IP Library Granted Patent US 8,337,988
Granted Patent B2
US 8,337,988 · App. 12/662,561 · Granted Dec 25, 2012

Coated article having low-E coating with absorber layer(s)

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Quick Facts
Patent No.
US 8,337,988
App. No.
12/662,561
Granted
Dec 25, 2012
Kind
B2
Abstract

A coated article is provided, having a coating supported by a glass substrate where the coating includes at least one color and/or reflectivity-adjusting absorber layer. The absorber layer(s) allows color tuning, and reduces the glass side reflection of the coated article and/or allows sheet resistance of the coating to be reduced without degrading glass side reflection. In certain example embodiments the absorber layer is provided between first and second dielectric layers which may be of substantially the same material and/or composition. In certain example embodiments, the coated article is capable of achieving desirable transmission, together with desired color, low reflectivity, and low selectivity, when having only one infrared (IR) reflecting layer of silver and/or gold. Coated articles according to certain example embodiments of this invention may be used in the context of insulating glass (IG) window units, monolithic windows, or the like.

Claims (58)

1. A coated article comprising a coating supported by a glass substrate, the coating comprising moving away from the glass substrate:

a first dielectric layer comprising silicon nitride;

a first contact layer;

an IR reflecting layer comprising silver, wherein the coating has only one IR reflecting layer comprising silver;

a second contact layer, the first and second contact layers each directly contacting the IR reflecting layer;

a second dielectric layer comprising silicon nitride; and

wherein at least one of the first and second dielectric layers comprising silicon nitride is split by an absorber layer comprising NbZr, wherein the absorber layer at least in part causes and/or permits color tuning of the coated article; and

wherein the coated article has a selectivity of at least about 1.2, a solar factor of no greater than about 32, and a glass side reflectance (Y) of the coated article is no greater than about 30%.

2. The coated article of claim 1 , wherein the absorber layer is provided so that the coated article is green colored by way of an a* g color value of from about −15.0 to −5.0 and a b* g color value of from about −6.0 to 3.0, and is able to achieve such coloration when having only one IR reflecting layer comprising silver.

3. The coated article of claim 2 , wherein the green colored coated article has an a* g color value of from about −12.0 to −7.0 and a b* g color value of from about

−3.0 to 1.0.

4. The coated article of claim 2 , wherein the glass substrate is substantially clear colored and the coating provides the green coloration to the coated article.

5. The coated article of claim 1 , wherein the absorber layer is provided so that the coated article is neutral-colored by way of an a* g color value of from about

−5.0 to 1.0 and a b* g color value of from about −5.0 to 1.0, and is able to achieve such coloration when having only one IR reflecting layer comprising silver.

6. The coated article of claim 5 , wherein the neutral-colored coated article has an a* g color value of from about −3.0 to 0 and a b* g color value of from about

−4.0 to 0.

7. The coated article of claim 5 , wherein the glass substrate is substantially clear colored and the coating provides the neutral coloration to the coated article.

8. The coated article of claim 1 , wherein the absorber layer is provided so that the coated article is blue-colored by way of an a* g color value of from about −4.0 to 2.0 and a b* g color value of from about −22.0 to −10.0, and is able to achieve such coloration when having only one IR reflecting layer comprising silver.

9. The coated article of claim 8 , wherein the blue-colored coated article has an a* g color value of from about −3.0 to 1.0 and a b* g color value of from about −19.0 to −15.0.

10. The coated article of claim 1 , wherein the coating further comprises an overcoat comprising an oxide and/or nitride of zirconium and/or aluminum.

11. The coated article of claim 1 , wherein the absorber layer comprising NbZr is oxided and/or nitrided.

12. The coated article of claim 1 , wherein the coated article has a selectivity of at least about 1.4.

13. The coated article of claim 1 , wherein the coated article has a solar factor of no greater than about 28.

14. The coated article of claim 1 , wherein the coated article has a visible transmission of from about 30 to 48%.

15. The coated article of claim 1 , wherein the absorber layer is located between the IR reflecting layer and the glass substrate, and wherein the coating further comprises another absorber layer located between at least the second contact layer and at least part of the second dielectric layer.

