Magnetic disk and method of manufacturing the same
View Patent ↗This invention provides a magnetic disk which can satisfactorily suppress the elution of internal components from an end face of a magnetic disk, and corrosion damage. The magnetic disk comprises a disk substrate, and a thin film including a magnetic layer, a carbon-based protective layer, and a lubricating layer provided in that order on the disk substrate. The main surface and the end face of the magnetic disk are covered with the carbonaceous protective layer. The carbon-based protective layer contains nitrogen at a part adjacent to the lubricating layer. The content of nitrogen atoms relative to the content of carbon atoms in the protective layer formed on the end face is equal to or more than the content of nitrogen atoms relative to the content of carbon atoms in the protective layer formed on the main surface.
1. A magnetic disk comprising:
a disk substrate, and
a thin film including a magnetic layer, a carbon-based protective layer, and a lubricating layer formed in this order over the disk substrate,
wherein a main surface and an end face of said magnetic disk are covered with said carbon-based protective layer, said carbon-based protective layer contains nitrogen at a part adjacent to the lubricating layer, and the content of nitrogen atoms relative to the content of carbon atoms in the protective layer formed on said end face is more than the content of nitrogen atoms relative to the content of carbon atoms in the protective layer formed on said main surface.
2. The magnetic disk according to claim 1 , wherein the content of nitrogen atoms relative to the content of carbon atoms in the protective layer formed on said end face is 0.10 (atomic ratio) or more.
3. The magnetic disk according to claim 1 , wherein the protective layer on the end face of said magnetic disk has a coverage of 95% or more.
4. The magnetic disk according to claim 1 , wherein said carbon-based protective layer has the characteristics of a CVD-formed protective layer.
5. The magnetic disk according to claim 1 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
6. A method of manufacturing a magnetic disk, comprising:
forming a magnetic layer and a carbon-based protective layer in this order over a disk substrate to cover a main surface and an end face of said magnetic disk with said carbon-based protective layer, and
then doping nitrogen into said carbon-based protective layer at a part adjacent to a lubricating layer so that a content of nitrogen atoms relative to carbon in the protective layer formed on said end face is more than a content of nitrogen atoms relative to the content of carbon atoms in the protective layer formed on said main surface.
7. The magnetic disk according to claim 2 , wherein the protective layer on the end face of said magnetic disk has a coverage of 95% or more.
8. The magnetic disk according to claim 2 , wherein said carbon-based protective layer has the characteristics of a CVD-formed protective layer.
9. The A magnetic disk according to claim 3 , wherein said carbon-based protective layer has the characteristics of a CVD-formed protective layer.
10. The magnetic disk according to claim 7 , wherein said carbon-based protective layer has the characteristics of a CVD-formed protective layer.
11. The magnetic disk according to claim 2 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
12. The magnetic disk according to claim 3 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
13. The magnetic disk according to claim 4 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
14. The magnetic disk according to claim 7 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
15. The magnetic disk according to claim 8 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
16. The magnetic disk according to claim 9 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.
17. The magnetic disk according to claim 10 , wherein said magnetic layer is a cobalt (Co) alloy based magnetic layer.