at least one of the intermediate layers comprises a polyalkenamer rubber selected from the group consisting of polybutenamer rubber, polypentenamer rubber, polyhexenamer rubber, polyheptenamer rubber, polyoctenamer rubber, polynonenamer rubber, polydecenamer rubber polyundecenamer rubber, polydodecenamer rubber, polytridecenamer rubber and any and all combinations thereof; and
the outer cover layer comprises a polymer selected from the group consisting of thermoset polyurethanes, thermoset polyureas, thermoplastic polyurethanes, thermoplastic polyureas, ionomers, styrenic block copolymers, ethylene/(meth)acrylic acid copolymers, or ethylene/(meth)acrylic acid/alkyl(meth)acrylate terpolymers, a unimodal ionomer, a bimodal ionomer, a modified unimodal ionomer, a modified bimodal ionomer and any and all combinations thereof.
2. The golf ball of claim 1 wherein in said blend composition;
A) Component A is present in an amount of from about 80 to about 98 wt % (based on the combined weight of Components A and B) one or more ionomers; and
B) Component B is present in an amount of from about 2 to about 20 wt % (based on the combined weight of Components A and B); and
wherein said blend composition has a flexural modulus of from about 15 to about 400 kpsi, and a Shore D hardness of from about 30 to about 80.
3. The golf ball of claim 1 wherein in said blend composition;
A) Component A is present in an amount of from about 85 to about 97 wt % (based on the combined weight of Components A and B) one or more ionomers and
B) Component B is present in an amount of from about 3 to about 15 wt % (based on the combined weight of Components A and B); and
wherein the blend composition has a flexural modulus of from about 200 to about 300 kpsi., and a Shore D hardness of from about 35 to about 75.
4. The golf ball of claim 1 , wherein said outer cover layer comprises a blend composition comprising one or more ionomers blended with;
A) one or more triblock copolymers; or
B) one or more hydrogenation products of the triblock copolymers; or
C) one or more hydrogenated diene block copolymers; and
wherein each triblock copolymer has
(i) a first polymer block comprising an aromatic vinyl compound,
(ii) a second polymer block comprising a conjugated diene compound, and wherein each hydrogenated diene block copolymer has a polystyrene-reduced number-average molecular weight of from 50,000 to 600,000, and is a hydrogenation product of;
(i) an A-B block copolymer, in which A is an alkenyl aromatic compound polymer block, and B is either
(1) a conjugated diene homopolymer block, wherein the vinyl content of the conjugated diene portion is more than 60%, or
(2) an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15-60%, or
(ii) an A-B-C block copolymer, in which A and B are as defined above and C is an alkenyl aromatic compound-conjugated diene copolymer tapered block, wherein the proportion of the alkenyl aromatic compound increases gradually, or
(iii) an A-B-A block copolymer, in which A and B are as defined above, and wherein in each of the hydrogenated diene block copolymers, the weight proportion of the alkenyl aromatic compound to conjugated diene is from 5/95 to 60/40, the content of the bound alkenyl aromatic compound in at least one block A is at least 3% by weight, the total of the bound alkenyl aromatic compound contents in the two block A's or the block A and the block C is 5% to 25% by weight based on the total monomers, and at least 80% of the double bond unsaturations of the conjugated diene portion is saturated by the hydrogenation.
5. The golf ball of claim 1 , wherein the outer cover layer comprises the reaction product of:
A) at least one component A comprising a monomer, oligomer, or prepolymer, or polymer comprising at least 5% by weight of at least one type of functional group;
B) at least one component B comprising a monomer, oligomer, prepolymer, or polymer comprising less by weight of anionic functional groups than the weight percentage of anionic functional groups of the at least one component A; and
C) at least one component C comprising a metal cation, wherein the reaction product comprises a pseudo-crosslinked network of the at least one component A in the presence of the at least one component B.
6. The golf ball of claim 1 , wherein the sodium salt of poly(meth)acrylic acid is a sodium salt of poly(acrylic acid).
7. The golf ball of claim 2 , wherein the sodium salt of poly(meth)acrylic acid is a sodium salt of poly(acrylic acid).
8. The golf ball of claim 3 , wherein the sodium salt of poly(meth)acrylic acid is a sodium salt of poly(acrylic acid).
9. A golf ball comprising;
1) a core comprising a center,
2) an outer cover layer; and
3) one or more intermediate lasers,
wherein at least one of the intermediate layers comprises a blend composition of;
(A) of from about 75 to about 99 wt % (based on the combined weight of Components A and B) of one or more ionomers; and
(B) of from about 1 to about 25 wt % (based on the combined weight of Components A and B) of a sodium salt of poly(meth)acrylic acid; and
wherein said blend composition has a flexural modulus of from about 5 to about 500 kpsi, and a Shore D hardness of from about 25 to about 85; and
the outer cover layer comprises a blend composition comprising one or more ionomers blended with;
A) one or more triblock copolymers; or
B) one or more hydrogenation products of the triblock copolymers; or
C) one or more hydrogenated diene block copolymers; and
wherein each triblock copolymer has
(i) a first polymer block comprising an aromatic vinyl compound,
(ii) a second polymer block comprising a conjugated diene compound, and wherein each hydrogenated diene block copolymer has a polystyrene-reduced number-average molecular weight of from 50,000 to 600,000, and is a hydrogenation product of;
(i) an A-B block copolymer, in which A is an alkenyl aromatic compound polymer block, and B is either
(1) a conjugated diene homopolymer block, wherein the vinyl content of the conjugated diene portion is more than 60%, or
(2) an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15-60%, or
(ii) an A-B-C block copolymer, in which A and B are as defined above and C is an alkenyl aromatic compound-conjugated diene copolymer tapered block, wherein the proportion of the alkenyl aromatic compound increases gradually, or
(iii) an A-B-A block copolymer, in which A and B are as defined above, and wherein in each of the hydrogenated diene block copolymers, the weight proportion of the alkenyl aromatic compound to conjugated diene is from 5/95 to 60/40, the content of the bound alkenyl aromatic compound in at least one block A is at least 3% by weight, the total of the bound alkenyl aromatic compound contents in the two block A's or the block A and the block C is 5% to 25% by weight based on the total monomers, and at least 80% of the double bond unsaturations of the conjugated diene portion is saturated by the hydrogenation.
10. The golf ball of claim 9 , wherein the sodium salt of poly(meth)acrylic is a sodium salt of poly(acrylic acid).
11. A golf ball comprising;
1) a core comprising a center,
2) an outer cover layer; and
3) one or more intermediate layers,
wherein at least one of the intermediate layers comprises a blend composition of;
(A) of from about 75 to about 99 wt % (based on the combined weight of Components A and B) of one or more ionomers; and
(B) of from about 1 to about 25 wt % (based on the combined weight of Components A and B) of a sodium salt of poly(meth)acrylic acid; and
wherein said blend composition has a flexural modulus of from about 5 to about 500 kpsi, and a Shore D hardness of from about 25 to about 85; and
the outer cover layer comprises the reaction product of:
A) at least one component A comprising a monomer, oligomer, or prepolymer, or polymer comprising at least 5% by weight of at least one type of functional group;
B) at least one component B comprising a monomer, oligomer, prepolymer, or polymer comprising less by weight of anionic functional groups than the weight percentage of anionic functional groups of the at least one component A; and
C) at least one component C comprising a metal cation, wherein the reaction product comprises a pseudo-crosslinked network of the at least one component A in the presence of the at least one component B.
12. The golf ball of claim 11 , wherein the sodium salt of poly(meth)acrylic acid is a sodium salt of poly(acrylic acid).