Liquid fuel from aquatic biomass
View Patent ↗A process is disclosed for converting aquatic biomass to a bio-oil. The process comprises mixing the aquatic biomass with a particulate catalytic material; subjecting the aquatic biomass to a catalytic cracking reaction to form a reaction mixture comprising a bio-oil; and isolating the bio-oil from the reaction mixture. Preferably the process is integrated with a plant for producing aquatic biomass, so that heat and CO 2 generated during the process may be used in the production of aquatic biomass.
1. A method for converting aquatic biomass to bio-oil, said method comprising the steps of:
a) contacting the aquatic biomass with a particulate catalyst material;
b) catalytically cracking the aquatic biomass at elevated temperature, whereby a reaction mixture is formed containing a bio-oil; and
c) isolating the bio-oil from the reaction mixture;
wherein step a) is preceded by the step of at least partially dewatering the aquatic biomass,
wherein the dewatering comprises collecting water containing the aquatic biomass with a screen and allowing the water to run off the screen.
2. The method of claim 1 , wherein step a) comprises milling the aquatic biomass with the particulate catalytic material.
3. The method of claim 1 wherein the particulate catalyst material comprises an inorganic oxide.
4. The method of claim 3 wherein the particulate catalyst material is hydrotalcite.
5. The method of claim 1 wherein the particulate catalyst material has a mean particle size in the range of from 1 mm to 10 nm.
6. The method of claim 1 whereby step b) is carried out at a temperature in the range of from 200 to 350° C.
7. The method of claim 1 whereby gas is formed in step b) and the gas is collected from the reaction mixture.
8. The method of claim 1 wherein coke is formed on the particulate catalyst material.
9. The method of claim 8 comprising the additional step of:
d) burning the coke off the particulate catalyst material.
10. The method of claim 9 which is integrated with a production process of aquatic biomass, and wherein CO 2 produced in step d) is utilized in the production process of aquatic biomass.
11. The method of claim 9 wherein heat produced in step d) is utilized in the production process of aquatic biomass.
12. The method of claim 1 wherein the isolating of step c) comprises separating the bio-oil from an aqueous phase.
13. The method of claim 12 wherein the separating is performed by gravity.
14. The method of claim 12 wherein the aqueous phase comprises dissolved organic reaction products, further comprising removing the dissolved organic reaction products from the aqueous phase to thereby yield extracted organic reaction products.
15. The method of claim 14 further comprising blending at least a portion of the extracted organic reaction products with at least a portion of the bio-oil to form a refining feedstock.
16. The method of claim 14 , further comprising upgrading at least a portion of the extracted organic reaction products to form specialty chemicals.