Non-zeolite base metal SCR catalyst
View Patent ↗A method of converting nitrogen oxides in a gas stream to nitrogen comprises contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a non-zeolite base metal catalyst consisting of: (a) at least one transition metal dispersed on a mixed oxide or composite oxide or a mixture thereof as support material consisting of cerium and zirconium; or (b) cerium oxide and zirconium oxide as single oxides or a composite oxide thereof or a mixture of the single oxides and the composite oxide dispersed on an inert oxide support material, whereon is dispersed at least one transition metal.
1. A method of converting nitrogen oxides in a gas stream to nitrogen comprising contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a non-zeolite base metal catalyst consisting of: (a) at least one transition metal dispersed on a mixed oxide or composite oxide or a mixture thereof as support material consisting of cerium and zirconium; or (b) cerium oxide and zirconium oxide as single oxides or a composite oxide thereof or a mixture of the single oxides and the composite oxide dispersed on an inert oxide support material, wherein at least one transition metal is dispersed thereon, wherein the at least one transition metal is selected from the group consisting of a Group VIB metal, a Group IB metal, a Group IVA metal, a Group VB metal, a Group VIIB metal, a Group VIII metal and mixtures of any two or more thereof, provided that at least one selected transition metal is tungsten.
2. A method according to claim 1 , wherein the content of cerium and zirconium as oxides in the catalyst is Ce x Zr 1-x O 2 , wherein X=0.1-0.9.
3. A method according to claim 2 , wherein the at least one transition metals is two or more dispersed transition metals.
4. A method according to claim 3 , wherein the two or more transition metals are selected from the group consisting of Cr, Ce, Mn, Fe, Co, Ni, W and Cu.
5. A method according to claim 4 , wherein the two or more transition metals are selected from the group consisting of Fe, W, Ce and Cu.
6. A method according to claim 3 , wherein the two or more transition metals comprise iron.
7. A method according to claim 3 , wherein the transition metal components of the base metal catalyst consist of iron and tungsten.
8. The method of claim 7 wherein said non-zeolite base metal catalyst containing said tungsten and iron is activated at a temperature of at least 600° C.
9. A method according to claim 3 , wherein the total at least one transition metal present in the catalyst is from 0.01 to 50 wt %, based on the total weight of the catalyst.
10. A method according to claim 9 , wherein the total at least one transition metal present in the catalyst is from 0.1 to 30 wt %, based on the total weight of the catalyst.
11. A method according to claim 10 , wherein the total at least one transition metal present in the catalyst is from 0.5 to 20 wt %, based on the total weight of the catalyst.
12. A method according to claim 1 , wherein the non-zeolite based metal catalyst consists of (b) and the inert oxide support is selected from the group consisting of alumina, titania, non-zeolite silica-alumina, ceria, zirconia and mixtures, composite oxides and mixed oxides of any two or more thereof.
13. A method according to claim 1 , wherein the nitrogen oxides are reduced with the nitrogenous reducing agent at a temperature of at least 100° C.
14. A method according to claim 13 , wherein the temperature is from about 150° C. to 750° C.
15. A method according to claim 1 , wherein the nitrogen oxides reduction is performed in the presence of oxygen.
16. A method according to claim 1 , wherein addition of nitrogenous reductant is controlled so that NH 3 upstream of the catalyst inlet is controlled to be 60% to 200% of theoretical ammonia calculated at 1:1 NH 3 /NO and 4:3 NH 3 /NO 2 .
17. A method according to claim 1 , wherein the ratio of nitrogen monoxide to nitrogen dioxide in the gas upstream of said catalyst is from 4:1 to 1:3 by volume.
18. A method according to claim 17 , wherein the molar ratio of nitrogen monoxide to nitrogen dioxide in the gas is adjusted by oxidising nitrogen monoxide to nitrogen dioxide using an oxidation catalyst located upstream of the catalyst.
19. A method according to claim 1 , wherein the nitrogenous reducing agent is selected from the group consisting of ammonia per se, hydrazine or an ammonia precursor selected from the group consisting of urea ((NH 2 ) 2 CO), ammonium carbonate, ammonium carbamate, ammonium hydrogen carbonate and ammonium formate.
20. The method of claim 1 wherein said non-zeolite base metal catalyst containing said at least one transition metal is activated at a temperature of at least 600° C.