IP Library Granted Patent US 8,236,704
Granted Patent B2
US 8,236,704 · App. 12/654,494 · Granted Aug 7, 2012

Etchant and array substrate having copper lines etched by the etchant

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Quick Facts
Patent No.
US 8,236,704
App. No.
12/654,494
Granted
Aug 7, 2012
Kind
B2
Abstract

An etchant includes hydrogen peroxide (H 2 O 2 ), and a mixed solution including at least one of an organic acid, an inorganic acid, and a neutral salt.

Claims (58)

1. A method of using an etchant for simultaneously etching and patterning a double metal layer, comprising:

providing an etchant comprising: hydrogen peroxide (H 2 O 2 ); sulfuric acid; a neutral salt; and a hydrogen peroxide (H 2 O 2 ) stabilizer;

controlling the concentration of hydrogen peroxide in the etchant at a value such that the etchant simultaneously etches and patterns both layers of the double metal layer;

controlling a molar ratio of hydrogen peroxide to sulfuric acid in the etchant to determine an etch time of the double metal layer; and

simultaneously etching and patterning both layers of the double metal layer using the etchant.

2. A method of using an etchant for simultaneously etching and patterning a double metal layer that includes a copper (Cu) layer and a molybdenum (Mo) layer, comprising:

providing an etchant comprising: hydrogen peroxide (H 2 O 2 ); at least one of an organic acid, and an inorganic acid, and a neutral salt; and a hydrogen peroxide (H 2 O 2 ) stabilizer;

controlling the concentration of hydrogen peroxide in the etchant at a value such that the etchant simultaneously etches and patterns both the Cu layer and the Mo layer of the double metal layer; and

simultaneously etching and patterning both the Cu layer and the Mo layer of the double metal layer.

3. The method of claim 2 , wherein the at least one of an organic acid, and an inorganic acid, and a neutral salt includes acetic acid.

4. The method of claim 2 , wherein the at least one of an organic acid, and an inorganic acid, and a neutral salt includes nitric acid.

5. The method of claim 2 wherein the at least one of an organic acid, and an inorganic acid, and a neutral salt includes hydrochloric acid.

6. The method of claim 2 , wherein the at least one of an organic acid, and an inorganic acid, and a neutral salt includes phosphoric acid.

7. The method of claim 2 , wherein the at least one of an organic acid, and an inorganic acid, and a neutral salt includes one of potassium chloride, sodium chloride, potassium hydrogen sulfate and potassium metaperiodate.

8. The method of claim 7 wherein the one of potassium chloride, sodium chloride, potassium hydrogen sulfate and potassium metaperiodate includes potassium hydrogen sulfate.

9. A method of using an etchant for simultaneously etching and patterning a double metal layer that includes a copper (Cu) layer and a molybdenum (Mo) layer, comprising:

providing an etchant comprising: hydrogen peroxide (H 2 O 2 ); sulfuric acid (H 2 SO 4 ); and a hydrogen peroxide (H 2 O 2 ) stablizer;

controlling a molar ratio of hydrogen peroxide to sulfuric acid in the etchant to determine an etch time of the copper layer;

controlling a concentration of hydrogen peroxide in the etchant at a value such that the etchant simultaneously etches and patterns both the Cu layer and the Mo layer of the double metal layer; and

simultaneously etching and patterning both the Cu layer and the Mo layer of the double metal layer.

10. The method of claim 9 , wherein the molar ratio of hydrogen peroxide to sulfuric acid is controlled such that 1000 angstroms of copper is etched in between about 5 and about 15 seconds.

11. The method of claim 9 , wherein the concentration of hydrogen peroxide is controlled such that an etch rate of molybdenum is between about 500 and about 2000 angstroms per minute.

