Waterbased dimerized rosins and the process to make them
View Patent ↗The present invention relates to a method to prepare dimerized rosins dispersible in water in presence of extremely low level of dimerization acid catalyst. The present invention relates also to its use as a tackifier resin, solid or in water, and ink resin, and an adhesive composition and ink composition comprising the rosin resin.
1. A method to produce a dimerized rosin comprising contacting a rosin with a catalyst comprising an alkyl substituted aryl sulfonic acid to produce the dimerized rosin containing the catalyst or a salt thereof, wherein the alkyl group has at least 5 carbon atoms.
2. The method of claim 1 further comprising neutralizing the dimerized rosin with an alkali salt or an organic amine then subsequently dispersing the dimerized rosin in water.
3. The method of claim 2 , wherein the dispersing comprises adding a surfactant.
4. The method of claim 1 wherein the catalyst is present from 1 to 5weight percent based on the weight of the rosin.
5. The method of claim 4 wherein the catalyst is selected from the group consisting of pentylbenzene sulfonic acid, hexylbenzene sulfonic acid, heptylbenzene sulfonic acid, octylbenzene sulfonic acid, nonylbenzene sulfonic acid, decylbenzene sulfonic acid, dodecylbenzene sulfonic acid, dodecyldiphenyl disulfonic acid, and combinations of any two or more thereof.
6. The method of claim 5 further comprising neutralizing the dimerized rosin by an alkali salt, an organic amine or ammonia then subsequently dispersing the dimerized rosin in water.
7. The method of claim 5 wherein the catalyst comprises dodecylbenzene sulfonic acid in an amount of 3 weight percent based on the weight of the rosin.