Production of synthesis gas through controlled oxidation of biomass
View Patent ↗A process for producing synthesis gas from biomass in which biomass is contacted with oxygen and steam, wherein the oxygen is present in an amount effective to oxidize the biomass partially and to heat the biomass to a temperature of at least 500° C. and no greater than 750° C. At least a portion of the partially oxidized biomass then is treated with oxygen and steam to heat the biomass to a temperature of at least 800° C., thereby producing a synthesis gas, which then is recovered.
1. A process for producing synthesis gas from biomass, comprising:
(a) contacting said biomass with an oxidizing gas comprising oxygen and steam, wherein said oxygen is present in an amount effective to oxidize said biomass and to heat said biomass to a temperature of at least 500° C. and no greater than a maximum of 750° C.;
(b) treating at least a portion of said oxidized biomass produced in step (a) with an oxidizing gas comprising oxygen and steam in a first stage to heat said oxidized biomass to a temperature which is at least 800° C. and does not exceed a maximum of 850° C.;
(c) treating at least a portion of said oxidized biomass produced in step (b) with an oxidizing gas comprising oxygen and steam in a second stage to heat said oxidized biomass to a temperature which is at least 900° C. and does not exceed a maximum of 1,000° C., thereby producing synthesis gas; and
(d) recovering said synthesis gas produced in step (c).
2. The process of claim 1 wherein, in step (a), said biomass is heated to a temperature of from about 600° C. to about 750° C.
3. The process of claim 2 wherein, in step (a), said biomass is heated to a temperature of from about 600° C. to about 725° C.
4. The process of claim 1 wherein, in step (a), said biomass is contacted with said oxygen at a weight ratio of oxygen to biomass of from about 0.20 to about 0.35 of the stoichiometric weight ratio needed for complete combustion of said biomass.
5. The process of claim 4 wherein, in step (a), said biomass is contacted with said oxygen at a weight ratio of oxygen to biomass of from about 0.20 to about 0.30 of the stoichiometric weight ratio needed for complete combustion of said biomass.
6. The process of claim 5 wherein, in step (a), said biomass is contacted with said oxygen at a weight ratio of oxygen to biomass of from about 0.25 to about 0.30 of the stoichiometric weight ratio needed for complete combustion of said biomass.
7. The process of claim 1 wherein, in step (a), said biomass is contacted with said oxygen and said steam in a fluidized bed of particulate material.
8. The process of claim 1 wherein in step (a), said biomass is contacted with oxygen and steam in the absence of nitrogen.
9. The process of claim 1 wherein, in step (c), said oxidized biomass is heated to a temperature of at least 925° C., and which does not exceed 1,000° C.
10. The process of claim 1 wherein, in steps (b) and (c), said oxidized biomass is contacted with oxygen and steam in the absence of nitrogen.
11. The process of claim 1 wherein said oxidizing gas, in step (a), further comprises carbon dioxide.
12. The process of claim 11 wherein said carbon dioxide is present is said oxidizing gas in step (a) in an amount that does not exceed 20 vol. %.
13. The process of claim 12 wherein said carbon dioxide is present in said oxidizing gas in step (a) in an amount of from about 10 vol. % to about 20 vol. %.
14. The process of claim 13 wherein oxygen is present in said oxidizing gas in step (a) in an amount of from about 30 vol. % to about 40 vol. %, carbon dioxide is present in said oxidizing gas in step (a) in an amount of from about 10 vol. % to about 20 vol. %, and the remainder of said oxidizing gas in step (a) essentially is steam.
15. The process of claim 1 wherein said oxidizing gas, in step (b), further comprises carbon dioxide.
16. The process of claim 15 wherein said carbon dioxide is present in said oxidizing gas in step (b) in an amount that does not exceed 20 vol. %.
17. The process of claim 16 wherein said carbon dioxide is present in said oxidizing gas in step (b) in an amount of from about 10 vol. % to about 20 vol. %.
18. The process of claim 17 wherein oxygen is present in said oxidizing gas in step (b) in an amount of from about 30 vol. % to about 40 vol. %, carbon dioxide is present in said oxidizing gas in step (b) in an amount of from about 10 vol. % to about 20 vol. %, and the remainder of said oxidizing gas in step (b) essentially is steam.
19. The process of claim 1 wherein said oxidizing gas, in step (c), further comprises carbon dioxide.
20. The process of claim 19 wherein said carbon dioxide is present in said oxidizing gas in step (c) in an amount that does not exceed 20 vol. %.
21. The process of claim 20 wherein said carbon dioxide is present in said oxidizing gas in step (c) in an amount of from about 10 vol. % to about 20 vol. %.
22. The process of claim 21 wherein oxygen is present in said oxidizing gas in step (c) in an amount of from about 30 vol. % to about 40 vol. %, carbon dioxide is present in said oxidizing gas in step (c) in an amount of from about 10 vol. % to about 20 vol. %, and the remainder of said oxidizing gas in step (c) essentially is steam.