Method for the production of pure C.I. pigment orange 74
View Patent ↗The invention relates to a method for conditioning and purifying pigment orange 74. The method is characterized in that the aqueous suspension of the raw pigment, optionally after adding an organic solvent from the group comprising isobutanol, chlorobenzene and o-dichlorobenzene, is subjected to a finishing treatment, the organic solvent is optionally removed using a distillation process, the remaining aqueous pigment suspension is mixed with a non-ionic surfactant and is heated to a temperature ranging from 30 to 100° C. and the pigment is then filtered off.
1. A process for preparing pure C.I. Pigment Orange 74, comprising the steps of subjecting an aqueous suspension of crude C.I. Pigment Orange 74 pigment, optionally after addition of one or more organic solvents selected from the group consisting of isobutanol, chlorobenzene and o-dichlorobenzene, to a conditioning treatment, removing any organic solvent by distillation, admixing the remaining aqueous pigment suspension with a nonionic surfactant, bringing the admixture to a temperature of 30 to 100° C. and filtering off the pigment.
2. The process as claimed in claim 1 wherein the conditioning treatment is carried out at a temperature between 30 and 200° C.
3. The process as claimed in claim 1 , wherein the conditioning treatment is carried out at a temperature between 80 and 200° C.
4. The process as claimed in claim 1 , wherein the conditioning treatment is carried out in water under superatmospheric pressure and at temperatures of 100 to 200° C.
5. The process as claimed in claim 1 , wherein the conditioning treatment is carried out in o-dichlorobenzene.
6. The process as claimed in claim 1 , wherein the amount of nonionic surfactant is in the range from 5% to 100% by weight, based on the weight of the pigment.
7. The process as claimed in claim 1 , wherein the amount of nonionic surfactant is in the range from 10% to 30% by weight, based on the weight of the pigment.
8. The process as claimed in claim 1 , wherein the aqueous pigment suspension is admixed with a nonionic surfactant and brought to a temperature of 50 to 90° C.
9. The process as claimed in claim 1 , wherein the nonionic surfactant is a fatty alcohol polyglycol ether.
10. A C.I. Pigment Orange 74 made in accordance with the process of claim 1 , wherein the optical purity C* is at least 43.00 in an alkyd-melamine varnish.
11. The C.I. Pigment Orange 74 as claimed in claim 10 , wherein the absolute hue angle H* is at least 29.00 in an alkyd-melamine varnish.
12. The C.I. Pigment Orange 74 as claimed in claim 10 , wherein the absolute lightness L* is at least 73.60 in an alkyd-melamine varnish.
13. A pigmented high molecular weight organic materials of natural or synthetic origin pigmented by the C.I. Pigment Orange as claimed in claim 10 .
14. A composition pigmented by the C.I. Pigment Orange as claimed in claim 10 , wherein the composition is a varnish, paint, electrophotographic toner, electrophotographic developer or inkjet ink.