Adhesives based on polyester-graft-poly(meth)acrylate copolymers
View Patent ↗The present invention relates to the use of mixtures comprising polymer types A, B and AB as or in adhesives, polymer type A being a copolyester prepared with cocondensation of unsaturated aliphatic dicarboxylic acids, polymer type B being a (meth)acrylate homopolymer and/or copolymer, and polymer type AB being a graft copolymer of polymer type A and polymer type B.
1. A method of preparing an adhesive, comprising:
preparing
a polymer A of copolyester by cocondensating at least one unsaturated aliphatic dicarboxylic acid,
a polymer B of at least one of (meth)acrylate homopolymer and copolymer, and
a polymer AB which is graft copolymer of said polymer A and said polymer B, to obtain a mixture comprising polymers A, B and AB.
2. The method according to claim 1 , wherein the unsaturated aliphatic dicarboxylic acid is selected from the group consisting of fumaric acid, maleic acid, itaconic acid and esterifiable derivatives thereof.
3. The method according to claim 1 , wherein the unsaturated aliphatic dicarboxylic acid is itaconic acid.
4. The method according to claim 1 , wherein the amount of polymer A is between 5% and 80% by weight, the amount of polymer B is between 5% and 80% by weight and the amount of polymer AB is between 10% and 98% by weight, based on the total mass of polymers A, B and AB.
5. The method according to claim 1 , wherein the polymer A is a copolyester whose unsaturated aliphatic dicarboxylic acid content, based on the total amount of polycarboxylic acids used, is between 0.1 mol % and 20 mol %.
6. The method according to claim 1 , wherein the mixture contains no styrene or styrene derivative.
7. The method according to claim 1 , wherein the polymer AB comprises a graft copolymer comprising a polyester main chain and a poly(meth)acrylate side chain.
8. The method according to claim 1 , wherein the average fraction of the poly(meth)acrylate fractions in the total mixture is between 10% and 90% by weight.
9. An adhesive, comprising:
a mixture of polymers A, B and AB,
wherein the polymer A is a copolyester prepared by a process comprising cocondensating an unsaturated aliphatic dicarboxylic acid, the polymer B is at least one of (meth)acrylate homopolymer and copolymer, and the polymer AB is a graft copolymer of said polymer A and said polymer B.
10. The adhesive according to claim 9 , wherein the unsaturated aliphatic dicarboxylic acid is itaconic acid.
11. The adhesive according to claim 9 , wherein the adhesive is a hotmelt adhesive.
12. The adhesive according to claim 9 , further comprising at least one of isocyanates and polyisocyanates.
13. The adhesive according to claim 9 , further comprising at least one member selected from the group consisting of other polyols, non-functionalized polymers, pigments, fillers, tackifiers, ageing inhibitors and auxiliaries.
14. A sealant comprising the adhesive according to claim 9 .
15. An adhesive bond comprising the adhesive according to claim 9 .