Laser-sensitive coating composition
View Patent ↗The present invention provides a laser-sensitive coating composition comprising titanium dioxide in the anatase form or polymeric particles comprising a polymeric matrix comprising one or more water-insoluble polymers and titanium dioxide in the anatase form encapsulated in the polymeric matrix, and a polymeric binder. The present invention also provides a process for the preparation of the compositions, processes for preparing substrates coated with the coating compositions, substrates coated with the compositions, processes for marking the substrates coated with the compositions, and marked substrates obtainable by the latter processes.
1. A process for preparing a marked substrate, comprising the steps of
i) applying to a substrate a composition comprising titanium dioxide in the anatase form, a polymeric binder and at least one of tungsten suboxide, tungsten bronze, or mixtures of tungsten trioxide, tungsten bronze and metallic tungsten,
and
ii) irradiating those parts of the substrate of step i), where a marking is intended, with infrared laser irradiation in order to generate a marking.
2. The process of claim 1 , wherein the substrate is paper, cardboard or polymer.
3. The process of claim 1 , wherein the composition further comprises an infrared absorber.
4. The process of claim 1 , wherein the composition further comprises a tungsten oxide of the formula WO 3-x , wherein x is 0.1-1.
5. The process of claim 4 , wherein the tungsten oxide is WO 2.7 .
6. A process for preparing a marked substrate A, comprising the steps of
i) obtaining a substrate A and a substrate B,
ii) applying to substrate B a composition comprising titanium dioxide in the anatase form, a polymeric binder and at least one of tungsten suboxide, tungsten bronze, or mixtures of tungsten trioxide, tungsten bronze and metallic tungsten,
iii) placing the coated side of substrate B of step ii) against substrate A, and
iv) irradiating those parts of the uncoated side of substrate B of step ii), where a marking of opposed substrate A is intended, with infrared laser irradiation in order to generate a marking on substrate A.
7. The process of claim 6 , wherein substrate B is paper, cardboard or polymer.
8. The process of claim 6 , wherein the composition further comprises an infrared absorber.
9. The process of claim 6 , wherein the composition further comprises a tungsten oxide of the formula WO 3-x , wherein x is 0.1-1.
10. The process of claim 9 , wherein the tungsten oxide is WO 2.7 .