Process for the production of propylene copolymers using a prepolymerised catalyst
View Patent ↗The present invention relates to a process for the production of propylene copolymers wherein in a first step an olefin polymerization catalyst comprising a solid catalyst component is subjected to a prepolymerization reaction in a prepolymerization reactor, in which propylene monomers are present in an amount of 98.0 to 99.9 mol % and further alpha-olefin monomers other than propylene are present in an amount of 0.1 to 2.0 mol %, based on the combined amount of propylene and further alpha-olefin monomers, so that a prepolymer is produced on the catalyst in an amount of 10 to 1000 g per g of the solid catalyst component, and in a second, subsequent step propylene and further alpha-olefin monomers other than propylene are copolymerized in the presence of the prepolymerized catalyst produced in the first step so that a propylene copolymer is obtained which contains at least 0.1 mol % of alpha-olefin units other than propylene, to propylene copolymers obtainable by such a process and to the use of a prepolymerized catalyst in such a process.
1. A process for the production of propylene copolymers wherein
in a first step, an olefin polymerisation catalyst comprising a solid catalyst component is subjected to a prepolymerisation reaction in a prepolymerisation reactor, in which propylene monomers are present in an amount of 98.5 to 99.8 mol % and further alpha-olefin monomers other than propylene are present in an amount of 0.2 to 1.5 mol %, based on the combined amount of propylene and further alpha-olefin monomers, so that a prepolymer is produced on the catalyst in an amount of 10 to 1000 g per g of the solid catalyst component, and
in a second, subsequent step, propylene and further alpha-olefin monomers other than propylene are copolymerised in the presence of the prepolymerised catalyst produced in the first step so that a propylene copolymer is obtained-which contains at least 0.1 mol % of alpha-olefin units other than propylene.
2. The process according to claim 1 , wherein in the first step in the prepolymerisation reactor propylene monomers are present in an amount of more than 99.2 to 99.6 mol % and further alpha-olefin monomers other than propylene are present in an amount of 0.4 to 0.8 mol %, based on the combined amount of propylene and further alpha-olefin monomers.
3. The process according to claim 1 , wherein the prepolymerisation reaction is conducted continuously.
4. The process according to claim 1 , wherein the prepolymerisation reaction is conducted in liquid phase.
5. The process according to claim 1 , wherein the prepolymerisation reaction is conducted at a temperature of 0 to 50 ° C.
6. The process according to according to claim 1 , wherein the propylene copolymer produced in the second step contains from 92 to 99.9 mol % propylene and from 0.1 to 8 mol % of an alpha-olefin other than propylene.
7. The process according to claim 1 , wherein the propylene copolymer produced in the second step has an amount of xylene insolubles of 92 to 98 wt %.
8. The process according to claim 1 , wherein the propylene copolymer produced in the second step has a MFR 2 (230 ° C,2.16 kg) of 0.1 to 500 g/10min.
9. The process according to claim 1 , wherein the alpha-olefin monomers other than propylene in the first and in the second step independently are selected from the group of alpha-olefins having from 2 to 10 carbon atoms.