Nanoparticles from slightly oxidised cellulose
View Patent ↗The present invention provides novel nanoscale cellulose particles and also a process for their production. The cellulose-based particles obtained have volume-averaged particle sizes of less than 300 run. These nanoparticles are produced from slightly oxidized cellulose and by input of energy into a water-containing medium after or during dispersion.
1. Process for producing a dispersion containing particles of slightly oxidized cellulose, which process comprises
a) slightly oxidized cellulose being introduced into an aqueous medium and
b) being simultaneously or subsequently dispersed therein by input of energy, wherein the volume-average particle size (D50 value) of the particles is less than 300 nm, determined by dynamic laser light scattering, wherein the D90 value of the dispersed particles is less than 300 nm, and wherein the slightly oxidized cellulose used is obtained by periodate oxidation, phosphoric acid/sodium nitrite oxidation or TEMPO-catalysed sodium hypochlorite oxidation,
wherein no dispersant is added before, during or after dispersing step b).
2. Process according to claim 1 , wherein the slightly oxidized cellulose used is obtained from chemical pulp, paper-grade pulp, microcrystalline cellulose or linters cellulose.
3. Process for producing a dispersion containing particles of slightly oxidized cellulose, which process comprises
a) slightly oxidized cellulose being introduced into an aqueous medium and
b) being simultaneously or subsequently dispersed therein by input of energy, wherein the volume-average particle size (D50 value) of the particles is less than 300 nm, determined by dynamic laser light scattering, and wherein the slightly oxidized cellulose used is obtained by periodate oxidation, phosphoric acid/sodium nitrite oxidation or TEMPO-catalysed sodium hypochlorite oxidation,
wherein no dispersant is added before, during or after dispersing step b), wherein the slightly oxidized cellulose used has an average degree of polymerization DP cuen in the range from 100 to 3000.
4. Process according to claim 1 , wherein the slightly oxidized cellulose used has a carboxyl or carbonyl content of 200 to 1500 mmol/kg with regard to the slightly oxidized cellulose.
5. Process according to claim 1 , wherein the energy input in step b) is at least 2000 kWh/t with regard to the mass of the slightly oxidized cellulose.
6. Process according to claim 1 , wherein the input of energy in step b) is effected via ultrasonicators, high-speed stirrers, dispersing devices based on the rotor-stator principle, jet dispersers or high pressure homogenizing dispersing devices.
7. Process according to claim 1 , wherein the input of energy in step b) is effected in at least two stages comprising the input of energy in a first stage via a dispersing device based on the rotor-stator principle followed by the input of energy in a second stage via a high pressure homogenizing dispersing device.
8. Process for producing a dispersion containing particles of slightly oxidized cellulose, which process comprises
a) slightly oxidized cellulose being introduced into an aqueous medium and
b) being simultaneously or subsequently dispersed therein by input of energy, wherein the volume-average particle size (D50 value) of the particles is less than 300 nm, determined by dynamic laser light scattering, and wherein the slightly oxidized cellulose used is obtained by periodate oxidation, phosphoric acid/sodium nitrite oxidation or TEMPO-catalysed sodium hypochlorite oxidation,
wherein no dispersant is added before, during or after dispersing step b), wherein the dispersion obtained in step b) has a solids concentration with regard to slightly oxidized cellulose in the range from 0.1% to 10% by weight.
9. Process according to claim 1 , wherein step b) is carried out at temperatures of 10 to 100° C.