Stable and compatible polymer blends
View Patent ↗The present invention pertains to products and processes relating to compatible polymer blends comprising at least one sulfonated polymer and at least one non-sulfonated polymer. The sulfonated polymers may be produced using a number of sulfonating agents including a coordination complex of sulfur trioxide. The polymeric blended materials described herein are useful in a variety of applications, including as coatings for medical devices, protective clothing and fabric, laboratory equipment, vascular stents and shunts, absorbent materials and separation membranes, three-dimensional constructs, devices, and other uses.
1. A polymeric material that is water insoluble and comprises (i) at least one uniformly sulfonated aryl-containing block copolymer comprising at least one arene moiety-containing unit and at least one non-arene moiety containing unit, wherein said sulfonated aryl-containing block copolymer is 50-80 mol % sulfonated; wherein said sulfonated aryl-containing block copolymer comprises a random block copolymer, a triblock copolymer, or a pseudorandom block copolymer wherein the end blocks comprise arylene-vinyl polymer and the central blocks comprise at least one monoalkene polymer segment prepared from a monoalkene selected from the group consisting of isobutylene, methyl cyclohexene, and methylcyclopentene, and (ii) at least one thermoplastic or thermosetting non-sulfonated homopolymer or copolymer selected from the group consisting of polyurethane, a segmented polyurethane, a poly(ether urethane), a poly(carbonate urethane), a poly(siloxy urethane), a polyurethane urea, an arylene-vinyl containing block copolymer, a polysiloxane, a polyamide, a polyketone, a polyester, a poly(ether-ester), a polyanhydride, a polyamine, a poly(ortho ester), a polyacrylate, a polyalkylene, a polycarbonate, a fluoropolymer, a polysulfone, carbohydrate polymers, a polypeptide, a polyphosphazine, a polyether, a poly(ether sulfone), a poly(vinylalcohol), poly(ethylene-co-vinyl acetate), poly(ethylene-co-vinyl alcohol), a poly(epoxide)-polyamine curing system, and an acrylate.
2. The polymeric material of claim 1 , wherein said uniformly sulfonated aryl-containing block copolymer comprises a pseudo-random block copolymer or a random block copolymer wherein the end blocks comprise arylene-vinyl polymer.
3. The polymeric material of claim 1 , wherein said uniformly sulfonated aryl-containing block copolymer comprises polyethersulfone, polyetherketone, polystyrene, methylmethacrylate, polydioxanone, polylactides, polyglycolides, lactide-glycolide copolymers or polyesters.
4. An article of manufacture made with the polymeric material of claim 1 , wherein said article is selected from the group consisting of a membrane, a medical device, a pharmaceutical composition, a moisture transfer membrane, a fluid-absorbing material, a fuel cell, a capacitor, a wound dressing, a fabric, a building material, a desalination membrane or device, a membrane for heating, a membrane or device for ventilating and air conditioning (HVAC), a packing material, a surface coating, a shunt, a stent, tubing, clothing, bedding, surface coatings, fluid absorbing materials, adhesives, fluid collection or storage bags, sensors, gauges, and fluid filters.
5. A method of making the polymeric material of claim 1 , wherein said method comprises the steps of combining at least one of said uniformly sulfonated aryl-containing block copolymer in solution with at least one of said thermoplastic or thermosetting non-sulfonated homopolymer or copolymer, allowing the solution to thoroughly mix, and isolating and/or processing the polymer blend.
6. The method of claim 5 wherein said step of isolating and/or processing the polymer blend comprises at least one of spray drying, precipitation, solvent evaporation, extruding, electrospraying, electrospinning, and precipitating the polymer blend.
7. The method of claim 5 further comprising the step of converting the polymer blend to salt form.
8. A method of making an article of manufacture comprising the polymeric material of claim 1 , comprising the steps of combining at least one of said uniformly sulfonated aryl-containing block copolymer in solution with at least one of said thermoplastic or thermosetting non-sulfonated homopolymer or copolymer, allowing the solution to thoroughly mix, isolating the polymer blend, and manipulating the polymer blend to form the article.
9. The method of claim 8 , wherein said step of manipulating the polymer blend comprises at least one of thermal lamination, transfer molding, press molding, extruding, thermal fiber-spinning, electrospinning, electrospraying, painting, dipping, and pressure spraying.