Thermoplastic polyurethane copolymer molding compositions
View Patent ↗Compositions for forming molded articles, particularly, shells for automotive applications are made up of melt blends of aliphatic thermoplastic urethane elastomer and an olefin-containing block copolymer crosslinked to a gel content of from 5 to 95%. These compositions may be blended to form a powder, pellets, microspheres or minibeads which may then be cast to form air bag door and instrument panel cover skins which may meet automotive deployment and weathering requirements.
1. A molding composition consisting of a compatible blend of
a) from 5 to 95 wt. % of an aliphatic thermoplastic polyurethane comprising the reaction product of
(i) a polyol component comprising at least one polyether polyol having a molecular weight of from 1000 to 10,000 Da and an unsaturation level less than or equal to 0.04 meq/g,
(ii) an isocyanate component comprising at least one aliphatic organic diisocyanate,
(iii) a chain extender,
(iv) optionally, a UV stabilizing agent,
(v) optionally, an antioxidant,
(vi) optionally, a pigment, and
(vii) a catalyst which promotes urethane formation,
b) from 5 to 95 wt. % of an olefin-containing block copolymer crosslinked to a gel content of from about 5 to about 95%,
c) optionally, a UV stabilizing agent,
d) optionally, an antioxidant,
e) optionally, a pigment,
f) optionally, a mold release agent, and
g) optionally, an ionomer.
2. The composition of claim 1 wherein component b) has a shear viscosity of approximately 900 at a shear rate of 250 sec −1 which drops to approximately 150 at 2100 sec −1 .
3. The composition of claim 1 wherein component b) is a block copolymer based on styrene and ethylene and/or butylene.
4. The composition of claim 1 wherein component a)(i) has an unsaturation level of less than 0.02 meq/g.
5. The composition of claim 1 wherein the aliphatic organic diisocyanate is selected from the group consisting of hexamethylene diisocyanate, hydrogenated diphenylmethane diisocyanate, and isophorone diisocyanate.
6. The composition of claim 1 wherein the chain extender is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, 1,4-butane diol, pentane diol, 3-methylpentane-1,5-diol, 1,6-hexane diol, hydroquinone bis(2-hydroxyethyl)ether, 1,4-cyclo-hexanedimethanol, neopentyl glycol, and hydrogenated bisphenol A.
7. The composition of claim 1 wherein the ionomer is an ethylene methacrylic acid copolymer.
8. The composition of claim 1 wherein the ionomer is an ethylene methacrylic acid copolymer in which a portion of the methacrylic acid is neutralized with a metal ion.
9. The composition of claim 1 wherein component a) is produced from a mixture comprising from 40 to 70 wt. %, based on total weight of the thermoplastic polyurethane, of the polyol component.
10. The composition of claim 1 wherein components a) and b) are melt blended.
11. The composition of claim 1 , wherein component a) comprises 45-90 wt. %, component b) comprises 5-45 wt. %, and component e) comprises 5-10 wt. %, of the molding composition.
12. The composition of claim 1 , wherein component a) comprises 45-90 wt. %, component b) comprises 5-45 wt. %, component e) comprises 5-10 wt. %, and component g) comprises 0-10 wt. % of the molding composition.
13. The composition of claim 1 wherein the ratio of a) to b) by weight is greater than or equal to 1:1.
14. A process for producing a slush castable powder comprising melt blending the composition of claim 1 in an extruder and cryogenically grinding the resulting melt blended extrudate.
15. A process for producing slush castable microspheres comprising melt blending the composition of claim 1 in an extruder, passing the melt blended composition through a die, and cutting the composition exiting the die.
16. A process for producing a slush castable powder comprising melt blending the composition of claim 1 in an extruder and underwater grinding the resulting melt blended extrudate.
17. A process for the production of a single layer cast shell comprising
a)applying the composition of claim 1 to a mold surface,
b) heating the mold surface to cause the applied composition to melt,
c) allowing the melt to flow over the mold surface, and
d) allowing the melt to cool.
18. A molded article produced by the process of claim 17 wherein no further components are added to the single layer cast shell.
19. A process for the production of a dual layer cast shell comprising
a) applying the composition of claim 1 to a mold as an outer layer, and
b) applying an inner layer comprising another composition to the outer layer,
and
c) molding the inner and outer layers in a manner such that the inner and outer layers harden and bond together.
20. The process of claim 19 in which the inner layer composition is a polyurethane produced from an aromatic polyisocyanate.
21. The process of claim 19 in which the inner layer composition has a melt flow comparable to the composition of the outer layer.
22. A molded article produced by the process of claim 19 in which the outer layer consists of the composition.
23. A molded article in the form of a skin, cover, or shell produced by the process of claim 19 in which the outer layer consists of the composition.
24. A thermoformed sheet consisting of the composition of claim 1 .
25. A process for the production of an article comprising injection molding the composition of claim 1 .
26. An injection molded article produced by the process of claim 25 which consists of the composition.