IP Library Granted Patent US 7,914,707
Granted Patent B2
US 7,914,707 · App. 12/649,100 · Granted Mar 29, 2011

Additive for non-aqueous electrolyte and secondary battery using the same

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Quick Facts
Patent No.
US 7,914,707
App. No.
12/649,100
Granted
Mar 29, 2011
Kind
B2
Abstract

Disclosed is a compound represented by the following formula 1: wherein, each of R 1 ˜R 13 independently represents —H, —F, —Cl, —Br, —I, —OH, —SH, —COOH, —PO 3 H 2 , —NH 2 , —NO 2 , —O(CH 2 CH 2 O) n H (wherein, n is an integer of 1˜5), C 1 ˜C 12 alkyl group, C 1 ˜C 12 aminoalkyl group, C 1 ˜C 12 hydroxyalkyl group, C 1 ˜C 12 haloalkyl group, C 2 ˜C 12 alkenyl group, C 1 ˜C 12 alkoxy group, C 1 ˜C 12 alkylamino group, C 1 ˜C 12 dialkylamino group, C 6 ˜C 18 aryl group, C 6 ˜C 18 aminoaryl group, C 6 ˜C 18 hydroxyaryl group, C 6 ˜C 18 haloaryl group, C 7 ˜C 18 benzyl group, C 7 ˜C 18 aminobenzyl group, C 7 ˜C 18 hydroxybenzyl group, C 7 ˜C 18 halobenzyl group, or nitrile group (—CN); and at least one of R 4 ˜R 13 is nitrile group (—CN). A non-aqueous electrolyte comprising: (i) a lithium salt, (ii) a solvent, and (iii) a compound represented by formula 1; and a secondary battery comprising the non-aqueous electrolyte are also disclosed. When the compound represented by formula 1 is added to a non-aqueous electrolyte, it is possible to improve the safety of a secondary battery in an overcharged state.

Claims (6)

1. A compound selected from the group consisting of formula 2, formula 3 and formula 4:

wherein each of R 1 ˜R 11 independently represents —H, —F, —Cl, —Br, —I, —SH, —COOH, —PO 3 H 2 , —NH 2 , —NO 2 , —O(CH 2 CH 2 O) n H (wherein n is an integer of 1˜5), C 1 ˜C 12 alkyl group, C 1 ˜C 12 aminoalkyl group, C 1 ˜C 12 hydroxyalkyl group, C 1 ˜C 12 haloalkyl group, C 2 ˜C 12 alkenyl group, C 1 ˜C 12 alkoxy group, C 1 ˜C 12 alkylamino group, C 1 ˜C 12 dialkylamino group, C 6 ˜C 18 aryl group, C 6 ˜C 18 aminoaryl group, C 6 ˜C 18 hydroxyaryl group, C 6 ˜C 18 haloaryl group, C 7 ˜C 18 benzyl group, C 7 ˜C 18 aminobenzyl group, C 7 ˜C 18 hydroxybenzyl group, C 7 ˜C 18 halobenzyl group, or nitrile group (—CN), wherein at least one of R 1 —R 11 of formula 2 is a nitrile group;

wherein each of R 1 ˜R 3 is the same as defined in the above formula 2; and

wherein each of R 1 ˜R 3 is the same as defined in the above formula 2.

2. The compound according to claim 1 , wherein at least two of R 1 ˜R 11 are a nitrile group (—CN).

3. The compound according to claim 1 , wherein at least two of R 4 ˜R 11 are a nitrile group (—CN).

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2021
From: LG CHEM, LTD.
To: LG ENERGY SOLUTION, LTD.
Reel/Frame 058295/0068 →