Surface-modified, pyrogenically prepared silicas
View Patent ↗Surface-modified, pyrogenically prepared silica is prepared by subjecting the pyrogenically prepared silica, which is in the form of aggregates of primary particles and possesses a BET surface area of 150±15 m 2 /g, the aggregates having an average area of 12 000-20 000 nm 2 , an average equivalent circle diameter (ECD) of 90-120 nm and an average circumference of 1150-1700 nm, to surface-modification in a known way. It can be used as a filler for thickening liquid systems.
1. A process for preparing a silica for incorporation into a resin, the method comprising:
pyrogenically preparing a silica powder;
applying at least one dimethylpolysiloxane surface modifier to the pyrogenic silica powder; and
heat treating the silica powder with the applied surface modifier to obtain the silica for incorporation into a resin;
wherein
the pyrogenically prepared silica powder comprises aggregates of primary particles,
a BET surface area of the aggregates is 150±15 m 2 /g,
an average area of the aggregates is from 12 000 to 20 000 nm 2 ,
an average equivalent circle diameter (ECD) of the aggregates is from 90 to 120 nm, and
an average circumference of the aggregates is from 1150 to 1700 nm.
2. The process of claim 1 , wherein the application of the at least one dimethylpolysiloxane surface modifier comprises spraying the silica with the at least one dimethylpolysiloxane surface modifier.
3. The process of claim 1 , wherein the application of the at least one dimethylpolysiloxane surface modifier comprises:
treating the silica with the at least one dimethylpolysiloxane surface modifier in vapor form to obtain a mixture, and subsequently
thermally treating the mixture at a temperature of 50 to 800° C. over a period of 0.1 to 6h.
4. The process of claim 2 , wherein the surface modification comprises spraying the silica with water prior to spraying the silica with the at least one dimethylpolysiloxane surface modifier.
5. The process of claim 2 , wherein the surface modification comprises spraying the silica with water after spraying the silica with the at least one dimethylpolysiloxane surface modifier.
6. The process of claim 4 , wherein the water comprises an acid.
7. The process of claim 5 , wherein the water comprises an acid.
8. The process of claim 1 , wherein the surface modifier consists essentially of polydimethylsiloxane.
9. The process of claim 1 , wherein the surface modifier consists of polydimethylsiloxane.