12. A method of fabricating a thin film transistor of display device, comprising:

forming a first metal layer on a substrate;

forming a second metal layer on the first metal layer;

patterning the first metal layer and the second metal layer to form a gate line and a gate electrode using an etchant that includes hydrogen peroxide (H 2 O 2 ) and a hydrogen peroxide (H 2 O 2 ) stabilizer and

forming a gate insulation layer on the gate line and the gate electrode;

forming an active layer on the gate insulation layer;

forming an ohmic contact layer on the active layer;

forming a third metal layer on the active layer;

forming a passivation layer on the second metal layer; and

forming a pixel electrode on the passivation layer; forming a fourth metal layer on the third metal layer;

patterning the third metal layer and the fourth metal layer to form a data line, a source electrode and a drain electrode using an etchant that includes hydrogen peroxide (H 2 O 2 ) and a hydrogen peroxide (H 2 O 2 ) stabilizer.

13. The method of claim 12 , wherein the first metal layer includes a molybdenum (Mo) layer.

14. The method of claim 12 , wherein the second metal layer includes a copper (Cu) layer.

15. The method of claim 12 , wherein the pixel electrode is electrically connected to the third metal layer.

16. The method of claim 12 , wherein the third metal layer includes a molybdenum (Mo) layer.

17. The method of claim 12 , wherein the fourth metal layer includes a copper (Cu) layer.

18. A method of fabricating a thin film transistor of a display device, comprising:

forming a first metal layer on a substrate;

forming a second metal layer including a copper (Cu) layer or copper alloy layer on the first metal layer; and

patterning the first and second metal layers using an etchant, the etchant including hydrogen peroxide (H 2 O 2 ) and at least one of an organic acid and a neutral salt;

forming a pixel region with the first metal layer and the second metal layer, the pixel region having a thin film transistor;

controlling the concentration of hydrogen peroxide in the etchant at a value such that the etchant simultaneously etches and patterns both the first metal layer and the second metal layer; and

simultaneously etching and patterning both the first metal layer and the second metal layer of the double metal layer.

19. The method of claim 18 , wherein the second metal layer includes a molybdenum (Mo) layer.

20. The method of claim 18 , wherein the first and second metal layers include a gate line and a gate electrode.

21. The method of claim 18 , wherein the first and second metal layers include a data line and source and drain electrodes.

22. The method of claim 18 , further comprising forming a pixel electrode on the second metal layer.

23. The method of claim 18 , wherein the etchant further comprises a hydrogen peroxide (H 2 O 2 ) stabilizer.

24. The method of claim 18 , wherein the organic acid includes an acetic acid (CH 3 COOH).

25. The method of claim 18 , wherein the neutral salt includes one of potassium chloride (KCl), sodium chloride (NaCl), potassium hydrogen sulfate (KHSO 4 ), and potassium metaperiodate (KIO4).

26. The method of claim 18 , wherein the etchant further comprises an inorganic acid.

27. The method of claim 26 , wherein the inorganic acid includes one of sulfuric acid (H 2 SO 4 ), nitric acid (HNO 3 ), hydrochloric acid (HCl), and phosphoric acid (H 3 PO 4 ).

28. The method of claim 18 , further comprising forming an insulation layer on the second metal layer.

29. The method of claim 28 , wherein the insulation layer is formed of one of an inorganic material and an organic material.

30. The method of claim 29 , wherein the inorganic material includes one of silicon oxide (SiOx) and silicon nitride (SiNx).

31. The method of claim 29 , wherein the organic material includes one of benzocyclobutene (BCB) and an acryl-base resin.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE SPELLING OF COMPANY NAME CHANGE DIPLAY TO "DISPLAY" PREVIOUSLY RECORDED ON REEL 028042 FRAME 0397. ASSIGNOR(S) HEREBY CONFIRMS THE NAME IS SPELLED CORRECTLY ON NAME CHANGE DOCUMENT. Recorded May 29, 2012
From: LG PHILIPS LDC CO., LTD.
To: LG DISPLAY CO., LTD.
Reel/Frame 028308/0035 →
CHANGE OF NAME Recorded Apr 13, 2012
From: LG PHILIPS LCD CO., LTD.
To: LG DIPLAY CO., LTD.
Reel/Frame 028042/0397 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2009
From: JO, GYOO CHUL; CHAE, KI-SUNG
To: LG.PHILIPS LCD CO., LTD.
Reel/Frame 023730/0237 →