16. A green colored insulating glass (IG) window unit including first and second substantially clear-colored glass substrates and a coating supported by at least the first glass substrate, the coating comprising moving away from the first glass substrate:

a first dielectric layer;

an absorber layer comprising NbZr;

a second dielectric layer;

a first contact layer;

an IR reflecting layer comprising silver, wherein the coating has only one IR reflecting layer comprising silver;

a second contact layer; and

a third dielectric layer,

wherein the IG unit has a visible transmission of from about 30 to 48%, and green color by way of an a* g color value of from about −15.0 to −5.0 and a b* g color value of from about −6.0 to 3.0, and wherein the IG window unit is able to achieve these characteristics including green color when having only one IR reflecting layer comprising silver.

17. The IG unit of claim 16 , wherein the absorber layer is partially oxided and/or nitrided.

18. The IG unit of claim 16 , wherein the coating further comprises an absorber layer comprising NiCr and/or NbZr located between at least the second contact layer and the third dielectric layer.

19. The IG unit of claim 18 , wherein the absorber layer located between at least the second contact layer and the third dielectric layer comprises NbZr.

20. The IG unit of claim 16 , wherein the absorber layer comprises NbZr, and wherein the first and second dielectric layers are of substantially the same material and each of the first and second dielectric layers directly contacts the absorber layer.

21. A blue-colored coated article including a coating supported by a substantially clear-colored glass substrate, the coating comprising moving away from the glass substrate:

a first dielectric layer;

an absorber layer comprising NbZr;

a second dielectric layer, wherein the absorber layer is between and directly contacting the first and second dielectric layers;

a first contact layer;

an IR reflecting layer comprising silver;

a second contact layer, wherein the first and second contact layers each directly contact the IR reflecting layer;

a third dielectric layer; and

wherein the absorber layer is provided in a location and thickness such that the coated article achieves blue coloration while having only one IR reflecting layer comprising silver.

22. A coated article including a coating supported by a substantially clear-colored glass substrate, the coating comprising moving away from the glass substrate:

a first dielectric layer;

a first contact layer;

an IR reflecting layer comprising silver, the coating having only one IR reflecting layer comprising silver;

a second contact layer, wherein the first and second contact layers each directly contact the IR reflecting layer;

a second dielectric layer;

a third dielectric layer;

an absorber layer comprising NiCr or NbZr, wherein said absorber layer is located between and directly contacting said second and third dielectric layers; and

wherein the coated article is substantially neutral-colored and the absorber layer is provided in thickness and location so that the coated article achieves neutral coloration while having only one IR reflecting layer comprising silver.

23. The coated article of claim 22 , wherein said absorber layer comprises NbZr.

24. The coated article of claim 22 , wherein said absorber layer comprises NiCr.

Assignments (5)
MERGER Recorded May 30, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
To: GUARDIAN EUROPE S.À R.L.
Reel/Frame 046834/0495 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME AND ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED ON REEL 044900 FRAME 0321. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Feb 28, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
Reel/Frame 045870/0001 →
CHANGE OF NAME Recorded Dec 18, 2017
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À.R.L.
Reel/Frame 044900/0321 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2017
From: GUARDIAN INDUSTRIES CORP.
To: GUARDIAN GLASS, LLC.
Reel/Frame 044053/0318 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2010
From: KNOLL, HARTMUT; BUTZ, JOCHEN; KRILTZ, UWE; DISTELDORF, BERND; FERREIRA, JOSE; PALLOTTA, PIERROT
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A. (C.R.V.C.); GUARDIAN INDUSTRIES CORP.
Reel/Frame 024811/0943 →